US4239539A
Expired / Lapsed
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Aminosilane modified zinc-rich coating compositions
Assignee: Akzo NV
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Filing: 1979-06-25
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Granted: 1980-12-16
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Expires: 1999-06-25
Abstract
Abstract Single-package zinc-rich coating compositions are provided by blending zinc, a partially hydrolyzed organic silicate and an aminoorganosilicon acylamino compound.
Inventors
- 👤 Thomas Ginsberg
- 👤 Lawrence G. Kaufman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 20:38
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/08; C09D5/10; C09D5/106; C08; C08K; C08K5/00; C08K5/54; C08K5/544; C08K5/5455; C09D183/00; C09D183/02
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
224 words
A composition for protecting ferrous metals from corrosion comprising particulate zinc, an unhydrolyzed or a partially hydrolyzed organic silicate hydrolyzed up to about 40% and a hardening amount of an aminoorganosilicon acylamino compound having the formula: ##STR18## wherein: X is an alkoxy radical having 1 to 6 carbon atoms; R is a alkylene radical having 1 to 4 carbon atoms; R 1 is hydrogen or an alkyl radical having 1 to 4 carbon atoms; R 2 is an alkylene radical having 2 to 4 carbon atoms; R 3 is a monovalent radical selected from the group consisting of hydrogen alkyl having 1 to 20 carbon atoms or phenyl; R 4 is a monovalent radical selected from the group consisting of alkyl having 1 to 20 carbon atoms, phenyl or silyl having the formula: ##STR19## wherein X, R and R 1 are as defined above; Q is a monovalent radical selected from the group consisting of hydrogen, alkyl having 1 to 4 carbon atoms, phenyl or an ester radical having the formula --COOR 5 wherein R 5 is alkyl having 1 to 4 carbon atoms; a is an integer having values of 0 to 2 and t and x are each integers having a value of 0 to 4, with the proviso that when x is at least 1, R 4 can also be hydrogen.
Claim 2
Dependent Claim
224 words
A composition for protecting ferrous metals from corrosion comprising particulate zinc, an unhydrolyzed or a partially hydrolyzed organic silicate hydrolyzed up to about 40% and a hardening amount of an aminoorganosilicon acylamino compound having the formula: ##STR18## wherein: X is an alkoxy radical having 1 to 6 carbon atoms; R is a alkylene radical having 1 to 4 carbon atoms; R 1 is hydrogen or an alkyl radical having 1 to 4 carbon atoms; R 2 is an alkylene radical having 2 to 4 carbon atoms; R 3 is a monovalent radical selected from the group consisting of hydrogen alkyl having 1 to 20 carbon atoms or phenyl; R 4 is a monovalent radical selected from the group consisting of alkyl having 1 to 20 carbon atoms, phenyl or silyl having the formula: ##STR19## wherein X, R and R 1 are as defined above; Q is a monovalent radical selected from the group consisting of hydrogen, alkyl having 1 to 4 carbon atoms, phenyl or an ester radical having the formula --COOR 5 wherein R 5 is alkyl having 1 to 4 carbon atoms; a is an integer having values of 0 to 2 and t and x are each integers having a value of 0 to 4, with the proviso that when x is at least 1, R 4 can also be hydrogen.
Claim 3
Dependent Claim
26 words
Composition claimed in claim 1 wherein R 3 is hydrogen, Q is hydrogen, t is 0, or 1, x is O and R 4 is alkyl.
Claim 4
Dependent Claim
28 words
Composition claimed in claim 1 wherein R 3 is hydrogen Q is hydrogen, t is 0 or 1, x is 1 and R 4 is hydrogen or alkyl.
Claim 5
Dependent Claim
46 words
Composition claimed in claim 1 wherein R 3 is hydrogen; Q is hydrogen; t is 0 or 1; x is 0 and R 4 is a silyl radical of the formula ##STR20## wherein R, R 1 and X and a are the same as defined above.
Claim 6
Dependent Claim
39 words
Composition claimed in claim 4 wherein a is 0; t is 0; R is --CH 2 CH 2 CH 2 --; and X is an alkoxy radical selected from the group consisting of methoxy, ethoxy, 2-ethoxyethoxy and 2-methoxyethoxy radicals.
Claim 7
Dependent Claim
11 words
Composition claimed in claim 5 wherein X is a methoxy radical.
Claim 8
Dependent Claim
11 words
Composition claimed in claim 5 wherein X is an ethoxy radical.
Claim 9
Dependent Claim
46 words
Composition claimed in claim 1 wherein R 3 is hydrogen; Q is hydrogen; t is 0 or 1; x is 1 and R 4 is a silyl radical of the formula ##STR21## wherein R, R 1 and X and a are the same as defined above.
Claim 10
Dependent Claim
46 words
Composition claimed in claim 8 wherein a is 0; t is 1; R is --CH 2 CH 2 CH 2 --; R 2 is --CH 2 CH 2 -- and X is an alkoxy radical selected from the group consisting of methoxy, ethoxy and 2-methoxyethoxy radicals.
Claim 11
Dependent Claim
11 words
Composition claimed in claim 9 wherein X is a methoxy radical.
Claim 12
Dependent Claim
11 words
Composition claimed in claim 9 wherein X is an ethoxy radical.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-12-16 | 1984-06-16 | 1984-12-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-12-16 | 1988-06-16 | 1988-12-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-12-16 | 1992-06-16 | 1992-12-16 | $7700.00 | Window Closed / Lapsed |