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Crystalline silicates and hydrocarbon-conversion processes employing same

Assignee: Shell USA Inc
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Filing: 1979-10-10
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Granted: 1980-12-09
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Expires: 1999-10-10
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Abstract

Abstract Novel crystalline silicates which in dehydrated form have the composition in terms of moles of the oxides: (1.0±0.3)(R) 2/n O.[aFe 2 O 3 .bAl 2 O 3 .cGa 2 O 3 .y(dSiO 2 .eGeO 2 )], wherein R is one or more mono- or bivalent cations and a, b, c, d, e, y and n are as defined hereinafter are disclosed. The thermally stable silicates are suitably employed as extracting agents, drying agents, ion exchange agents, catalysts and catalyst carriers.

Inventors

  • 👤 Herman W. Kouwenhoven
  • 👤 Willem H. J. Stork

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 19:48
CPC Classifications
C; C07; C07C; C07C2/00; C07C2/86; C07C2/861; B; B01; B01J; B01J29/00; B01J29/88; B01J39/00; B01J39/08; B01J39/09; C01; C01B; C01B33/00; C01B33/20; C01B33/26; C01B33/28; C01B33/2807; C01B33/2884; C07C1/00; C07C1/02; C07C1/04; C07C1/0425; C07C1/043; C07C1/0435; C07C1/044; C07C1/20; C07C2/76; C07C2/862; C07C2/864; C07C2523/00; C07C2523/06; C07C2523/16; C07C2523/24; C07C2523/26; C07C2523/70; C07C2523/72; C07C2529/00; C07C2529/88; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52; Y10; Y10S; Y10S208/00; Y10S208/95

