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US4234466A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for preparation of solid pigment resin dispersion

Assignee: ROSPATCH Corp A MICHIGAN CORP
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Filing: 1977-12-01
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Granted: 1980-11-18
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Expires: 1997-12-01
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Abstract

Abstract A process for preparing a solid pigment dispersed composition which comprises subjecting a liquid composition comprising at least one ethylenically unsaturated polymerizable compound, at least one resin dissolved or dispersed therein and at least one pigment dispersed therein to suspension or bulk polymerization, if necessary, with previous color matching.

Inventors

  • 👤 Mitsuru Takahashi
  • 👤 Yukio Omori
  • 👤 Shuji Ikeda
  • 👤 Hiroyoshi Kataoka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 14:26
CPC Classifications
C; C09; C09D; C09D17/00

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 212 words
A process for preparing a solid pigment dispersed composition which comprises subjecting A. a liquid composition comprising: i. at least one ethylenically unsaturated polymerizable compound selected from the group consisting of monovinyl aromatic hydrocarbons, ethylenically unsaturated carboxylic esters, acrylonitrile, methacrylonitrile, glycidyl vinyl compounds, ethylenically unsaturated compounds having at least one hydroxyl group, ethylenically unsaturated carboxylic acids, ethylenically unsaturated amides and ethylenically unsaturated compounds having at least one blocked isocyanate group, and ii. at least one resin dissolved or dispersed therein, said resin being selected from the group consisting of natural resins, rosin esters, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cellulose methyl ether, cellulose ethyl ether, xylene resins, toluene resins, petroleum resins, silicon resins, polyurethane resins, phenol resins, aminoplast resins, epoxy resins, blocked polyisocyanate resins, acrylic resins, methacrylic resins and alkyd resins having at least one mercapto group to be grafted with the ethylenically unsaturated compound, and B. at least one pigment dispersed in said liquid composition, to suspension or bulk polymerization to form a reaction mixture and recovering the product from suspension or bulk polymerization reaction mixture, the suspension polymerization being performed in the presence of a suspension stabilizer to produce a spherical particulate product, said liquid composition being color matched to said pigment before said suspension or bulk polymerization.
Claim 2
Dependent Claim 212 words
A process for preparing a solid pigment dispersed composition which comprises subjecting A. a liquid composition comprising: i. at least one ethylenically unsaturated polymerizable compound selected from the group consisting of monovinyl aromatic hydrocarbons, ethylenically unsaturated carboxylic esters, acrylonitrile, methacrylonitrile, glycidyl vinyl compounds, ethylenically unsaturated compounds having at least one hydroxyl group, ethylenically unsaturated carboxylic acids, ethylenically unsaturated amides and ethylenically unsaturated compounds having at least one blocked isocyanate group, and ii. at least one resin dissolved or dispersed therein, said resin being selected from the group consisting of natural resins, rosin esters, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cellulose methyl ether, cellulose ethyl ether, xylene resins, toluene resins, petroleum resins, silicon resins, polyurethane resins, phenol resins, aminoplast resins, epoxy resins, blocked polyisocyanate resins, acrylic resins, methacrylic resins and alkyd resins having at least one mercapto group to be grafted with the ethylenically unsaturated compound, and B. at least one pigment dispersed in said liquid composition, to suspension or bulk polymerization to form a reaction mixture and recovering the product from suspension or bulk polymerization reaction mixture, the suspension polymerization being performed in the presence of a suspension stabilizer to produce a spherical particulate product, said liquid composition being color matched to said pigment before said suspension or bulk polymerization.
Claim 3
Dependent Claim 27 words
The process according to claim 1, wherein the resin is an alkyd resin having at least one mercapto group to be grafted with the ethylenically unsaturated compound.
Claim 4
Dependent Claim 27 words
The process according to claim 1, wherein the mercapto group is the one introduced by reacting a hydroxyl group with the carboxyl group in a mercaptocarboxylic acid.
Claim 5
Dependent Claim 13 words
The process according to claim 1, wherein the mercaptocarboxylic acid is thioglycollic acid.
Claim 6
Dependent Claim 32 words
The process according to claim 1, wherein the ethylenically unsaturated compound is used in an amount of 27 to 96% by weight on the basis of the weight of the liquid composition.
Claim 7
Dependent Claim 30 words
The process according to claim 1, wherein the resin is used in an amount of 3 to 60% by weight on the basis of the weight of the liquid composition.
Claim 8
Dependent Claim 30 words
The process according to claim 1, wherein the pigment is used in an amount of 1 to 70% by weight on the basis of the weight of the liquid composition.
Claim 9
Dependent Claim 12 words
The process according to claim 1, wherein the polymerization is suspension polymerization.
Claim 10
Dependent Claim 19 words
The process according to claim 1, wherein the polymerization is carried out in the presence of a polymerization initiator.
Claim 11
Dependent Claim 20 words
The process according to claim 9, wherein the polymerization is carried out in the presence of a chain transfer agent.
Claim 12
Dependent Claim 52 words
The process according to claim 1, wherein the color matching is made to a supplementary color standard previously prepared by the same process as used for preparation of a coating film for color inspection, which comprises applying a paint containing the liquid composition on a substrate and drying or curing the same.
Claim 13
Dependent Claim 13 words
The process according to claim 11, wherein the curing is effected by heating.
Claim 14
Dependent Claim 15 words
The process according to claim 11, wherein the curing is effected by ultraviolet ray irradiation.
Claim 15
Dependent Claim 15 words
The process according to claim 11, wherein the curing is effected by electron beam radiation.

References Cited (Backward Citations)

US2171765A Cited
US2839479A Cited
US3054762A Cited
US3298979A Cited
US3734872A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-11-18 1984-05-19 1984-11-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-11-18 1988-05-19 1988-11-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-11-18 1992-05-19 1992-11-18 $7700.00 Window Closed / Lapsed

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