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US4235835A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermosetting compositions for injection molding

Assignee: Union Carbide Corp
•
Filing: 1979-11-29
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Granted: 1980-11-25
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Expires: 1999-11-29
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Abstract

Abstract Vulcanizable ethylene-vinyl acetate compositions, a process for preparing thermoset products by injection molding and crosslinking said compositions, and the articles of manufacture produced therefrom.

Inventors

  • 👤 Gary L. Stutzman
  • 👤 Carlo F. Martino

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 09:29
CPC Classifications
C; C08; C08K; C08K9/00; C08K9/04; C08K9/06; C08K13/00; C08K13/08; C08K3/00; C08K3/34; C08K3/346; C08K5/00; C08K5/04; C08K5/14; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L31/00; C08L31/02; C08L31/04

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 311 words
A process for preparing a thermoset injection molded product having a hot tensile strength of at least 250 pounds per square inch when measured according to ASTM D412-64T at the mold temperature employed in said process, which process comprises the steps of: injecting a vulcanizable composition into a preheated mold, said mold having been preheated to a temperature sufficient to crosslink said vulcanizable composition within five minutes, said composition consisting essentially of about 35 to about 75 parts by weight of (A) an ethylene-vinyl acetate copolymer containing about 7 to about 55 weight percent of vinyl acetate based on the total weight of said copolymer; about 65 to about 25 parts by weight of (B) a clay filler selected from the class consisting of an organosilane treated clay and an organopolyester treated clay wherein said organopolyester is reaction product of polyfunctional organic carboxylic acid and/or polyfunctional organic carboxylic acid anhydride with polyhydric alcohol; the sum of (A)+(B) being about 100 parts by weight in the composition; about 1 to about 5 parts by weight based on the sum of (A)+(B) of (C) an organic peroxide crosslinking agent having a half-life at its stock temperature of greater than one hour; and 0 to about 5 parts by weight based on the sum of (A)+(B) of (D) of an organic crosslinking booster; wherein said components (A), (B), (C) and (D) are such that a crosslinked product obtained upon crosslinking an admixture containing only said components (A), (B), (C) and (D) in the same proportions as (A), (B), (C) and (D) are present in said vulcanizable composition, has a hot tensile strength of at least 250 pounds per square inch when measured according to ASTM D412-64T at the same temperature employed to crosslink said admixture; crosslinking said composition in said mold, and recovering the thermoset injected molded product by removing it from said mold.
Claim 2
Dependent Claim 311 words
A process for preparing a thermoset injection molded product having a hot tensile strength of at least 250 pounds per square inch when measured according to ASTM D412-64T at the mold temperature employed in said process, which process comprises the steps of: injecting a vulcanizable composition into a preheated mold, said mold having been preheated to a temperature sufficient to crosslink said vulcanizable composition within five minutes, said composition consisting essentially of about 35 to about 75 parts by weight of (A) an ethylene-vinyl acetate copolymer containing about 7 to about 55 weight percent of vinyl acetate based on the total weight of said copolymer; about 65 to about 25 parts by weight of (B) a clay filler selected from the class consisting of an organosilane treated clay and an organopolyester treated clay wherein said organopolyester is reaction product of polyfunctional organic carboxylic acid and/or polyfunctional organic carboxylic acid anhydride with polyhydric alcohol; the sum of (A)+(B) being about 100 parts by weight in the composition; about 1 to about 5 parts by weight based on the sum of (A)+(B) of (C) an organic peroxide crosslinking agent having a half-life at its stock temperature of greater than one hour; and 0 to about 5 parts by weight based on the sum of (A)+(B) of (D) of an organic crosslinking booster; wherein said components (A), (B), (C) and (D) are such that a crosslinked product obtained upon crosslinking an admixture containing only said components (A), (B), (C) and (D) in the same proportions as (A), (B), (C) and (D) are present in said vulcanizable composition, has a hot tensile strength of at least 250 pounds per square inch when measured according to ASTM D412-64T at the same temperature employed to crosslink said admixture; crosslinking said composition in said mold, and recovering the thermoset injected molded product by removing it from said mold.
Claim 3
Dependent Claim 70 words
The process of claim 1, wherein the ethylene-vinyl acetate copolymer contains from about 10 to about 35 weight percent of vinyl acetate based on the weight of the copolymer, wherein the clay filler is an organosilane treated clay, and wherein the amount ratio of (A) to (B) ranges from about 40 to about 65 parts by weight of (A) to about 60 to about 35 parts by weight of (B).
Claim 4
Dependent Claim 14 words
The process of claim 2, wherein the organic peroxide crosslinking agent is 1,1-bis(t-butylperoxy)-3,3,5-trimethyl cyclohexane.
Claim 5
Dependent Claim 17 words
The process of claim 2, wherein the organosilane treated filler is vinyltris (2-methoxyethoxy) silane treated calcined clay.
Claim 6
Dependent Claim 13 words
The process of claim 3, wherein the crosslinking booster is trimethylol propane trimethacrylate.
Claim 7
Dependent Claim 51 words
The process of claim 2, wherein the ethylene-vinyl acetate copolymer contains about 28 weight percent vinyl acetate and has a melt index of about 20, and wherein the amount of ratio of (A) to (B) is about 60 parts by weight of (A) to about 40 parts by weight of (B).
Claim 8
Dependent Claim 36 words
The process of claim 6, wherein the organic peroxide crosslinking agent is present in an amount of about 1.5 parts by weight based on the sum of (A)+(B) and wherein said organic peroxide is 1,1-bis(t-butylperoxy)-3,3,5-trimethyl cyclohexane.
Claim 9
Dependent Claim 17 words
The process of claim 7, wherein the organosilane treated filler is vinyltris (2-methoxyethoxy) silane treated calcined clay.
Claim 10
Dependent Claim 14 words
The process of claim 8, wherein the organic crosslinking booster is trimethylol propane trimethacrylate.
Claim 11
Dependent Claim 27 words
The process of claim 9, wherein the organic crosslinking booster is present in an amount of about 2.5 parts by weight based on the sum of (A)+(B).
Claim 12
Dependent Claim 23 words
The process of claim 1, wherein said mold has been preheated to a temperature sufficient to crosslink the composition in about three minutes.
Claim 13
Dependent Claim 29 words
The process of claim 1, wherein warm runner injection molding is employed, the runner being maintained at about the same temperature as the stock temperature of the vulcanizable composition.

References Cited (Backward Citations)

US3425980A Cited
US3812228A Cited
US3922442A Cited
US3923731A Cited
US3957719A Cited
US3959433A Cited
US3979180A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-11-25 1984-05-26 1984-11-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-11-25 1988-05-26 1988-11-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-11-25 1992-05-26 1992-11-25 $7700.00 Window Closed / Lapsed

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