Patent US4240832A successfully refreshed from Google Patents.
US4240832A
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Dental pulp capping and cavity lining composition and preparative method
Assignee: Manufacturers Hanover Trust Co
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Filing: 1979-02-12
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Granted: 1980-12-23
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Expires: 1999-02-12
Abstract
Abstract This invention discloses an improved dental pulp capping and cavity lining composition which is successful in capping and preserving the vitality of moderately inflammed, as well as normal, healthy dental pulps and also serves as an acid resistant, protective cavity liner. This composition is prepared by reacting suitable phenolic derivatives with formaldehyde or its polymer, under carefully controlled conditions, to form a low molecular weight polymer condensate, which is first purified and then compounded into a two-paste composition of optimized utility. In use, one paste portion, containing the condensate, reacts with the other paste portion, containing calcium hydroxide, to yield after mixing a solid protective layer of set material, which facilitates healing of the pulp and formation of secondary dentin.
Inventors
- 👤 Emil Jandourek
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 11:00
CPC Classifications
C; C08; C08G; C08G8/00; C08G8/04; C08G8/08; C08G8/18; A; A61; A61K; A61K6/00; A61K6/80; A61K6/884; A61K6/891; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
84 words
A dental composition which comprises calcium hydroxide and a condensate of an ester of salicylic acid and an aldehyde selected from the group consisting of acetaldehyde, formaldehyde and its oligomers, such as paraformaldehyde and metaformaldehyde or trioxane, and where the aldehyde to salicylate ratio is from about 0.5 to 1.0 moles of aldehyde per mole of salicylate, the calcium hydroxide being present in stoichiometric excess over said condensate, which reacts with it to form a hard, rigid mass, containing free calcium hydroxide dispersed therein.
Claim 2
Dependent Claim
84 words
A dental composition which comprises calcium hydroxide and a condensate of an ester of salicylic acid and an aldehyde selected from the group consisting of acetaldehyde, formaldehyde and its oligomers, such as paraformaldehyde and metaformaldehyde or trioxane, and where the aldehyde to salicylate ratio is from about 0.5 to 1.0 moles of aldehyde per mole of salicylate, the calcium hydroxide being present in stoichiometric excess over said condensate, which reacts with it to form a hard, rigid mass, containing free calcium hydroxide dispersed therein.
Claim 3
Dependent Claim
77 words
A dental cement composition consisting essentially of calcium hydroxide and a condensate of an ester of salicylic acid and a selected aldehyde, said ester of salicylic acid being selected from a group consisting of alkyl and certain aryl salicylates, including the methyl, ethyl, propyl, isobutyl butyl hexyl and benzyl esters, while the said aldehyde may be selected from the group consisting of alkyl aldehydes including acetaldehyde, formaldehyde and its oligomers, such as paraformaldehyde and metaformaldehyde or trioxane.
Claim 4
Dependent Claim
77 words
A dental cement composition consisting essentially of calcium hydroxide and a condensate of an ester of salicylic acid and a selected aldehyde, said ester of salicylic acid being selected from a group consisting of alkyl and certain aryl salicylates, including the methyl, ethyl, propyl, isobutyl butyl hexyl and benzyl esters, while the said aldehyde may be selected from the group consisting of alkyl aldehydes including acetaldehyde, formaldehyde and its oligomers, such as paraformaldehyde and metaformaldehyde or trioxane.
Claim 5
Dependent Claim
88 words
A dental cement composition comprising calcium hydroxide and a condensate of an ester of salicylic acid and an aldehyde diluted to a suitable viscosity said aldehyde being selected from the group consisting of acetaldehyde, formaldehyde and its oligomers, such as paraformaldehyde and metaformaldehyde or trioxane with alkyl salicylates selected from the group consisting of alkyl and aryl salicylates including methyl, ethyl, propyl, isobutyl, butyl hexyl and benzyl esters, and where the aldehyde to salicylate ratio is from about 0.5 to 1.0 moles of aldehyde per mole of salicylate.
Claim 6
Dependent Claim
88 words
A dental cement composition comprising calcium hydroxide and a condensate of an ester of salicylic acid and an aldehyde diluted to a suitable viscosity said aldehyde being selected from the group consisting of acetaldehyde, formaldehyde and its oligomers, such as paraformaldehyde and metaformaldehyde or trioxane with alkyl salicylates selected from the group consisting of alkyl and aryl salicylates including methyl, ethyl, propyl, isobutyl, butyl hexyl and benzyl esters, and where the aldehyde to salicylate ratio is from about 0.5 to 1.0 moles of aldehyde per mole of salicylate.
