Patent US4232145A successfully refreshed from Google Patents.
US4232145A
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Injection moldable glass clear transparent polyamide
Assignee: Inventa AG fuer Forschung und Patentverwertung
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Filing: 1978-12-18
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Granted: 1980-11-04
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Expires: 1998-12-18
Abstract
Abstract Polyamides are described which are useful for injection molding and which are produced by the polycondensation of (a) a diaminodicyclohexane or a diaminodicyclohexylalkane, (b) a polyamide-forming aromatic dicarboxylic acid of more than 9 carbon atoms, and (c) an ω-amino-acid, a lactam of more than 9 carbon atoms, or an aliphatic dicarboxylic acid-diamine mixture or salt thereof.
Inventors
- 👤 Eduard Schmid
- 👤 Wolfgang Griehl
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 17:37
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/02; C08G69/36
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
301 words
A copolyamide having a glass transition temperature (Tg) of 140°-170° C. consisting essentially of the polymeric condensation product of (a) a diamine of the formula ##STR2## wherein R 1 and R 2 are independently selected from the group consisting of hydrogen and methyl, n is an integer from 0 to 6, and wherein each cyclohexane ring may be partially or wholly substituted with methyl groups; (b) a substantially stoichiometric amount, based on the amount of component (a), of a dicarboxylic acid or acid mixture, consisting of from 50 to 100% of isophthalic acid, from 0 to 50 mol or weight % of terephthalic acid, and from 0 to 15 mol % of other polyamide-forming dicarboxylic acid or acids; and (c) 30 to 40% by weight, based on the total weight of components (a), (b) and (c), of a further polyamide-forming component which is selected from the group consisting of amino lauric acid, laurolactam and aminoundecanoic acid, some of said group may be replaced by a member of the class consisting of aliphatic dicarboxylic acids and aliphatic diamines, stoichiometric mixtures of aliphatic dicarboxylic acids and aliphatic diamines, and blends of said salts and mixtures, said member subject to the conditions that the average number of carbon atoms per amide group or between each pair of amide-forming groups is at least 9, that the minimum number of carbon atoms between the amide-forming groups is at least 6, and that, when component (b) is not 100% isophthalic acid or isophthalic acid/terephthalic acid mixture, the sum of the weights of the other polyamide-forming dicarboxylic acids in (b) and of component (c) must be from 30 to 40% by weight, based on the total weight of components (a), (b) and (c), said product having a melt viscosity of 2000 to 15000 poises at about 300° C.
Claim 2
Dependent Claim
301 words
A copolyamide having a glass transition temperature (Tg) of 140°-170° C. consisting essentially of the polymeric condensation product of (a) a diamine of the formula ##STR2## wherein R 1 and R 2 are independently selected from the group consisting of hydrogen and methyl, n is an integer from 0 to 6, and wherein each cyclohexane ring may be partially or wholly substituted with methyl groups; (b) a substantially stoichiometric amount, based on the amount of component (a), of a dicarboxylic acid or acid mixture, consisting of from 50 to 100% of isophthalic acid, from 0 to 50 mol or weight % of terephthalic acid, and from 0 to 15 mol % of other polyamide-forming dicarboxylic acid or acids; and (c) 30 to 40% by weight, based on the total weight of components (a), (b) and (c), of a further polyamide-forming component which is selected from the group consisting of amino lauric acid, laurolactam and aminoundecanoic acid, some of said group may be replaced by a member of the class consisting of aliphatic dicarboxylic acids and aliphatic diamines, stoichiometric mixtures of aliphatic dicarboxylic acids and aliphatic diamines, and blends of said salts and mixtures, said member subject to the conditions that the average number of carbon atoms per amide group or between each pair of amide-forming groups is at least 9, that the minimum number of carbon atoms between the amide-forming groups is at least 6, and that, when component (b) is not 100% isophthalic acid or isophthalic acid/terephthalic acid mixture, the sum of the weights of the other polyamide-forming dicarboxylic acids in (b) and of component (c) must be from 30 to 40% by weight, based on the total weight of components (a), (b) and (c), said product having a melt viscosity of 2000 to 15000 poises at about 300° C.
