US4232078A
Expired / Lapsed
US
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Multi-colored synthetic resin sheet
Assignee: Mitsubishi Chemical Corp
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Filing: 1978-10-13
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Granted: 1980-11-04
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Expires: 1998-10-13
Abstract
Abstract A multi-colored synthetic resin sheet having an upper surface, a lower surface and a uniformly colored longitudinal cross-section which has at least two longitudinally adjacent different colors, with the boundary portion between the colors being in a gradated state on the upper surface and throughout a transversal section of sheet, is formed by adjacently feeding at least two differently colored polymerizable liquids into a polymerizing apparatus and polymerizing and hardening the materials.
Inventors
- 👤 Isao Kamada
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 19:13
CPC Classifications
B; B29; B29C; B29C39/00; B29C39/003; B29C39/006; B29C39/02; B29C39/12; B29C39/14; B29C39/142; B29C39/144; B29C39/16; B44; B44C; B44C5/00; B44C5/04; B44F; B44F1/00; B44F1/08; B29K; B29K2105/00; B29K2105/0002; B29K2995/00; B29K2995/0018; B29K2995/002; B29K2995/0021; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/26
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
61 words
A multi-colored synthetic resin sheet having an upper surface, a lower surface, and a uniformly colored longitudinal cross-section, which has at least two longitudinally adjacent different colors with a boundary portion therein between, with the boundary portion between said colors being in a gradated state on the upper surface, on the lower surface and throughout a transversal cross-section of said sheet.
Claim 2
Dependent Claim
61 words
A multi-colored synthetic resin sheet having an upper surface, a lower surface, and a uniformly colored longitudinal cross-section, which has at least two longitudinally adjacent different colors with a boundary portion therein between, with the boundary portion between said colors being in a gradated state on the upper surface, on the lower surface and throughout a transversal cross-section of said sheet.
Claim 3
Dependent Claim
15 words
The sheet of claim 1, wherein said sheet further comprises a dye or a pigment.
Claim 4
Dependent Claim
17 words
The synthetic resin sheet of claim 1 wherein the thickness of said sheet is 1.5 mm-15 mm.
Claim 5
Dependent Claim
38 words
The sheet of claim 1, wherein said synthetic resin is a polymer prepared from monomers selected from the group consisting of monoethylenically unsaturated compounds, polyfunctional polymerizable compounds, and mixtures thereof, wherein said compounds are liquid under normal pressure.
Claim 6
Dependent Claim
39 words
The sheet of claim 4, wherein said monoethylenically unsaturated compounds are selected from the group consisting of methacrylate, halogen or alkyl substituents thereof; ethylene, halogens or alkyl substituents thereof; vinyl acetate; acrylates; acrylonitrile, substituted derivatives thereof; and mixtures thereof.
Claim 7
Dependent Claim
29 words
The sheet of claim 4, wherein said polyfunctional compounds are selected from the group consisting of glycol dimethacrylate, diallyl methacrylate, diallyl phthalate, diethylene glycol bisallyl carbonate and mixtures thereof.
Claim 8
Dependent Claim
16 words
The sheet of claim 4, wherein said polymerizable liquid material comprises a copolymer of methyl methacrylate.
Claim 9
Independent Claim
88 words
A method of producing a multi-colored synthetic resin sheet which comprises: adjacently feeding onto a moving belt at least two differently colored liquids comprising polymerizable monomer; polymerizing and hardening said liquids; thereby obtaining a multi-colored synthetic resin sheet which has an upper surface, a lower surface, and a uniformly colored longitudinal cross-section, which has at least two longitudinally adjacent colors with the boundary portion between said colors being in a gradated state on the upper surface, on the lower surface, and throughout a transversal cross-section of said sheet.
Claim 10
Independent Claim
88 words
A method of producing a multi-colored synthetic resin sheet which comprises: adjacently feeding onto a moving belt at least two differently colored liquids comprising polymerizable monomer; polymerizing and hardening said liquids; thereby obtaining a multi-colored synthetic resin sheet which has an upper surface, a lower surface, and a uniformly colored longitudinal cross-section, which has at least two longitudinally adjacent colors with the boundary portion between said colors being in a gradated state on the upper surface, on the lower surface, and throughout a transversal cross-section of said sheet.
Claim 11
Dependent Claim
24 words
The method of claim 8 wherein the difference in viscosity between two adjacent liquid raw materials is less than 10 poises at 20° C.
Claim 12
Dependent Claim
17 words
The method of claim 8 wherein said liquid polymerizable materials comprise a mixture of monomers and polymers.
Claim 13
Dependent Claim
33 words
The method of claim 8 wherein said liquid raw materials further comprise an additive selected from the group consisting of initiators, stabilizers, plasticizers, polymerization regulators, fillers, releasing agents, viscosity modifiers and mixtures thereof.
Claim 14
Dependent Claim
14 words
The method of claim 8 wherein after hardening, said synthetic resin sheet is cooled.
Claim 15
Dependent Claim
14 words
The method of claim 8 wherein said moving belts comprises a continuous-belt, sheet-making apparatus.
Claim 16
Dependent Claim
11 words
The synthetic resin sheet produced by the method of claim 8.
Claim 17
Dependent Claim
21 words
The method of claim 8 wherein the liquid polymerizable materials comprise a dye or a pigment dispersed in a carrier medium.
Claim 18
Dependent Claim
17 words
The method of claim 15 wherein said pigment or dye is in the powdery or pasty form.
Claim 19
Dependent Claim
20 words
The method of claim 8, wherein the viscosity of said colored polymerizable liquid material is 30-50 poises at 20° C.
Claim 20
Dependent Claim
14 words
The method of claim 13 wherein said viscosity is 5-40 poises at 20° C.
Claim 21
Dependent Claim
36 words
The method of claim 8 wherein said polymerizable liquid materials comprise a compound selected from the group consisting of monoethylenically unsaturated compounds, polyfunctional polymerizable compounds, and mixtures thereof, wherein said compounds are liquids under normal pressure.
Claim 22
Dependent Claim
39 words
The method of claim 19 wherein said monoethylenically unsaturated compounds are selected from the group consisting of methacrylates, halogen or alkyl substituents thereof; ethylene, halogens or alkyl substituents thereof; vinyl acetate; acrylates; acrylonitrile, substituted derivatives thereof; and mixtures thereof.
Claim 23
Dependent Claim
29 words
The method of claim 19 wherein said polyfunctional compounds are selected from the group consisting of glycol dimethacrylate, diallyl methacrylate, diallyl phthalate, diethylene glycol bisallyl carbonate and mixtures thereof.
Claim 24
Dependent Claim
15 words
The method of claim 19 wherein said liquid materials comprise a copolymer of methyl methacrylate.
Claim 25
Dependent Claim
23 words
The method of claim 8 wherein said liquid polymerizable material comprises a copolymer of methyl methacrylate and styrene in a ratio of 2:8-8:2.
Claim 26
Dependent Claim
20 words
The method of claim 23 wherein said copolymer is dissolved in an amount of from 0.5 to 4% by weight.
Claim 27
Dependent Claim
42 words
The method of claim 8 wherein said polymerization comprises two polymerization stages; wherein the first stage is carried out at a temperature of less than 100° C. and the second stage is carried out at a temperature of higher than 100° C.
Claim 28
Dependent Claim
16 words
The method of claim 25 wherein the temperature of said first stage is about 65°-90° C.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-11-04 | 1984-05-05 | 1984-11-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-11-04 | 1988-05-05 | 1988-11-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-11-04 | 1992-05-05 | 1992-11-04 | $7700.00 | Window Closed / Lapsed |