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US4233570A
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Tunable, rare earth-doped solid state lasers
Assignee: United States Department of Energy
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Filing: 1978-01-11
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Granted: 1980-11-11
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Expires: 1998-01-11
Abstract
Abstract Laser apparatus comprising combinations of an excimer pump laser and a rare earth-doped solid matrix, utilizing the 5d-4f radiative transition in a rare earth ion to produce visible and ultra-violet laser radiation with high overall efficiency in selected cases and relatively long radiative lifetimes.
Inventors
- 👤 John L. Emmett
- 👤 Ralph R. Jacobs
- 👤 William F. Krupke
- 👤 Marvin J. Weber
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 15:32
CPC Classifications
H; H01; H01S; H01S3/00; H01S3/14; H01S3/16
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
159 words
A method for producing tunable laser light in the visible and ultraviolet, the method comprising the steps of: exciting a rare gas-halogen gas or rare gas dimer so that the gas emits radiation at a wavelengths substantially below λ=4500 A; directing a portion of the emitted radiation to a solid matrix which is doped by rare earth ion in a fraction 0.1-2.0% numerical density; causing a substantial number of rare earth ions in the dopant to be excited into a 5d spectroscopic level of the ions by absorption of the emitted radiation; allowing the excited rare earth ions to decay non-radiatively to an energy level substantially at the lower end of the 5d band that has a radiative lifetime exceeding 65 nsec.; allowing the excited rare earth ion to decay radiatively from its position substantially at the lower end of the 5d absorption band, with the emission radiation at a wavelength in the wavelength region 1700 A <λ<5200 A.
Claim 2
Independent Claim
159 words
A method for producing tunable laser light in the visible and ultraviolet, the method comprising the steps of: exciting a rare gas-halogen gas or rare gas dimer so that the gas emits radiation at a wavelengths substantially below λ=4500 A; directing a portion of the emitted radiation to a solid matrix which is doped by rare earth ion in a fraction 0.1-2.0% numerical density; causing a substantial number of rare earth ions in the dopant to be excited into a 5d spectroscopic level of the ions by absorption of the emitted radiation; allowing the excited rare earth ions to decay non-radiatively to an energy level substantially at the lower end of the 5d band that has a radiative lifetime exceeding 65 nsec.; allowing the excited rare earth ion to decay radiatively from its position substantially at the lower end of the 5d absorption band, with the emission radiation at a wavelength in the wavelength region 1700 A <λ<5200 A.
Claim 3
Dependent Claim
32 words
A method according to claim 1, wherein said pump gas is drawn from the group consisting of N 2 , XeF, KrF, ArF, Ar 2 , Kr 2 and Xe 2 .
Claim 4
Independent Claim
148 words
A method for producing tunable laser light in the visible and ultraviolet, the method comprising the steps of: exciting a rare gas dimer so that the gas emits radiation at wavelengths substantially below λ=4500 A; directing a portion of the emitted radiation to a solid matrix which is doped by rare earth ions in a fraction 0.1 to 2.0% numerical density; causing a substantial number of rare earth ions in the dopant to be excited into a 5d spectroscopic level of the ions by absorption of the emitted radiation; allowing the excited rare earth ions to decay non-radiatively to an energy level substantially at the lower end of the 5d band; allowing the excited rare earth ions to decay radiatively from a position substantially at the lower end of the 5d absorption band, with the emission radiation at a wavelength in the wavelength region 1700 A <λ<5200 A.
Claim 5
Independent Claim
148 words
A method for producing tunable laser light in the visible and ultraviolet, the method comprising the steps of: exciting a rare gas dimer so that the gas emits radiation at wavelengths substantially below λ=4500 A; directing a portion of the emitted radiation to a solid matrix which is doped by rare earth ions in a fraction 0.1 to 2.0% numerical density; causing a substantial number of rare earth ions in the dopant to be excited into a 5d spectroscopic level of the ions by absorption of the emitted radiation; allowing the excited rare earth ions to decay non-radiatively to an energy level substantially at the lower end of the 5d band; allowing the excited rare earth ions to decay radiatively from a position substantially at the lower end of the 5d absorption band, with the emission radiation at a wavelength in the wavelength region 1700 A <λ<5200 A.
Claim 6
Dependent Claim
96 words
Solid state laser apparatus comprising: a solid matrix of YAG or NaF, which is substantially transparent to radiation in the wavelength range 2400 A<λ<4000 A; a Ce dopant, being present in the solid matrix in a fraction 0.01% to 2% of the numerical density of atoms of the solid matrix, with an ion of the dopant having at least one 5d spectroscopic atomic level lying above the 4f spectroscopic levels of the ion; pump means to excite a substantial number of Ce ions into an absorption band that contains said 5d spectroscopic level for the ions.
