Patent US4237024A successfully refreshed from Google Patents.
US4237024A
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Dishwashing composition and method of making the same
Assignee: Certified Chemicals Inc
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Filing: 1978-06-16
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Granted: 1980-12-02
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Expires: 1998-06-16
Abstract
Abstract A method of making a dishwashing composition and the composition so produced comprises mixing an aqueous solution of sodium hypochlorite with substantially dry ingredients including phosphates known as sequestering agents or builder salts and a carrier material. An alkali metal silicate is also added in substantially dry form and/or as an aqueous solution. Agitation is continued until agglomerated granules of the desired size are attained. Following agglomeration, the composition is conditioned to reduce the moisture content resulting in a substantially dry, granular dishwashing composition. Preferably, a low foam non-ionic surfactant is sprayed onto the granules before the composition is packaged.
Inventors
- 👤 Walter J. Fedechko
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 16:30
CPC Classifications
C; C11; C11D; C11D11/00; C11D11/0082; C11D3/00; C11D3/395; C11D3/3953
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
146 words
A method of making an agglomerated dishwashing composition comprising the steps of: (a) forming a composition mixture by mixing an aqueous solution of sodium hypochlorite at a rate of about 4 to about 25% per minute based on the total weight of any substantially dry ingredients in an amount sufficient to yield about 0.25 to about 1.6% available chlorine in the composition with at least one alkaline sequestrant builder salt, a water soluble carrier material and an alkali metal silicate having a SiO 2 to M 2 O ratio of about 1:1 to about 3.22:1 wherein M is at least one alkali metal; (b) agitating the composition mixture after adding the ingredients set forth in step (a) for a sufficient time to form agglomerated granules of the composition mixture; and (c) conditioning the agglomerated granules by reducing the moisture content of agglomerated granules by about 0.25-5%.
Claim 2
Independent Claim
146 words
A method of making an agglomerated dishwashing composition comprising the steps of: (a) forming a composition mixture by mixing an aqueous solution of sodium hypochlorite at a rate of about 4 to about 25% per minute based on the total weight of any substantially dry ingredients in an amount sufficient to yield about 0.25 to about 1.6% available chlorine in the composition with at least one alkaline sequestrant builder salt, a water soluble carrier material and an alkali metal silicate having a SiO 2 to M 2 O ratio of about 1:1 to about 3.22:1 wherein M is at least one alkali metal; (b) agitating the composition mixture after adding the ingredients set forth in step (a) for a sufficient time to form agglomerated granules of the composition mixture; and (c) conditioning the agglomerated granules by reducing the moisture content of agglomerated granules by about 0.25-5%.
Claim 3
Dependent Claim
74 words
A method according to claim 1 wherein the sequestrant builder salt is selected from the group consisting of sodium tripolyphosphate, trisodium phosphate, tetrasodium pyrophosphate, tetrapotassium pyrophosphate, sodium hexametaphosphate and mixtures thereof; the carrier material is selected from the group consisting of sodium chloride, potassium chloride, sodium carbonate, potassium carbonate, sodium sulfate, potassium sulfate, sodium bicarbonate, borax and mixtures thereof; and wherein M is selected from the group consisting of sodium, potassium and mixtures thereof.
Claim 4
Dependent Claim
52 words
A method according to claim 1 wherein the sequestrant builder salt is present in an amount of about 30 to about 47%, the carrier material is present in an amount of about 25 to about 40%, and the alkali metal silicate is present in an amount of about 6 to about 24%.
Claim 5
Dependent Claim
19 words
A method according to claim 1 further comprising spraying a low foam nonionic surfactant on the conditioned agglomerated granules.
Claim 6
Dependent Claim
88 words
A method according to claim 1 wherein the sequestrant builder salt is about 25 to about 35% sodium tripolyphosphate and about 5 to about 12% trisodium phosphate, the carrier material is about 25 to about 40% sodium chloride, the alkali metal silicate is about 6 to about 24% of silicate selected from the group consisting of sodium silicate, potassium silicate and mixtures thereof, and the aqueous solution of sodium hypochlorite is present in a sufficient amount to yield about 0.4 to about 1.2% available chlorine in the composition.
