Method of preparing phosphonates from nitriles

Claim 2

The process for producing aminophosphonic acids having the following formulae, ##STR6## wherein R is a saturated or unsaturated aliphatic radical having 1-22 carbon atoms or phenyl or benzyl or naphthyl radical or substituted aliphatic or aromatic radicals, R' is a difunctional aliphatic bridging radical having 1-10 carbon atoms, and n is ≧2, comprising reacting at a temperature of from about 100° C. to about 200° C. a mixture consisting essentially of phosphorous acid and an organonitrile selected from the group consisting essentially of R--CN, NC--R'--CN and ##STR7## R being a saturated or unsaturated aliphatic radical, or phenyl, benzyl or naphthyl or substituted aliphatic or aromatic radical, R' being an aliphatic bridging radical, and n being a positive integer of 2 or greater.

Claim 3

The process for producing aminophosphonic acids having the formula ##STR8## wherein R is a saturated or unsaturated aliphatic radical having 1-22 carbon atoms or phenyl or benzyl or naphthyl radical or substituted aliphatic or aromatic radicals, comprising reacting a mixture at temperatures of from about 100° C. to about 200° C., said mixture consisting essentially of phosphorous acid and an organonitrile of the formula R--C.tbd.N wherein R is a saturated or unsaturated aliphatic radical having 1-22 carbon atoms or phenyl or benzyl or naththyl radical or substituted aliphatic or aromatic radicals.

Claim 4

The process for producing aminophosphonic acids having the formula ##STR8## wherein R is a saturated or unsaturated aliphatic radical having 1-22 carbon atoms or phenyl or benzyl or naphthyl radical or substituted aliphatic or aromatic radicals, comprising reacting a mixture at temperatures of from about 100° C. to about 200° C., said mixture consisting essentially of phosphorous acid and an organonitrile of the formula R--C.tbd.N wherein R is a saturated or unsaturated aliphatic radical having 1-22 carbon atoms or phenyl or benzyl or naththyl radical or substituted aliphatic or aromatic radicals.

Claim 5

The process for producing aminophosphonic acids having the formula ##STR9## wherein R' is a aliphatic bridging radical having 1-10 carbon atoms, comprising reacting a mixture at a temperature of from about 100° C. to about 200° C., said mixture consisting essentially of phosphorous acid with an organo-dinitrile of the formula N.tbd.C--R'--C.tbd.N wherein R' is an aliphatic bridging radical having 1-10 carbon atoms.

Claim 6

The process for producing aminophosphonic acids having the formula ##STR9## wherein R' is a aliphatic bridging radical having 1-10 carbon atoms, comprising reacting a mixture at a temperature of from about 100° C. to about 200° C., said mixture consisting essentially of phosphorous acid with an organo-dinitrile of the formula N.tbd.C--R'--C.tbd.N wherein R' is an aliphatic bridging radical having 1-10 carbon atoms.

Claim 7

The process for producing aminophosphonic acids having the formula ##STR10## wherein n is a positive integer equal to or greater than 2 comprising reacting a mixture at a temperature of from about 100° C. to about 200° C., said mixture consisting essentially of phosphorous acid with an organonitrile of the formula ##STR11## wherein n is a positive integer equal to or greater than 2.

Claim 8

The process for producing aminophosphonic acids having the formula ##STR10## wherein n is a positive integer equal to or greater than 2 comprising reacting a mixture at a temperature of from about 100° C. to about 200° C., said mixture consisting essentially of phosphorous acid with an organonitrile of the formula ##STR11## wherein n is a positive integer equal to or greater than 2.

Claim 9

The process for preparing organo-alphaamino-diphosphonic acids having the general structural formula ##STR12## where X is: R, R being a saturated or unsaturated aliphatic radical having from 1 to about 22 carbon atoms or phenyl, benzyl or naphthyl radical or substituted aliphatic or aromatic radicals; or ##STR13## R' being an aliphatic bridging radical having from 1 to about 10 carbonatoms; or --CH.sub.2 --CH].sub.n where n is a positive integer of 2 or greater; or --R'--CN, R' being an aliphatic bridging radical having from about 1 to about 10 carbon atoms, comprising reacting at a temperature of from about 100° C. to 200° C. a mixture, said mixture consisting essentially phosphorous acid with an organonitrile selected from the group consisting of R--CN, NC--R'--CN and ##STR14## R being a saturated or unsaturated aliphatic radical having from about 1 to about 22 carbon atoms or phenyl, benzyl or naphthyl radical or substituted aliphatic or aromatic radicals, R' being an aliphatic bridging radical having from 1 to about 10 carbon atoms, and n being a positive integer of 2 or greater.

Claim 10

The process for preparing organo-alphaamino-diphosphonic acids having the general structural formula ##STR12## where X is: R, R being a saturated or unsaturated aliphatic radical having from 1 to about 22 carbon atoms or phenyl, benzyl or naphthyl radical or substituted aliphatic or aromatic radicals; or ##STR13## R' being an aliphatic bridging radical having from 1 to about 10 carbonatoms; or --CH.sub.2 --CH].sub.n where n is a positive integer of 2 or greater; or --R'--CN, R' being an aliphatic bridging radical having from about 1 to about 10 carbon atoms, comprising reacting at a temperature of from about 100° C. to 200° C. a mixture, said mixture consisting essentially phosphorous acid with an organonitrile selected from the group consisting of R--CN, NC--R'--CN and ##STR14## R being a saturated or unsaturated aliphatic radical having from about 1 to about 22 carbon atoms or phenyl, benzyl or naphthyl radical or substituted aliphatic or aromatic radicals, R' being an aliphatic bridging radical having from 1 to about 10 carbon atoms, and n being a positive integer of 2 or greater.

Claim 11

The process of claim 5 wherein the reaction is carried out at a temperature of at least about 100° C.

Claim 12

The process of claim 5 wherein the reaction is carried out at a temperature of from about 135° C. to about 160° C.

Claim 13

The process of claim 5 wherein the reaction is carried out in a solvent.

Claim 14

The process of claim 8 wherein the reaction is carried out at a temperature of from about 135° C. to about 160° C.

Claim 15

The process of claim 9 wherein the solvent is excess phosphorous acid, an organic acid, dimethylsulfoxide, tetramethylene sulfone, or chlorinated aromatic hydrocarbon.

Claim 16

The process for producing 1-aminoalkane-1,1-diphosphonic acid of the formula ##STR15## wherein R is an alkyl radical, which comprises reacting at a temperature between about 140° C. and about 200° C., a mixture consisting essentially of phosphorous acid and a nitrile of the formula R--CN, R being defined as above.

Claim 17

The process for producing 1-aminoalkane-1,1-diphosphonic acid of the formula ##STR15## wherein R is an alkyl radical, which comprises reacting at a temperature between about 140° C. and about 200° C., a mixture consisting essentially of phosphorous acid and a nitrile of the formula R--CN, R being defined as above.