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US4239532A Expired / Lapsed US ⏱️ 0.0 years remaining

Addition and measurement of gases dissolved in molten metals

Assignee: PPG Industries Inc
•
Filing: 1978-12-11
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Granted: 1980-12-16
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Expires: 1998-12-11
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Abstract

Abstract Method and apparatus for measuring gases dissolved in molten metal. Also disclosed are method and apparatus for dissolving gases in molten metal and a method of forming a gas permeable but molten metal impervious ceramic tube. A ceramic member is leached by an invention process so as to be selectively gas permeable. The member is inserted into molten metal to submerge the permeable portion. Then a vacuum is applied to the member and dissolved gases are measured by the change in pressure caused by gases entering from the molten metal. In another embodiment gas is applied to the submerged member to cause it to dissolve in the molten metal.

Inventors

  • 👤 Ties Allersma
  • 👤 James E. Simpson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 20:01
CPC Classifications
G; G01; G01N; G01N7/00; G01N7/10; G01F; G01F13/00; G01N33/00; G01N33/20; G01N33/202; G01N33/2022; G01N33/2025

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 95 words
Apparatus for measuring at least one dissolved gas in a liquid comprising: a probe having a unitary outer wall to define a passageway within said probe, a portion of said outer wall to be submerged in the liquid permeable with respect to the at least one gas to be measured but impermeable to the liquid containing the at least one dissolved gas and the remaining wall portion impermeable to both the at least one gas and the liquid; means for drawing a vacuum on said passageway; and means for measuring gas pressure in said probe.
Claim 2
Dependent Claim 95 words
Apparatus for measuring at least one dissolved gas in a liquid comprising: a probe having a unitary outer wall to define a passageway within said probe, a portion of said outer wall to be submerged in the liquid permeable with respect to the at least one gas to be measured but impermeable to the liquid containing the at least one dissolved gas and the remaining wall portion impermeable to both the at least one gas and the liquid; means for drawing a vacuum on said passageway; and means for measuring gas pressure in said probe.
Claim 3
Dependent Claim 26 words
The apparatus as set forth in claim 1 further including: means for isolating said probe and said gas pressure measuring means from said vacuum drawing means.
Claim 4
Dependent Claim 25 words
The apparatus as set forth in claim 1 wherein said probe includes a closed end ceramic tube having said permeable portion adjacent the closed end.
Claim 5
Dependent Claim 31 words
The apparatus as set forth in claim 1 or 2 wherein said impermeable outer wall portion includes a mullite and glassy material and said permeable outer wall portion comprises primarily mullite.
Claim 6
Dependent Claim 18 words
The apparatus as set forth in claim 1 wherein said gas pressure measuring means includes a pressure transducer.
Claim 7
Dependent Claim 18 words
The apparatus as set forth in claim 1 wherein said gas pressure measuring means includes a diaphragm gauge.
Claim 8
Dependent Claim 18 words
The apparatus as set forth in claim 1 wherein said gas pressure measuring means includes an ion pump.
Claim 9
Dependent Claim 27 words
The apparatus as set forth in claim 4 wherein said impervious outer wall portion is about 80 weight percent mullite and about 20 weight percent silicon dioxide.
Claim 10
Dependent Claim 17 words
The apparatus as set forth in claim 1 wherein the liquid is at least one molten metal.
Claim 11
Dependent Claim 25 words
The apparatus as set forth in claim 9 wherein the at least one molten metal includes tin and the at least one gas includes hydrogen.

References Cited (Backward Citations)

US2411157A Cited
US3298069A Cited
US3795500A Cited
US3855098A Cited
US3743588A Cited
US3934470A Cited
US4003818A Cited
US3896020A Cited
US3932135A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-12-16 1984-06-16 1984-12-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-12-16 1988-06-16 1988-12-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-12-16 1992-06-16 1992-12-16 $7700.00 Window Closed / Lapsed

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