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US4238528A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyimide coating process and material

Assignee: International Business Machines Corp
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Filing: 1979-10-02
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Granted: 1980-12-09
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Expires: 1999-10-02
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Abstract

Abstract A protective layer composition, suitable for protecting metal electrodes on components and other microelectronic circuitry, comprises an organic thermoplastic polymeric material, an organic solvent or solvents, and a non-ionic fluorocarbon surfactant as a wetting/leveling/flow control agent. A typical formulation comprises an aromatic polymer which cures to form a polyamide-imide polymer, an organic solvent or a mixture of orangic solvents and a non-ionic fluorocarbon surfactant.

Inventors

  • 👤 Raymond W. Angelo
  • 👤 Richard M. Poliak
  • 👤 John R. Susko

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 15:42
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/68; H10P14/683; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/303; H01B3/306; H05; H05K; H05K3/00; H05K3/22; H05K3/28; H05K3/284; H10W; H10W74/00; H10W74/01; H10W74/10; H10W74/131; H10W74/40; H10W74/47; H05K2201/00; H05K2201/09; H05K2201/09818; H05K2201/09872; H05K2201/10; H05K2201/10613; H05K2201/10954; H05K2201/10977; H10P14/63; H10P14/6326; H10P14/6342; H10W72/00; H10W72/071; H10W72/072; H10W72/07251; H10W72/20; Y; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49117; Y10T29/49124; Y10T29/4913; Y10T29/49146; Y10T29/49169; Y10T29/49171

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 55 words
A process for forming a seal coating on electronic circuitry comprising: applying to said circuitry a filler free coating material which includes: an aromatic polymer which, when cured, forms a polyimide, an organic solvent for said polymer, and a non-ionic fluorocarbon surfactant, and curing the material to form a polyimide seal coating on said circuitry.
Claim 2
Dependent Claim 55 words
A process for forming a seal coating on electronic circuitry comprising: applying to said circuitry a filler free coating material which includes: an aromatic polymer which, when cured, forms a polyimide, an organic solvent for said polymer, and a non-ionic fluorocarbon surfactant, and curing the material to form a polyimide seal coating on said circuitry.
Claim 3
Dependent Claim 23 words
The process of claim 1 wherein the aromatic polymer is selected from the group consisting of a polyamic acid and a polyamic acid-imide.
Claim 4
Dependent Claim 21 words
The process of claim 1 wherein the layer includes from about 0 to 1% by weight of a silane adhesion promoter.
Claim 5
Dependent Claim 28 words
The process of claim 1 wherein the coating material includes by weight: about 2 to 20% polymer, about 0.001 to 1.0% surfactant and about 80 to 90% solvent.
Claim 6
Dependent Claim 28 words
The process of claim 4 wherein the coating material includes by weight about 4 to 8% polymer, about 0.001 to 1% surfactant and about 92 to 96% solvent.
Claim 7
Dependent Claim 155 words
The process of claim 1 wherein the fluorocarbon surfactant is selected from the group consisting of non-ionic fluoroinated alkyl-ester surfactants represented by the formula: ##STR8## where R f is a perfluoroalkyl group having from 3 to 12 carbon atoms and m is integer from 2 to 12, and R' is a low molecular weight polyoxethylene, a polyoxypropylene or a polyoxyethylenepolyoxypropylene copolymer group, N-polyoxyethylene substituted perfluorosulfonamides represented by the formula: ##STR9## in which R is a lower alkyl group having from 1 to 6 carbon atoms such as methyl, ethyl propyl, butyl, etc. and n is an integer from 2-30, and N-alkanol perfluoroalkanesulfonamides represented by the formula: R.sub.f SO.sub.2 N(R')RCH.sub.2 OH where R f is a perfluoroalkyl group containing 4 to 12 carbon atoms, R is an alkylene bridging group containing 1 to 12 carbon atoms, and R' is a hydrogen atom or an alkyl group containing 1 to 6 carbon atoms; and the corresponding esters.
Claim 8
Dependent Claim 111 words
A process for forming an aromatic seal coating on metal conductor lines on the surface of a substrate and the solder joints and pads forming the connection between the substrate and an integrated circuit chip which is electrically bonded thereto comprising applying to said surface a filler free coating material which comprises 2 to 20% by weight of an aromatic polymer which, when cured, forms a polyimide about 80 to 90% by weight of an organic solvent for said polymer, about 0.001 to 1% by weight of a non-ionic fluorocarbon surfactant, and about 0 to 1% by weight of silane adhesion promoter, and curing material to form a polyimide seal coating.
Claim 9
Dependent Claim 111 words
A process for forming an aromatic seal coating on metal conductor lines on the surface of a substrate and the solder joints and pads forming the connection between the substrate and an integrated circuit chip which is electrically bonded thereto comprising applying to said surface a filler free coating material which comprises 2 to 20% by weight of an aromatic polymer which, when cured, forms a polyimide about 80 to 90% by weight of an organic solvent for said polymer, about 0.001 to 1% by weight of a non-ionic fluorocarbon surfactant, and about 0 to 1% by weight of silane adhesion promoter, and curing material to form a polyimide seal coating.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-12-09 1984-06-09 1984-12-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-12-09 1988-06-09 1988-12-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-12-09 1992-06-09 1992-12-09 $7700.00 Window Closed / Lapsed

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