Claim 3
Dependent Claim
8 words
A copolyamide according to claim 1 wherein n=1-6.
Claim 4
Dependent Claim
21 words
A copolyamide according to claim 1 wherein (c) is taken from the class consisting of aminolauric acid, laurolactam, and aminoundecanoic acid.
Claim 5
Dependent Claim
14 words
A copolyamide according to claim 1 wherein (b) is an isophthalic acid-terephthalic acid mixture.
Claim 6
Dependent Claim
22 words
A copolyamide according to claim 1 wherein said melt viscosity is 4000 to 10,000 poises and Tg is 150° to 170° C.
Claim 7
Dependent Claim
14 words
A copolyamide according to claim 1 wherein (a) consists essentially of bis (4-amino-3-methyl-cyclohexyl) methane.
Claim 8
Dependent Claim
13 words
A copolyamide according to claim 1 wherein (a) is a liquid isomeric mixture.
Claim 9
Dependent Claim
13 words
A copolyamide according to claim 1 wherein (b) consists essentially of isophthalic acid.
Claim 10
Dependent Claim
13 words
A copolyamide according to claim 1 wherein (c) consists essentially of aminolauric acid.
Claim 11
Dependent Claim
12 words
A copolyamide according to claim 1 wherein (c) consists essentially of laurolactam.
Claim 12
Dependent Claim
14 words
A copolyamide according to claim 1 wherein (a) consists essentially of 2,2-bis (4-aminocyclohexyl) propane.
Claim 13
Dependent Claim
22 words
A copolyamide according to claim 1 wherein (a) is selected from the group consisting of 4,4'-diamino-dicyclohexyl methane and 1,2 bis (4-amino-dicyclohexyl) ethane.
Claim 14
Dependent Claim
20 words
A copolyamide according to claim 1 wherein (b) is an isophthalic acid-terephthalic acid mixture and contains another polyamide-forming dicarboxylic acid.
Claim 15
Dependent Claim
17 words
A copolyamide according to claim 13 wherein said polyamide-forming dicarboxylic acid has at least 8 carbon atoms.
Claim 16
Dependent Claim
32 words
A copolyamide according to claim 14 wherein said polyamide-forming dicarboxylic acid is taken from the group consisting of suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, or a branched chain-substituted homolog thereof.
Claim 17
Dependent Claim
11 words
A copolyamide according to claim 1 wherein (c) is aminoundecanoic acid.
Claim 18
Dependent Claim
33 words
A copolyamide according to claim 1 wherein said diamines of (c) are selected from the group consisting of 1,6 diaminohexane, 1,8 diaminoactane, 1,9 diaminononane, 1,10 diaminodecane, 1,12 diaminododecane, trimethylhexamethylene diamine and mixtures thereof.
Claim 19
Dependent Claim
29 words
A copolyamide according to claim 1 wherein said dicarboxylic acids of component (c) are selected from the group consisting of azelaic acid, sebacic acid, dodecanedioic acid and mixtures thereof.
Claim 20
Dependent Claim
42 words
A copolyamide according to claim 1 wherein said dicarboxylic acids and aliphatic amines of (c) are selected from the group consisting of 1,6 diaminohexane; 1,12 diaminododecane; trimethylhexamethylenediamine; 1,8 diaminooctane; 1,9 diaminononane; 1,10 diaminodecane; azelaic acid; sebacic acid; dodecanedioic acid and salts thereof.
References Cited (Backward Citations)
US3847877A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-11-04 | 1984-05-05 | 1984-11-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-11-04 | 1988-05-05 | 1988-11-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-11-04 | 1992-05-05 | 1992-11-04 | $7700.00 | Window Closed / Lapsed |