Imaging compositions and methods

Claim 2

A color-forming precursor composition comprising an organic color-forming, metal-complexing compound having a plurality of ligand groups and an organic cosolvent for said compound, said compound having the formula R.sup.1 (L).sub.n wherein n is a number from 2 to about 100, L is a metal-complexing ligand group, and R 1 is a polyvalent organic group having a valence of n, provided that when n is 2 or 3 and R 1 is a fatty hydrocarbon group, R 1 contains about 34 and 51 carbon atoms respectively, said compound being capable of complexing with transition metal ions to form metal-containing colored products which are substantially insoluble in organic cosolvents for said compound.

Claim 3

A composition according to claim 1 wherein L is a metal-complexing ligand group having the formula ##STR10##

Claim 4

A composition according to claim 1 wherein at least one of said ligand groups comprises a hydroxy-substituted aromatic group.

Claim 5

A composition according to claim 1 wherein at least one of said ligand groups comprises a benzene ring having at least two hydroxyl groups substituted on said ring.

Claim 6

A composition according to claim 4 wherein at least two of said hydroxyl groups are substituted in adjacent positions on said ring.

Claim 7

A composition according to claim 1 wherein said color-forming, metal-complexing compound has the formula ##STR11## wherein n is 2 or 3 or mixtures thereof; when n is 2, R 1 is a hydrocarbon group containing about 34 carbon atoms, and when n is 3, R 1 is a hydrocarbon group containing about 51 carbon atoms.

Claim 8

A composition according to claim 6 wherein n is mixtures of 2 and 3 and wherein said composition contains about 3% of the compound wherein n is 3 and about 97% of the compound wherein n is 2.

Claim 9

A composition according to claim 1 wherein L is a metal-complexing ligand group derived from dithiooxamide.

Claim 10

A composition according to claim 8 wherein said metal-complexing ligand group has the formula ##STR12## wherein R 5 is H or hydrocarbyl.

Claim 11

A composition according to claim 1, wherein said composition includes a reaction accelerating compound selected from the group consisting of tributyl phosphate and a compound having the formula R 6 O--CH 2 CH 2 O-- y R 7 , and mixtures thereof, wherein R 6 and R 7 are hydrogen, lower alkyl acyl or aryl and wherein y is 2-10 and when either of R 6 or R 7 is hydrogen, the complementary R 6 or R 7 is lower alkyl of at least 3 carbon atoms, acyl or aryl.

Claim 12

An encapsulated, color-generating precursor composition comprising rupturable microcapsules containing a liquid fill comprising the precursor composition of claim 1.

Claim 13

A composition for providing a dark, permanent image on substrates comprising a color-forming precursor composition and a color-activating composition, said precursor composition comprising the composition of claim 1 and said color-activating composition comprising a transition metal salt of an oleophilic, organic salt.

Claim 14

A composition according to claim 12, wherein said transition metal salt is ferric benzoate.

Claim 15

A composition according to claim 12, wherein the number of moles of transition metal salt is about one-half the number of ligand groups included in said metal-complexing compound.

Claim 16

A sheet-like substrate having at least a portion of one major surface coated with the color-forming precursor composition of claim 1.

Claim 17

A method of providing a dark, permanent image on a sheet-like substrate comprising (a) coating at least a portion of one major surface of said substrate with the color-forming precursor composition of claim 1; and (b) contacting a color-activating composition with a transfer means and subsequently contacting said substrate surface with said transfer means whereby said color-activating composition is brought into contact with said color-forming precursor composition and a dark, permanent image is formed on said substrate.

Claim 18

A method according to claim 16, wherein said transfer means is a portion of a human body.

