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Patent US4235709A successfully refreshed from Google Patents.
US4235709A
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Selective flocculation process for treating fines of phosphate ores
Assignee: Bureau de Recherches Géologiques et Minières
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Filing: 1978-08-02
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Granted: 1980-11-25
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Expires: 1998-08-02
Abstract
Abstract A selective flocculation process is provided for the treatment of phosphate ores formed essentially of apatite and a mixture of silicate minerals, for the separation and valorization, i.e., recovery, of the fines, particularly of the fractions whose particle size is less than about 40 mu m. The process comprises the following sequence of three steps: (a) a first step of conditioning the ore by contacting the particles of the ore pulp with a conditioning agent such as sodium silicate; (b) a second step of flocculation with the selective formation of apatite agglomerates, by diluting the pulp resulting from the first step with water and by adding thereto a flocculation agent constituted by a water-soluble anionic polymer capable of being fixed only on the apatite particles, said flocculation agent being essentially selected from among cellulose derivatives, starches and polysaccharides generally, comprising carboxyl groups; (c) a third step of separation by sedimentation and precipitation operations of the dispersed minerals and of the flocculated material, which is constituted essentially of apatite, the latter then being recovered directly, the separation being effected on said flocculated material only to a cut-off dimension of about 40 mu m.
Inventors
- 👤 Gerard Baudet
- 👤 Michel Morio
- 👤 Christian Vautrelle
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 07:00
CPC Classifications
B; B01; B01D; B01D21/00; B01D21/01; C; C01; C01B; C01B25/00; C01B25/16; C01B25/26; C01B25/32
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
200 words
Selective flocculation process for the recovery treatment of phosphate ore fractions having fine granulometry, said fractions being formed essentially of apatite and a mixture of silicate materials, particularly of the fractions whose particle size is less than about 40 μm, said process comprising the following sequence of three steps: (a) a first step of conditioning said fractions by contacting the particles of the ore pulp with a conditioning agent to form a dispersion; (b) a second step of flocculation with the selective formation of apatite agglomerates, by diluting the pulp resulting from the first step with water and by adding thereto a flocculation agent constituted by a watersoluble anionic polymer capable of being fixed only on the apatite particles, said flocculation agent being selected from the group consisting of derivatives of cellulose, starches, and polysaccharides containing carboxyl groups; and (c) a third step of separation by sedimentation and precipitation operations of the dispersed minerals and of the flocculated material, which flocculated material is constituted essentially of apatite, the latter then being recovered directly, the separation being carried out to recover flocculated material having a particle size equal to or greater than a cut-off size comprised between 30 and 100 μm.
Claim 2
Dependent Claim
200 words
Selective flocculation process for the recovery treatment of phosphate ore fractions having fine granulometry, said fractions being formed essentially of apatite and a mixture of silicate materials, particularly of the fractions whose particle size is less than about 40 μm, said process comprising the following sequence of three steps: (a) a first step of conditioning said fractions by contacting the particles of the ore pulp with a conditioning agent to form a dispersion; (b) a second step of flocculation with the selective formation of apatite agglomerates, by diluting the pulp resulting from the first step with water and by adding thereto a flocculation agent constituted by a watersoluble anionic polymer capable of being fixed only on the apatite particles, said flocculation agent being selected from the group consisting of derivatives of cellulose, starches, and polysaccharides containing carboxyl groups; and (c) a third step of separation by sedimentation and precipitation operations of the dispersed minerals and of the flocculated material, which flocculated material is constituted essentially of apatite, the latter then being recovered directly, the separation being carried out to recover flocculated material having a particle size equal to or greater than a cut-off size comprised between 30 and 100 μm.
Claim 3
Dependent Claim
14 words
Process according to claim 1, wherein said conditioning agent is constituted by sodium silicate.
Claim 4
Dependent Claim
35 words
Process according to claim 2, wherein sodium silicate is used having a ratio SiO 2 /Na 2 O of about 3.5, such a silicate having in aqueous solution a density in the vicinity of 1.33.
Claim 5
Dependent Claim
22 words
Process according to claim 1, wherein the duration of said first step (a) is of the order of 0.5 to 3 minutes.
Claim 6
Dependent Claim
26 words
Process according to claim 1, wherein in said first step (a), a stirrer is used with a mechanical dispersing effect, capable of well individualizing the particles.
Claim 7
Dependent Claim
25 words
Process according to claim 1, wherein in said first step (a), the concentration of solid material is in the order of 150 to 250 g/liter.
Claim 8
Dependent Claim
36 words
Process according to claim 1, wherein in the case of treating phosphate ores with a siliceous gangue, the pH is adjusted in the course of the first step (a) to values comprised between 6 and 10.
Claim 9
Dependent Claim
24 words
Process according to claim 7, wherein said pH is adjusted to about 9, by the addition of a basic agent constituted by sodium hydroxide.
Claim 10
Dependent Claim
42 words
Process according to claim 1, wherein before operating the flocculation provided in the second step (b), the pulp derived from the first step (a) is diluted with water to bring it to a concentration of the order of 50 to 100 g/liter.