Claim 7
Dependent Claim
106 words
A dental cement composition consisting essentially of a first paste containing the reaction product of a salicylate ester and an aldehyde selected from the group consisting of acetaldehyde, formaldehyde and its oligomers, such as paraformaldehyde and metaformaldehyde or tioxane, diluted to suitable viscosity and mixed to a paste with certain fillers, at least one of which is radiopaque, and suitable pigments, and a second paste comprising calcium hydroxide, zinc oxide and zinc stearate, plus suitable liquid matrix, said calcium hydroxide being present in stoichiometric excess over said reaction product in the first past so that following admixture in equal proportions a hard rigid mass is formed.
Claim 8
Dependent Claim
106 words
A dental cement composition consisting essentially of a first paste containing the reaction product of a salicylate ester and an aldehyde selected from the group consisting of acetaldehyde, formaldehyde and its oligomers, such as paraformaldehyde and metaformaldehyde or tioxane, diluted to suitable viscosity and mixed to a paste with certain fillers, at least one of which is radiopaque, and suitable pigments, and a second paste comprising calcium hydroxide, zinc oxide and zinc stearate, plus suitable liquid matrix, said calcium hydroxide being present in stoichiometric excess over said reaction product in the first past so that following admixture in equal proportions a hard rigid mass is formed.
Claim 9
Dependent Claim
104 words
A dental cement composition which comprises a first paste containing the condensate of about sixteen equivalents of methyl salicylate and about ten to thirteen equivalents of paraformaldehyde and a second paste comprising about 35 parts of mixed ortho and para isomers of N-ethyl, toluenesulfonamide, about 50 parts of calcium hydroxide, about 14 parts of zinc oxide and approximately one part of zinc stearate said calcium hydroxide being present in stoichiometric excess over said reaction product and reactable with it upon admixture to form a hard, rigid mass wherein the excess of free calcium hydroxide is continuously available for promotion of a secondary dentin growth.
Claim 10
Dependent Claim
104 words
A dental cement composition which comprises a first paste containing the condensate of about sixteen equivalents of methyl salicylate and about ten to thirteen equivalents of paraformaldehyde and a second paste comprising about 35 parts of mixed ortho and para isomers of N-ethyl, toluenesulfonamide, about 50 parts of calcium hydroxide, about 14 parts of zinc oxide and approximately one part of zinc stearate said calcium hydroxide being present in stoichiometric excess over said reaction product and reactable with it upon admixture to form a hard, rigid mass wherein the excess of free calcium hydroxide is continuously available for promotion of a secondary dentin growth.
Claim 11
Dependent Claim
62 words
A dental composition consisting essentially of a mixture of about 20% of the condensate of methyl salicylates and paraformaldehyde, plus about 5% methyl salicylate diluent and about 60% of a blend of solids consisting of calcium hydroxide, titanium dioxide, barium sulfate and zinc oxide, plus pigments and sub micron silaceous thickener, and about 15% mixed ortho and para isomers of n-ethyl toluenesulfonamide.
Claim 12
Dependent Claim
62 words
A dental composition consisting essentially of a mixture of about 20% of the condensate of methyl salicylates and paraformaldehyde, plus about 5% methyl salicylate diluent and about 60% of a blend of solids consisting of calcium hydroxide, titanium dioxide, barium sulfate and zinc oxide, plus pigments and sub micron silaceous thickener, and about 15% mixed ortho and para isomers of n-ethyl toluenesulfonamide.
Claim 13
Dependent Claim
16 words
A composition as defined in claim 1 which further contains at least one inert powdered filler.
Claim 14
Dependent Claim
37 words
A composition as defined in claim 1, containing an inert powdered filler selected from the group consisting of silica, titanium dioxide, barium sulfate and mixtures thereof or any other inert combination of suitable radiolucent or radiopaque fillers.
Claim 15
Dependent Claim
50 words
A composition as defined in claim 1 which contains a plasticizer miscible with the particular condensate of an ester of salicylic acid and the selected aldehyde which is employed, said plasticizer not entering into the reaction between said condensate and calcium hydroxide and consisting of ethyltoluenesulfonamide or other suitable liquids.
Claim 16
Dependent Claim
31 words
A composition as defined in claim 5 wherein the resin condensate is selected from an aldehyde to salicylate ratio of about 0.5 to 1.0 moles of aldehyde per mole of salicylate.
Claim 17
Dependent Claim
31 words
A composition as defined in claim 5 wherein the resin condensate is selected from an aldehyde to salicylate ratio of about 0.7 to 0.9 moles of aldehyde per mole of salicylate.
Claim 18
Dependent Claim
31 words
A composition as defined in claim 6 wherein the resin condensate to alkyl salicylate ratio is 40 to 80 parts resin condensate to 60 to 20 parts alkyl salicylate by weight.
Claim 19
Dependent Claim
27 words
A composition as defined in claim 6 wherein the solid to liquid ratio is 30 to 70 parts liquid to 70 to 30 parts solid by weight.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-12-23 | 1984-06-23 | 1984-12-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-12-23 | 1988-06-23 | 1988-12-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-12-23 | 1992-06-23 | 1992-12-23 | $7700.00 | Window Closed / Lapsed |