Claim 7
Dependent Claim
96 words
Solid state laser apparatus comprising: a solid matrix of YAG or NaF, which is substantially transparent to radiation in the wavelength range 2400 A<λ<4000 A; a Ce dopant, being present in the solid matrix in a fraction 0.01% to 2% of the numerical density of atoms of the solid matrix, with an ion of the dopant having at least one 5d spectroscopic atomic level lying above the 4f spectroscopic levels of the ion; pump means to excite a substantial number of Ce ions into an absorption band that contains said 5d spectroscopic level for the ions.
Claim 8
Dependent Claim
134 words
Solid state laser apparatus comprising: a solid matrix that is substantially transparent to radiation in the wavelength range 2400 A <λ<4000 A; a rare earth dopant, being present in the solid matrix in a fraction 0.01% to 2% of the numerical density of atoms of the solid matrix, with an ion of the rare earth dopant having at least one 5d spectroscopic atomic level lying above the 4f spectroscopic levels of the ion; pump means to excite a substantial number of rare earth ions into an absorption band which contains said 5d spectroscopic level for the ions, with the pump means including a rare gas dimer which, when excited, emits in said wavelength region, the rare gas dimer being selected from the group consisting of Ar 2 , Kr 2 and Xe 2 .
Claim 9
Dependent Claim
134 words
Solid state laser apparatus comprising: a solid matrix that is substantially transparent to radiation in the wavelength range 2400 A <λ<4000 A; a rare earth dopant, being present in the solid matrix in a fraction 0.01% to 2% of the numerical density of atoms of the solid matrix, with an ion of the rare earth dopant having at least one 5d spectroscopic atomic level lying above the 4f spectroscopic levels of the ion; pump means to excite a substantial number of rare earth ions into an absorption band which contains said 5d spectroscopic level for the ions, with the pump means including a rare gas dimer which, when excited, emits in said wavelength region, the rare gas dimer being selected from the group consisting of Ar 2 , Kr 2 and Xe 2 .
Claim 10
Dependent Claim
110 words
Solid state laser apparatus comprising: a solid matrix that is substantially transparent to radiation in the wavelength range 2400 A <λ<4000 A; a rare earth dopant, being present in the solid matrix in a fraction 0.01% to 2% of the numerical density of atoms of the solid matrix, with an ion of the rare earth dopant having at least one 5d spectroscopic atomic level lying substantially above the 4f spectroscopic levels of the ion; pump means to excite a substantial number of rare earth ions into an absorption band which contains said 5d spectroscopic level for the ions, with the pump means including the XeF or the N 2 molecule.
Claim 11
Dependent Claim
110 words
Solid state laser apparatus comprising: a solid matrix that is substantially transparent to radiation in the wavelength range 2400 A <λ<4000 A; a rare earth dopant, being present in the solid matrix in a fraction 0.01% to 2% of the numerical density of atoms of the solid matrix, with an ion of the rare earth dopant having at least one 5d spectroscopic atomic level lying substantially above the 4f spectroscopic levels of the ion; pump means to excite a substantial number of rare earth ions into an absorption band which contains said 5d spectroscopic level for the ions, with the pump means including the XeF or the N 2 molecule.
Claim 12
Dependent Claim
132 words
Solid state laser apparatus comprising: a solid matrix, drawn from the group consisting of CaF 2 , BaF 2 , SrF 2 , SrAl 2 O 4 , which is substantially transparent to radiation in the wavelength range 2400 A <λ<4000 A; a rare earth dopant, drawn from the divalent group consisting of Eu 2+ and Yb 2+ , being present in the solid matrix in a fraction 0.01% to 2% of the numerical density of atoms of the solid matrix, with an ion of the rare earth dopant having at least one 5d spectroscopic atomic level lying substantially above the 4f spectroscopic levels of the ion; and pump means to excite a substantial number of rare earth ions into an absorption band which contains said 5d spectroscopic level for the ions.
Claim 13
Dependent Claim
132 words
Solid state laser apparatus comprising: a solid matrix, drawn from the group consisting of CaF 2 , BaF 2 , SrF 2 , SrAl 2 O 4 , which is substantially transparent to radiation in the wavelength range 2400 A <λ<4000 A; a rare earth dopant, drawn from the divalent group consisting of Eu 2+ and Yb 2+ , being present in the solid matrix in a fraction 0.01% to 2% of the numerical density of atoms of the solid matrix, with an ion of the rare earth dopant having at least one 5d spectroscopic atomic level lying substantially above the 4f spectroscopic levels of the ion; and pump means to excite a substantial number of rare earth ions into an absorption band which contains said 5d spectroscopic level for the ions.
References Cited (Backward Citations)
US4132962A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-11-11 | 1984-05-12 | 1984-11-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-11-11 | 1988-05-12 | 1988-11-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-11-11 | 1992-05-12 | 1992-11-11 | $7700.00 | Window Closed / Lapsed |