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US4229608A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat balanced cyclic process for manufacture of light olefins

Assignee: Mobil Oil AS
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Filing: 1978-12-18
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Granted: 1980-10-21
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Expires: 1998-12-18
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Abstract

Abstract A catalytic heat balanced cyclic process is provided for converting a charge consisting essentially of methanol, dimethyl ether or mixtures thereof to a hydrocarbon product rich in ethylene and propylene by contact, under specified conditions of temperature and contact time, with a catalyst comprising a crystalline aluminosilicate zeolite characterized by pores, the major dimension of which is less than 6 Angstroms and the capability, under such conditions, of producing less than about 20 weight percent methane in said hydrocarbon product, regenerating the catalyst so employed at a temperature between about 1200° and about 1400° F. to remove accumulated carbonaceous deposit therefrom and provide a source of hot regenerated catalyst for further contact, under controlled temperature conditions, with said charge.

Inventors

  • 👤 Nai Y. Chen
  • 👤 Werner O. Haag
  • 👤 Rudolph M. Lago

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 16:36
CPC Classifications
B; B01; B01J; B01J8/00; B01J8/18; B01J8/24; B01J8/38; B01J8/384; B01J8/388; C; C07; C07C; C07C1/00; C07C1/20; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/50; C07C2529/70; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/584; Y02P30/00; Y02P30/20; Y02P30/40

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 255 words
A heat balanced cyclic process for converting a charge consisting essentially of methanol, dimethyl ether or mixtures thereof to a hydrocarbon product rich in ethylene and propylene which comprises contacting said charge with a fluidized catalyst comprising a crystalline aluminosilicate zeolite characterized by pores, the major dimension of which is less than 6 Angstroms, further characterized by pore windows of about a size such as would be provided by 8-membered rings of oxygen atoms and the capability, under the hereinafter specified conditions, of producing less than 20 weight percent methane in said hydrocarbon product, said contacting taking place in a riser reactor at an inlet temperature between about 800 and 1000° F. and an increased outlet temperature between about 900° and about 1150° F. with a weight ratio of catalyst to charge between about 5 and about 12 and a residence time between catalyst and charge of less than 30 seconds, during which time, a minor proportion of less than about 9 percent by weight of the charge is converted to form a carbonaceous deposit on said catalyst in an amount of between about 0.4 and about 1 weight percent, thereafter separating the hydrocarbon product, rich in ethylene and propylene from the carbonaceous deposit-containing catalyst, conducting the latter to a regenerator, maintained at a temperature within the approximate range of 1200° to 1400° F., wherein said carbonaceous deposit is removed by combustion in air, recycling the resulting hot regenerated catalyst to further contact with a fresh stream of said charge and repeating the above cycle.
Claim 2
Dependent Claim 255 words
A heat balanced cyclic process for converting a charge consisting essentially of methanol, dimethyl ether or mixtures thereof to a hydrocarbon product rich in ethylene and propylene which comprises contacting said charge with a fluidized catalyst comprising a crystalline aluminosilicate zeolite characterized by pores, the major dimension of which is less than 6 Angstroms, further characterized by pore windows of about a size such as would be provided by 8-membered rings of oxygen atoms and the capability, under the hereinafter specified conditions, of producing less than 20 weight percent methane in said hydrocarbon product, said contacting taking place in a riser reactor at an inlet temperature between about 800 and 1000° F. and an increased outlet temperature between about 900° and about 1150° F. with a weight ratio of catalyst to charge between about 5 and about 12 and a residence time between catalyst and charge of less than 30 seconds, during which time, a minor proportion of less than about 9 percent by weight of the charge is converted to form a carbonaceous deposit on said catalyst in an amount of between about 0.4 and about 1 weight percent, thereafter separating the hydrocarbon product, rich in ethylene and propylene from the carbonaceous deposit-containing catalyst, conducting the latter to a regenerator, maintained at a temperature within the approximate range of 1200° to 1400° F., wherein said carbonaceous deposit is removed by combustion in air, recycling the resulting hot regenerated catalyst to further contact with a fresh stream of said charge and repeating the above cycle.
Claim 3
Dependent Claim 12 words
The process of claim 1 wherein the charge consists essentially of methanol.
Claim 4
Dependent Claim 15 words
The process of claim 1 wherein said residence time is less than about 15 seconds.
Claim 5
Dependent Claim 25 words
The process of claim 1 wherein between about 4 and about 6 percent by weight of the charge is converted to form said carbonaceous deposit.
Claim 6
Dependent Claim 16 words
The process of claim 1 wherein said crystalline aluminosilicate zeolite is predominantly in the hydrogen form.
Claim 7
Dependent Claim 16 words
The process of claim 1 wherein said crystalline aluminosilicate zeolite is contained in a matrix therefor.
Claim 8
Dependent Claim 10 words
The process of claim 1 wherein said zeolite is erionite.
Claim 9
Dependent Claim 10 words
The process of claim 1 wherein said zeolite is chabazite.
Claim 10
Dependent Claim 11 words
The process of claim 1 wherein said zeolite is zeolite T.
Claim 11
Dependent Claim 11 words
The process of claim 1 wherein said zeolite is zeolite ZK-5.

References Cited (Backward Citations)

US4046825A Cited
US4062905A Cited
US4134926A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-10-21 1984-04-21 1984-10-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-10-21 1988-04-21 1988-10-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-10-21 1992-04-21 1992-10-21 $7700.00 Window Closed / Lapsed

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