Patent US4228263A successfully refreshed from Google Patents.
US4228263A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polymerization of propylene with a catalyst prepared in situ
Assignee: EIDP Inc
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Filing: 1978-06-20
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Granted: 1980-10-14
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Expires: 1998-06-20
Abstract
Abstract In the production of elastomeric polypropylene by polymerizing propylene in the presence of a catalyst system which is the reaction product of a metal oxide and and an organometallic compound of Zr, Ti or Hf under conditions such that the reaction medium contains liquid propylene, a fluid, mobile slurry of polypropylene in propylene is formed by mixing the components of the catalyst system together in the presence of the propylene to be polymerized.
Inventors
- 👤 Edward G. Howard, Jr.
- 👤 Christos Sarafidis
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 21:50
CPC Classifications
C; C08; C08F; C08F10/00; C08F10/04; C08F10/06; Y; Y10; Y10S; Y10S526/00; Y10S526/903
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
164 words
In the method of producing elastomeric polymers of propylene and up to about 5 mole % of another α-olefin by the polymerization of propylene in the presence of a catalyst system which is the reaction product of a metal oxide and an organometallic compound of the formula (RCH 2 ) 4 M, where M is Zr, Ti or Hf; R is aryl, aralkyl, tertiary alkyl or trialkylsilyl; the aforementioned alkyl groups are C 1 -C 12 ; and the RCH 2 group has no hydrogen bonded to the carbon which is beta to M; at a temperature of 20° to 100° C. and a pressure of 147 psi up to 5000 psi (0.1-34.5 MPa) such that the reaction medium contains liquid propylene, the improvement which comprises mixing the components of the catalyst system together, whereby they react to form said catalyst system, in a solvent consisting principally of liquid propylene and the elastomeric polymer is produced as a mobile slurry in said liquid propylene.
Claim 2
Dependent Claim
164 words
In the method of producing elastomeric polymers of propylene and up to about 5 mole % of another α-olefin by the polymerization of propylene in the presence of a catalyst system which is the reaction product of a metal oxide and an organometallic compound of the formula (RCH 2 ) 4 M, where M is Zr, Ti or Hf; R is aryl, aralkyl, tertiary alkyl or trialkylsilyl; the aforementioned alkyl groups are C 1 -C 12 ; and the RCH 2 group has no hydrogen bonded to the carbon which is beta to M; at a temperature of 20° to 100° C. and a pressure of 147 psi up to 5000 psi (0.1-34.5 MPa) such that the reaction medium contains liquid propylene, the improvement which comprises mixing the components of the catalyst system together, whereby they react to form said catalyst system, in a solvent consisting principally of liquid propylene and the elastomeric polymer is produced as a mobile slurry in said liquid propylene.
Claim 3
Dependent Claim
27 words
The method of claim 1 in which the polymerization is carried out at 40° to 90° C. and a pressure of less than 1000 psi (6.9 MPa).
Claim 4
Dependent Claim
18 words
The method of claim 1 in which the catalyst system is the reaction product of alumina and tetraneophylzirconium.
Claim 5
Dependent Claim
17 words
The method of claim 1 in which the polymerization is carried out in the presence of hydrogen.
Claim 6
Dependent Claim
20 words
The method of claim 1 in which the polymerization is carried out at a temperature of 60° to 90° C.
Claim 7
Dependent Claim
21 words
The method of claim 1 in which up to 5 mole percent of the propylene monomer is replaced with another α-olefin.
Claim 8
Dependent Claim
11 words
The method of claim 6 in which the α-olefin is ethylene.
Claim 9
Dependent Claim
18 words
The method of claim 2 in which the catalyst system is the reaction product of alumina and tetraneophylzirconium.
Claim 10
Dependent Claim
17 words
The method of claim 8 in which the polymerization is carried out in the presence of hydrogen.
Claim 11
Dependent Claim
20 words
The method of claim 9 in which up to 5 mole percent of the propylene monomer is replaced with ethylene.
References Cited (Backward Citations)
US3002961A
Cited
GB909081A
Cited
FR1389767A
Cited
US3840508A
Cited
US3694422A
Cited
US3794628A
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US3875132A
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US3932307A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-10-14 | 1984-04-14 | 1984-10-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-10-14 | 1988-04-14 | 1988-10-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-10-14 | 1992-04-14 | 1992-10-14 | $7700.00 | Window Closed / Lapsed |