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Process for the manufacture of coarse aluminum hydroxide

Assignee: Rio Tinto Switzerland AG
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Filing: 1979-10-24
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Granted: 1980-11-18
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Expires: 1999-10-24
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Abstract

Abstract Process for the manufacture of coarse aluminum hydroxide, containing a maximum of 15 weight percent of the particles in a particle size under 45 micrometers, with a productivity that may be higher than 60 grams of precipitated Al2O3. The process consists of a decomposition in two stages (an agglomeration phase and a growth phase); each stage proceeding within defined temperature ranges with seed material of different constitution. The first (fine) seed amount is added at the start of the decomposition in such an amount, that the ratio of the supersaturation of the aluminate liquor to the surface area of the seed hydroxide per liter of the aluminate liquor presented for decomposition exhibits a value of 7 to 25 grams per square meter. The process exhibits the advantage of the high productivity of the so-called European process and the advantage of the so-called American process by obtaining a coarse product hydroxide.

Inventors

  • 👤 Otto Tschamper

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 06:58
CPC Classifications
C; C01; C01F; C01F7/00; C01F7/02; C01F7/04; C01F7/14; C01F7/144; C01P; C01P2004/00; C01P2004/60; C01P2004/61; C01P2006/00; C01P2006/12

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 254 words
A process for the manufacture of coarse aluminum hydroxide having a maximum of 15 weight percent of particles with a diameter less than 45 micrometers by a two stage decomposition of a supersaturated alkaline aluminate solution, by the addition of aluminum hydroxide seed material of different quality to said aluminate solution in each of said two stages, which comprises (a) distributing the quantity of aluminum hydroxide seed material as follows: adding to said aluminate solution a first addition of fine seed material (primary seed material) in a first stage of the decomposition, where the quantity thereof is so calculated that the ratio between the supersaturation in grams of Al 2 O 3 per liter of aluminate liquor and the surface area of said seed material expressed in square meters per liter of aluminate liquor lies between 7 and 25 grams per square meter; and adding to said aluminate solution a second addition of coarse seed material (secondary seed material) in a second stage of the decomposition after an interval of approximately two hours after the first addition such that the total amount of seed material (primary and secondary seed material) is at least 130 grams Al(OH) 3 per liter of aluminate liquor; and (b) regulating the temperature of the decomposition in the following manner: conducting said first stage of the decomposition in a temperature range of 77 degrees Celsius to 66 degrees Celsius; and conducting said second stage of the decomposition at a reduced temperature which can be down to approximately 40 degrees Celsius.
Claim 2
Dependent Claim 254 words
A process for the manufacture of coarse aluminum hydroxide having a maximum of 15 weight percent of particles with a diameter less than 45 micrometers by a two stage decomposition of a supersaturated alkaline aluminate solution, by the addition of aluminum hydroxide seed material of different quality to said aluminate solution in each of said two stages, which comprises (a) distributing the quantity of aluminum hydroxide seed material as follows: adding to said aluminate solution a first addition of fine seed material (primary seed material) in a first stage of the decomposition, where the quantity thereof is so calculated that the ratio between the supersaturation in grams of Al 2 O 3 per liter of aluminate liquor and the surface area of said seed material expressed in square meters per liter of aluminate liquor lies between 7 and 25 grams per square meter; and adding to said aluminate solution a second addition of coarse seed material (secondary seed material) in a second stage of the decomposition after an interval of approximately two hours after the first addition such that the total amount of seed material (primary and secondary seed material) is at least 130 grams Al(OH) 3 per liter of aluminate liquor; and (b) regulating the temperature of the decomposition in the following manner: conducting said first stage of the decomposition in a temperature range of 77 degrees Celsius to 66 degrees Celsius; and conducting said second stage of the decomposition at a reduced temperature which can be down to approximately 40 degrees Celsius.
Claim 3
Dependent Claim 18 words
A process according to claim 1 wherein the time of the first decomposition stage is about six hours.
Claim 4
Dependent Claim 28 words
A process according to claim 1 wherein the caustic liquor concentration expressed in grams of Na 2 O caustic per liter is at least 100 grams per liter.
Claim 5
Dependent Claim 20 words
A process according to claim 1 including the step of continuously applying cooling at said second stage of the decomposition.
Claim 6
Dependent Claim 24 words
A process according to claim 1 including the step of applying cooling at the second stage of the decomposition in one or more steps.
Claim 7
Dependent Claim 30 words
A process according to claim 1 including applying cooling at said second stage of the decomposition and adding said coarse seed material immediately before, during, or immediately after said cooling.
Claim 8
Dependent Claim 32 words
A process according to claim 1 wherein the ratio of supersaturation of the liquor to the surface area of the primary seed material is between 7 and 16 grams per square meter.
Claim 9
Dependent Claim 23 words
A process according to claim 1 wherein the total amount of seed in said second stage does not exceed 400 grams per liter.
Claim 10
Dependent Claim 16 words
A process according to claim 1 wherein said secondary seed material is added at one time.
Claim 11
Dependent Claim 19 words
A process according to claim 1 including the step of applying cooling following said first stage of the decomposition.

References Cited (Backward Citations)

US2657978A Cited
US2707669A Cited
FR1391596A Cited
US3486850A Cited
US3649184A Cited
US3906084A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-11-18 1984-05-19 1984-11-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-11-18 1988-05-19 1988-11-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-11-18 1992-05-19 1992-11-18 $7700.00 Window Closed / Lapsed

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