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Hydroisomerization of pentane utilizing Pd exchanged mordenite

Assignee: Saint Gobain Abrasives Inc
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Filing: 1979-06-28
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Granted: 1980-11-04
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Expires: 1999-06-28
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Abstract

Abstract Ammonia exchanged large port mordenite, which is subsequently mildly acid leached, and calcined, in which at least 95% of the exchangeable sodium has been removed and having from 0.38 to 0.8 milliequivalents of acid sites at least as strong as 48% sulfuric acid per gram (as measured by titration with butylamine, and employing dicinnamalacetone indicator) has been found to be highly active hydrocarbon isomerization catalyst. Incorporation of noble metal, e.g. palladium, on the catalyst improves the selectivity for isomerization of normal pentane to isopentane for highly active catalysts at high conversion rates.

Inventors

  • 👤 Joseph R. Kiovsky
  • 👤 William J. Goyette

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 19:43
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/18; B01J29/20; B01J29/22; C; C07; C07C; C07C5/00; C07C5/22; C07C5/27; C07C5/2767; C07C5/277; C07C5/2791

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 66 words
A method of isomerizing comprising passing a mixture of hydrogen and pentane over Pd exchanged mordenite at a temperature between 450° F. and 550° F., characterized in that said mordenite contain less than 0.2% by weight exchanged sodium, has a silica to alumina ratio of between 10 and 17, contains from 0.38 to 0.8 milliequivalents per gram of acid sites stronger than 48% aqueous sulfuric acid.
Claim 2
Independent Claim 66 words
A method of isomerizing comprising passing a mixture of hydrogen and pentane over Pd exchanged mordenite at a temperature between 450° F. and 550° F., characterized in that said mordenite contain less than 0.2% by weight exchanged sodium, has a silica to alumina ratio of between 10 and 17, contains from 0.38 to 0.8 milliequivalents per gram of acid sites stronger than 48% aqueous sulfuric acid.

References Cited (Backward Citations)

US3190939A Cited
US3507931A Cited
US3574092A Cited
US3932554A Cited
US3836597A Cited
US3842114A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-11-04 1984-05-05 1984-11-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-11-04 1988-05-05 1988-11-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-11-04 1992-05-05 1992-11-04 $7700.00 Window Closed / Lapsed

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