Claim 19

A method of providing a dark, permanent image on paper comprising (a) providing a transfer sheet having at least a portion of one major surface coated with rupturable microcapsules containing a liquid fill, said liquid fill comprising a color-forming precursor composition according to claim 1; (b) juxtaposing said transfer sheet overlying a receptor sheet such that the capsule coated surface of the transfer sheet is in contact with the receptor sheet; (c) applying pressure to the obverse surface of said transfer sheet to rupture at least a portion of said microcapsules and transfer at least a portion of said color-forming precursor composition to at least a portion of said receptor sheet thereby sensitizing portions of said receptor sheet; (d) separating said receptor sheet and said transfer sheet; and (e) contacting a color-activating composition with a transfer means and subsequently contacting a sensitized area of said receptor sheet with said transfer means whereby said color-activating composition is brought into contact with said color-forming precursor composition to form a dark, permanent image in said sensitized area of said receptor sheet.

Claim 20

A method according to claim 18 wherein said transfer means is a portion of a human body.

Claim 21

A method according to claim 18 wherein said transfer sheet has images in mirror-image form on said capsule coated surface, said images comprising visible ink which is at least partially soluble in said cosolvent and is transferred to said receptor sheet when said capsules are ruptured.

Claim 22

A composition according to claim 1 wherein n is 3 or mixtures of 2 and 3.

Claim 23

A method of making dark, permanent, non-migrating images in a cosolvent environment on a paper substrate comprising (a) coating at least a portion of the substrate with the color-forming precursor composition of claim 1 and wherein said cosolvent includes a reaction accelerating compound selected from the group consisting of trioctyl phosphate, tributyl phosphate and a compound having the formula R 6 O--CH 2 CH 2 O-- y R 7 , and mixtures thereof, wherein R 6 and R 7 are hydrogen, lower alkyl, acyl or aryl and wherein Y is 2-10 and when either of R 6 or R 7 is hydrogen, the complementary R 6 or R 7 is lower alkyl of at least 3 carbon atoms, acyl or aryl, and (b) contacting a color-activating composition with a transfer means and subsequently contacting said substrate surface with said transfer means whereby said color-activating composition is brought into contact with said color-forming precursor composition and a dark, permanent, non-migrating image is formed.

Claim 24

A composition according to claim 1 wherein said color-forming, metal-complexing compound has the formula ##STR13## wherein n is 2 or 3 or mixtures thereof; when n is 2, R 4 is a hydrocarbon group containing about 34 carbon atoms, and when n is 3, R 4 is a hydrocarbon group containing about 51 carbon atoms.

Claim 25

A color-forming precursor composition according to claim 1 wherein said composition contains a sufficient amount of said compound wherein n is 3 or greater to provide crosslinked complexes with transition metal ions which are substantially insoluble in organic cosolvents for said compounds.

Claim 26

A color-forming precursor composition comprising an organic color-forming, metal-complexing compound having a plurality of ligand groups and an organic cosolvent for said compound, said compound having the formula ##STR14## wherein n is a number from 2 to about 100 R 1 is a polyvalent organic group having a valence of n R 2 is an organic group independently selected from the group consisting of H, or hydrocarbyl, a is an integer from 1 to 5, and b is o or an integer from 1-4 and a+b is less than 6 .

Claim 27

A color-forming precursor composition comprising an organic color-forming, metal-complexing compound having a plurality of ligand groups and an organic cosolvent for said compound, said compound having the formula ##STR14## wherein n is a number from 2 to about 100 R 1 is a polyvalent organic group having a valence of n R 2 is an organic group independently selected from the group consisting of H, or hydrocarbyl, a is an integer from 1 to 5, and b is o or an integer from 1-4 and a+b is less than 6 .

Claim 28

A composition according to claim 25 wherein a is at least 2 and at least 2 of said hydroxyl groups are in adjacent positions.

Claim 29

A composition according to claim 25 wherein R 2 , a and b are as previously defined; n is 2; and R 1 is a bivalent, organic group selected from the group consisting of ##STR15## wherein R 2 is independently H or hydrocarbyl; and X is 0 or is an integer up to about 100.

Claim 30

A composition according to claim 25 wherein R 2 , a and b are as previously defined; n is 3; and R 1 is a trivalent, organic group selected from the group consisting of --COR 3 --CR 2 3 -- 2 , --OCR 3 --CR 2 3 O-- 2 , ##STR16## wherein R 3 is as previously defined.