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 204 words
A process for the preparation of aromatic hydrocarbons which comprises contacting as feed at least one acyclic organic compound or a mixture of substantially acyclic organic compounds with shaped catalyst particles comprising from about 0-90% w of binder material and 10-100% w of crystalline silicates, which silicates are characterized in that: (a) they are thermally stable up to temperatures above 600° C.; (b) after dehydration in vacuum at 400° C. they are capable of absorbing more than 3% w water at 25° C. and saturated water vapor pressure; and (c) in the dehydrated form they have the following overall composition, in terms of moles of the oxides: (1.0±0.3)(R) 2/n O.[a Fe 2 O 3 .b Al 2 O 3 .c Ga 2 O 3 ].y(d SiO 2 .e GeO 2 ), where R=one or more monovalent or bivalent cations introduced during preparation of said silicates and selected from the group consisting of alkaline metals, alkaline earth metals and organic cations obtained from primary, secondary and tertiary alkylamines and quaternary ammonium compounds; a>0.5 b≧0; c≧0; a+b+c=1; y=10 to 300 d≧0.1; e≧0; d+e=1, n is the valency of R; and their X-ray diffraction patterns include, inter alia, the reflections given in Table A of this specification.
Claim 2
Dependent Claim 204 words
A process for the preparation of aromatic hydrocarbons which comprises contacting as feed at least one acyclic organic compound or a mixture of substantially acyclic organic compounds with shaped catalyst particles comprising from about 0-90% w of binder material and 10-100% w of crystalline silicates, which silicates are characterized in that: (a) they are thermally stable up to temperatures above 600° C.; (b) after dehydration in vacuum at 400° C. they are capable of absorbing more than 3% w water at 25° C. and saturated water vapor pressure; and (c) in the dehydrated form they have the following overall composition, in terms of moles of the oxides: (1.0±0.3)(R) 2/n O.[a Fe 2 O 3 .b Al 2 O 3 .c Ga 2 O 3 ].y(d SiO 2 .e GeO 2 ), where R=one or more monovalent or bivalent cations introduced during preparation of said silicates and selected from the group consisting of alkaline metals, alkaline earth metals and organic cations obtained from primary, secondary and tertiary alkylamines and quaternary ammonium compounds; a>0.5 b≧0; c≧0; a+b+c=1; y=10 to 300 d≧0.1; e≧0; d+e=1, n is the valency of R; and their X-ray diffraction patterns include, inter alia, the reflections given in Table A of this specification.
Claim 3
Dependent Claim 13 words
A process according to claim 1, wherein the acyclic organic compound is methanol.
Claim 4
Dependent Claim 18 words
A process according to claim 1, wherein the mixture of substantially acyclic organic compounds is a petroleum gasoline.
Claim 5
Dependent Claim 26 words
A process according to claim 1, wherein the mixture of substantially acyclic compounds is a product obtained in the hydrocarbon synthesis according to the Fischer-Tropsch Process.
Claim 6
Dependent Claim 19 words
A process according to claim 1 for the selective preparation of p-xylene wherein the acyclic organic compound is isobutene.
Claim 7
Dependent Claim 194 words
A hydrocarbon conversion process which comprises contacting a petroleum hydrocarbon fraction at an elevated temperature and pressure with shaped catalyst particles comprising from about 0-90% w of binder material and 10-100% w of crystalline silicates, which silicates are characterized in that; (a) they are thermally stable up to temperatures above 600° C.; (b) after dehydration in vacuum at 400° C. they are capable of absorbing more than 3% w water at 25° C. and saturated water vapor pressure; and (c) in the dehydrated form they have the following overall composition, in terms of moles of the oxides: (1.0±0.3)(R) 2/n O.[a Fe 2 O 3 .b Al 2 O 3 .c Ga 2 O 3 ].y(d SiO 2 .e GeO 2 ), where R=one or more monovalent or bivalent cations introduced during preparation of said silicates and selected from the group consisting of alkaline metals, alkaline earth metals and organic cations obtained from primary, secondary and tertiary alkylamines and quaternary ammonium compounds; a>0.5 b≧0; c≧0; a+b+c=1; y=10 to 300 d≧0.1; e≧0; d+e=1, n is the valency of R; and their X-ray diffraction patterns include, inter alia, the reflections given in Table A of this specification.
Claim 8
Dependent Claim 194 words
A hydrocarbon conversion process which comprises contacting a petroleum hydrocarbon fraction at an elevated temperature and pressure with shaped catalyst particles comprising from about 0-90% w of binder material and 10-100% w of crystalline silicates, which silicates are characterized in that; (a) they are thermally stable up to temperatures above 600° C.; (b) after dehydration in vacuum at 400° C. they are capable of absorbing more than 3% w water at 25° C. and saturated water vapor pressure; and (c) in the dehydrated form they have the following overall composition, in terms of moles of the oxides: (1.0±0.3)(R) 2/n O.[a Fe 2 O 3 .b Al 2 O 3 .c Ga 2 O 3 ].y(d SiO 2 .e GeO 2 ), where R=one or more monovalent or bivalent cations introduced during preparation of said silicates and selected from the group consisting of alkaline metals, alkaline earth metals and organic cations obtained from primary, secondary and tertiary alkylamines and quaternary ammonium compounds; a>0.5 b≧0; c≧0; a+b+c=1; y=10 to 300 d≧0.1; e≧0; d+e=1, n is the valency of R; and their X-ray diffraction patterns include, inter alia, the reflections given in Table A of this specification.
Claim 9
Dependent Claim 38 words
A process according to claim 6 for dewaxing of a gas oil distillate which comprises contacting said catalyst with a wax-containing gas oil distillate feed and separating a gas oil product having lower wax content than said feed.
Claim 10
Dependent Claim 42 words
A process according to claim 6 for the preparation of p-xylene which comprises contacting said catalyst with a hydrocarbon feed containing a mixture of isomeric C 8 aromatics and separating a hydrocarbon product having a p-xylene content higher than said hydrocarbon feed.

References Cited (Backward Citations)

GB1264545A Cited
DE2017807A1 Cited
US3702886A Cited
US3941871A Cited
US4039600A Cited
US4061724A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-12-09 1984-06-09 1984-12-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-12-09 1988-06-09 1988-12-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-12-09 1992-06-09 1992-12-09 $7700.00 Window Closed / Lapsed

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