Claim 11
Dependent Claim
26 words
Process according to claim 1, wherein as a flocculation agent, there is used cellulose or a modified starch, such as carboxymethyl modified cellulose or carboxymethyl starch.
Claim 12
Dependent Claim
47 words
Process according to claim 1, wherein the dose of the flocculation agent to be added in the course of the second step (b) is of the order of 0.1 to 8 kg/ton, of pulp, the calculation being with respect to the dry matter content of the latter.
Claim 13
Dependent Claim
19 words
Process according to claim 11, wherein said dose of flocculation agent is from 0.1 to 5 kg/t of pulp.
Claim 14
Dependent Claim
20 words
Process according to claim 1, wherein in the course of the second step (b), moderate conditions of stirring are used.
Claim 15
Dependent Claim
24 words
Process according to claim 1, wherein the duration of the flocculation treatment in the second step (b) is in the order of 1 minute.
Claim 16
Dependent Claim
134 words
The process according to claim 1, wherein for the separation in accordance with the third step (c), two successive operations of decantation-sedimentation are carried out, by operating in the course of the first operation with an initial concentration of the order of 50 g/liter and by separating by decantation the particles of flocculated material of granulometry higher than 40 μm from those of granulometry less than 40 μm, which latter particles are discarded, and by operating in the course of the second operation with the fraction of particles of flocculated material of granulometry higher than 40 μm diluted to a concentration of about 25 g/liter and by separating the final phosphate concentrate constituted by the particles of flocculated material of granulometry higher than 40 μm from the ones of granulometry less than 40 μm.
Claim 17
Dependent Claim
40 words
Process according to claim 15, wherein the product emerging from the first decantation is rewashed and diluted to a concentration of the order of 25 g/liter, following which a second sedimentation operation is carried out which provides the final concentrate.
Claim 18
Dependent Claim
182 words
A selective flocculation process for the treatment of fine fractions of phosphate ore comprised of apatite and a mixture of silicate minerals, the fine fractions being comprised of particles having a particle size less than about 40 μm, comprising the steps of: (a) conditioning the ore by contacting under agitation the particles of the ore pulp with a conditioning agent comprising sodium silicate, the concentration of solid material in the pulp being from about 150 to 250 g/liters, to form a dispersion; (b) diluting the pulp from step (a) with water to a concentration of solid material from about 50 to 100 g/liter and adding thereto under agitation a flocculation agent comprised of water-soluble anionic polymer capable of being fixed on the apatite particles, said flocculation agent being selected from the group consisting of derivatives of cellulose, starches, and polysaccharides containing carboxyl groups, to selectively form apatite agglomerates; and (c) subjecting the mixture from step (b) to decantation and sedimentation to recover apatite agglomerates having a particle size equal to or greater than a cut-off size comprised between 30 and 100 μm.
Claim 19
Dependent Claim
182 words
A selective flocculation process for the treatment of fine fractions of phosphate ore comprised of apatite and a mixture of silicate minerals, the fine fractions being comprised of particles having a particle size less than about 40 μm, comprising the steps of: (a) conditioning the ore by contacting under agitation the particles of the ore pulp with a conditioning agent comprising sodium silicate, the concentration of solid material in the pulp being from about 150 to 250 g/liters, to form a dispersion; (b) diluting the pulp from step (a) with water to a concentration of solid material from about 50 to 100 g/liter and adding thereto under agitation a flocculation agent comprised of water-soluble anionic polymer capable of being fixed on the apatite particles, said flocculation agent being selected from the group consisting of derivatives of cellulose, starches, and polysaccharides containing carboxyl groups, to selectively form apatite agglomerates; and (c) subjecting the mixture from step (b) to decantation and sedimentation to recover apatite agglomerates having a particle size equal to or greater than a cut-off size comprised between 30 and 100 μm.
Claim 20
Dependent Claim
19 words
Process according to claim 17, wherein the pH of the pulp in step (a) is from 6 to 10.
Claim 21
Dependent Claim
24 words
Process according to claim 17, wherein the sodium silicate used in step (a) has a SiO 2 /Na 2 O ratio of about 3.5.
Claim 22
Dependent Claim
24 words
Process according to claim 17, wherein the conditioning agent is present in an amount of from 7.5 to 15 kg per ton of ore.
Claim 23
Dependent Claim
24 words
Process according to claim 17, wherein in step (a) the ore particles are contacted with conditioning agent for from 30 seconds to 3 minutes.
Claim 24
Dependent Claim
19 words
Process according to claim 17, wherein the pH of the pulp in step (b) is from 6 to 10.
Claim 25
Dependent Claim
16 words
Process according to claim 17, wherein the flocculation agent is carboxymethyl modified cellulose or carboxymethyl starch.
Claim 26
Dependent Claim
27 words
Process according to claim 17, wherein the flocculation agent is present in an amount of from 0.1 to 8 kg per ton of ore in the pulp.
Claim 27
Dependent Claim
19 words
Process according to claim 17, wherein the duration of the flocculation treatment in step (b) is about 1 minute.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-11-25 | 1984-05-26 | 1984-11-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-11-25 | 1988-05-26 | 1988-11-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-11-25 | 1992-05-26 | 1992-11-25 | $7700.00 | Window Closed / Lapsed |