Claim 7
Dependent Claim
20 words
A method according to claim 5 wherein agitating step (b) is continued for about 10 seconds to about 5 minutes.
Claim 8
Dependent Claim
28 words
A method according to claim 1 wherein a sufficient amount of the aqueous solution of sodium hypochlorite is used to yield about 1% available chlorine in the composition.
Claim 9
Dependent Claim
161 words
A method according to claim 1 wherein a sufficient amount of the aqueous solution of sodium hypochlorite is used to yield about 1% available chlorine in the composition and is added at a rate of about 12% per minute based on the total weight of any substantially dry ingredients, the sequestrant builder salt is about 30% sodium tripolyphosphate and about 7% trisodium phosphate, the carrier material is about 34.5% sodium chloride, the alkali metal silicate is present in an amount of about 9.6% derived from about 1.6% of substantially dry alkali metal silicate and about 8% derived from the aqueous solution of alkali metal silicate and is selected from the group consisting of sodium silicate, potassium silicate and mixtures thereof having a SiO 2 :M 2 O ratio of about 2.4:1 wherein M is selected from the group consisting of sodium, potassium and mixtures thereof, the method further comprising spraying about 2% low foam nonionic surfactant on the conditioned agglomerated granules.
Claim 10
Dependent Claim
16 words
A method according to claim 1 wherein the alkali metal silicate is a substantially dry ingredient.
Claim 11
Dependent Claim
32 words
A method according to claim 9 wherein the sequestrant builder salt, the carrier material and the alkali metal silicate are premixed together to form a relatively homogeneous mixture of substantially dry ingredients.
Claim 12
Dependent Claim
19 words
A method according to claim 1 wherein the alkali metal silicate is in the form of an aqueous solution.
Claim 13
Dependent Claim
66 words
A method according to claim 11 wherein the aqueous solution of sodium hypochlorite is mixed with the aqueous solution of alkali metal silicate to form a mixed solution, the mixed solution being mixed with the sequestrant builder salt and the carrier material at a rate of about 4 to about 25% per minute based on the weight of the sequestrant builder salt and the carrier material.
Claim 14
Dependent Claim
18 words
A method according to claim 12 wherein the sequestrant builder salt and the carrier material are premixed together.
Claim 15
Dependent Claim
81 words
A method according to claim 1 wherein a portion of the alkali metal silicate is present in substantially dry form and another portion of the alkali metal silicate is present in the form of an aqueous solution, the aqueous solution of alkali metal silicate being mixed with the aqueous solution of sodium hypochlorite to form a mixed solution and the mixed solution is added to the sequestrant builder salt, the carrier material and the substantially dry portion of alkali metal silicate.
Claim 16
Independent Claim
226 words
A method of making a dishwashing composition comprising the steps of: (a) mixing together substantially dry ingredients including about 30% to about 47% alkaline sequestrant builder salt, about 25% to about 40% water soluble carrier material and alkali metal silicate selected from the group consisting of sodium silicate, potassium silicate and mixtures thereof having a SiO 2 :M 2 O ratio of about 1:1 to about 3.22:1 wherein M is selected from the group consisting of sodium, potassium and mixtures thereof; (b) mixing together liquid ingredients including an aqueous solution of sodium hypochlorite sufficient to yield about 0.25% to about 1.6% available chlorine in the composition and an aqueous solution of alkali metal silicate selected from the group consisting of sodium silicate, potassium silicate and mixtures thereof, whereby the composition will contain a total of about 6% to about 24% alkali metal silicate from the substantially dry and liquid alkali metal silicate ingredients; (c) adding the mixed liquid ingredients to said mixed substantially dry ingredients at a rate of about 4% per minute to about 25% per minute based on the weight of said mixed substantially dry ingredients to form the composition mixture; (d) agitating the composition mixture after completing the addition step (c) to form agglomerated granules of the composition mixture; and (e) conditioning the agglomerated granules by reducing their moisture content by about 0.25-5%.
