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US4237193A Expired / Lapsed US ⏱️ 0.0 years remaining

Oxidation corrosion resistant superalloys and coatings

Assignee: General Electric Co
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Filing: 1978-06-16
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Granted: 1980-12-02
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Expires: 1998-06-16
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Abstract

Abstract An article of manufacture having improved high temperature oxidation and corrosion resistance comprising: (a) a superalloy substrate containing a carbide reinforcing phase, and (b) a coating consisting of chromium, aluminum, carbon, at least one element selected from iron, cobalt or nickel, and optionally an element selected from yttrium or the rare earth elements.

Inventors

  • 👤 Melvin R. Jackson
  • 👤 John R. Rairden, III

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:58
CPC Classifications
C; C23; C23C; C23C28/00; C23C28/02; C23C28/023; C23C30/00; C23C4/00; C23C4/04; C23C4/06; C23C4/073; Y; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12493; Y10T428/12736; Y10T428/1275; Y10T428/12757; Y10T428/12771; Y10T428/12861; Y10T428/12931; Y10T428/12937

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 100 words
An article of manufacture having improved high temperature oxidation and corrosion resistance comprising: (a) a superalloy substrate containing a carbide reinforcing phase, and (b) a coating consisting of chromium, aluminum, carbon and at least one element selected from iron, cobalt or nickel, subject to the proviso that the coatings contain an amount of carbon (1) sufficient to saturate any solid state phases of the coating composition, (2) sufficient to essentially equilibrate the chemical potential of carbon in the coating with that in the substrate with minimum interaction, and (3) insufficient to form substantial quantities of carbides in the coating composition.
Claim 2
Dependent Claim 100 words
An article of manufacture having improved high temperature oxidation and corrosion resistance comprising: (a) a superalloy substrate containing a carbide reinforcing phase, and (b) a coating consisting of chromium, aluminum, carbon and at least one element selected from iron, cobalt or nickel, subject to the proviso that the coatings contain an amount of carbon (1) sufficient to saturate any solid state phases of the coating composition, (2) sufficient to essentially equilibrate the chemical potential of carbon in the coating with that in the substrate with minimum interaction, and (3) insufficient to form substantial quantities of carbides in the coating composition.
Claim 3
Dependent Claim 116 words
An article of manufacture having improved high temperature oxidation and corrosion resistance comprising: (a) a superalloy substrate containing a carbide reinforcing phase; (b) a coating consisting of chromium, aluminum, carbon, and at least one element selected from iron, cobalt or nickel, subject to the proviso that the coatings contain an amount of carbon (1) sufficient to saturate any solid state phases of the coating composition, (2) sufficient to essentially equilibrate the chemical potential of carbon in the coating with that in the substrate with minimum interaction, and (3) insufficient to form substantial quantities of carbides in the coating composition; and (c) an aluminizing overcoating to further increase the oxidation and corrosion resistance of the coated substrate.
Claim 4
Dependent Claim 116 words
An article of manufacture having improved high temperature oxidation and corrosion resistance comprising: (a) a superalloy substrate containing a carbide reinforcing phase; (b) a coating consisting of chromium, aluminum, carbon, and at least one element selected from iron, cobalt or nickel, subject to the proviso that the coatings contain an amount of carbon (1) sufficient to saturate any solid state phases of the coating composition, (2) sufficient to essentially equilibrate the chemical potential of carbon in the coating with that in the substrate with minimum interaction, and (3) insufficient to form substantial quantities of carbides in the coating composition; and (c) an aluminizing overcoating to further increase the oxidation and corrosion resistance of the coated substrate.
Claim 5
Dependent Claim 126 words
A superalloy article of manufacture having improved high temperature oxidation and corrosion resistance selected from directionally solidified multivariant eutectic superalloys comprising a matrix of nickel or cobalt-base superalloy body, said matrix containing an aligned eutectic carbide reinforcing phase comprising (a) a superalloy substrate containing a carbide reinforcing phase; and (b) a coating consisting of chromium, aluminum, carbon, and at least one element selected from iron, cobalt, or nickel, subject to the proviso that the coatings contain an amount of carbon (1) sufficient to saturate any solid state phases of the coating composition, (2) sufficient to essentially equilibrate the chemical potential of carbon in the coating with that in the substrate with minimum interaction, and (3) insufficient to form substantial quantities of carbides in the coating composition.
Claim 6
Dependent Claim 126 words
A superalloy article of manufacture having improved high temperature oxidation and corrosion resistance selected from directionally solidified multivariant eutectic superalloys comprising a matrix of nickel or cobalt-base superalloy body, said matrix containing an aligned eutectic carbide reinforcing phase comprising (a) a superalloy substrate containing a carbide reinforcing phase; and (b) a coating consisting of chromium, aluminum, carbon, and at least one element selected from iron, cobalt, or nickel, subject to the proviso that the coatings contain an amount of carbon (1) sufficient to saturate any solid state phases of the coating composition, (2) sufficient to essentially equilibrate the chemical potential of carbon in the coating with that in the substrate with minimum interaction, and (3) insufficient to form substantial quantities of carbides in the coating composition.
Claim 7
Dependent Claim 18 words
The claim 3 article, wherein the coating contains an element selected from yttrium or the rare earth elements.
Claim 8
Dependent Claim 32 words
The claim 4 article, wherein the eutectic carbide reinforcing phase is selected from carbides of the group consisting of tantalum and vanadium and their alloys and mixtures thereof embedded in the matrix.
Claim 9
Dependent Claim 25 words
The claim 3, 4 or 5 article, further comprising (c) an aluminizing overcoating to further increase the oxidation and corrosion resistance of the coated substrate.

References Cited (Backward Citations)

CA710749A Cited
US3573963A Cited
US3754898A Cited
US4003765A Cited
US3873347A Cited
US4082581A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-12-02 1984-06-02 1984-12-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-12-02 1988-06-02 1988-12-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-12-02 1992-06-02 1992-12-02 $7700.00 Window Closed / Lapsed

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