Claim 17
Independent Claim
226 words
A method of making a dishwashing composition comprising the steps of: (a) mixing together substantially dry ingredients including about 30% to about 47% alkaline sequestrant builder salt, about 25% to about 40% water soluble carrier material and alkali metal silicate selected from the group consisting of sodium silicate, potassium silicate and mixtures thereof having a SiO 2 :M 2 O ratio of about 1:1 to about 3.22:1 wherein M is selected from the group consisting of sodium, potassium and mixtures thereof; (b) mixing together liquid ingredients including an aqueous solution of sodium hypochlorite sufficient to yield about 0.25% to about 1.6% available chlorine in the composition and an aqueous solution of alkali metal silicate selected from the group consisting of sodium silicate, potassium silicate and mixtures thereof, whereby the composition will contain a total of about 6% to about 24% alkali metal silicate from the substantially dry and liquid alkali metal silicate ingredients; (c) adding the mixed liquid ingredients to said mixed substantially dry ingredients at a rate of about 4% per minute to about 25% per minute based on the weight of said mixed substantially dry ingredients to form the composition mixture; (d) agitating the composition mixture after completing the addition step (c) to form agglomerated granules of the composition mixture; and (e) conditioning the agglomerated granules by reducing their moisture content by about 0.25-5%.
Claim 18
Dependent Claim
46 words
A method according to claim 15 wherein the total amount of alkali metal silicate in the composition is derived from about 1% to about 10% of the substantially dry alkali metal silicate and about 5% to about 14% of the aqueous solution of alkali metal silicate.
Claim 19
Dependent Claim
25 words
A method according to claim 15 further comprising spraying about 1% to about 4% of a low foam nonionic surfactant on the conditioned agglomerated granules.
Claim 20
Dependent Claim
79 words
A method according to claim 17 wherein the sequestrant builder salt is selected from the group consisting of sodium tripolyphosphate, trisodium phosphate, tetrasodium pyrophosphate, tetrapotassium pyrophosphate, sodium hexametaphosphate and mixtures thereof; the carrier material is selected from the group consisting of sodium chloride, potassium chloride, sodium carbonate, potassium carbonate, sodium sulfate, potassium sulfate, sodium bicarbonate, borax and mixtures thereof; and said agitating step (d) continues for about 10 seconds to about 5 minutes after completing the addition step (c).
Claim 21
Dependent Claim
95 words
A method according to claim 18 wherein the sequestrant builder salt is about 25% to about 35% sodium tripolyphosphate and about 5% to about 12% trisodium phosphate, the carrier material is sodium chloride, the aqueous solution of sodium hypochlorite is present in an amount to yield about 0.4% to about 1.2% available chlorine in the composition, and the total amount of alkali metal silicate in the composition is derived from about 1% to about 10% substantially dry alkali metal silicate and from about 5% to about 14% of the aqueous solution of alkali metal silicate.
Claim 22
Dependent Claim
162 words
A method according to claim 17 wherein said sequestrant builder salt includes about 30% sodium tripolyphosphate and about 7% trisodium phosphate, said carrier material so includes about 34.5% sodium chloride, the total amount of alkali metal silicate in the composition is about 9.6% derived from about 1.6% of substantially dry sodium silicate and about 8% derived from an aqueous solution of sodium silicate, said sodium silicate having a SiO 2 :Na 2 O ratio of about 2.4:1, the mixed liquid ingredients are added to the mixed substantially dry ingredients at a rate of about 12% per minute based on the weight of the mixed substantially dry ingredients, the the composition mixture is agitated for about one minute after completing the addition of the liquid ingredients to the substantially dry ingredients, the moisture content of the composition is reduced from about 15% to about 14%, and about 2% of a low foam nonionic surfactant is sprayed on the conditioned particles of the composition.
Claim 23
Dependent Claim
14 words
A dishwashing composition made according to the method of any one of claims 1-20.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-12-02 | 1984-06-02 | 1984-12-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-12-02 | 1988-06-02 | 1988-12-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-12-02 | 1992-06-02 | 1992-12-02 | $7700.00 | Window Closed / Lapsed |