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US4228263A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymerization of propylene with a catalyst prepared in situ

Assignee: EIDP Inc
•
Filing: 1978-06-20
•
Granted: 1980-10-14
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Expires: 1998-06-20
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Abstract

Abstract In the production of elastomeric polypropylene by polymerizing propylene in the presence of a catalyst system which is the reaction product of a metal oxide and and an organometallic compound of Zr, Ti or Hf under conditions such that the reaction medium contains liquid propylene, a fluid, mobile slurry of polypropylene in propylene is formed by mixing the components of the catalyst system together in the presence of the propylene to be polymerized.

Inventors

  • 👤 Edward G. Howard, Jr.
  • 👤 Christos Sarafidis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 19:44
CPC Classifications
C; C08; C08F; C08F10/00; C08F10/04; C08F10/06; Y; Y10; Y10S; Y10S526/00; Y10S526/903

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 164 words
In the method of producing elastomeric polymers of propylene and up to about 5 mole % of another α-olefin by the polymerization of propylene in the presence of a catalyst system which is the reaction product of a metal oxide and an organometallic compound of the formula (RCH 2 ) 4 M, where M is Zr, Ti or Hf; R is aryl, aralkyl, tertiary alkyl or trialkylsilyl; the aforementioned alkyl groups are C 1 -C 12 ; and the RCH 2 group has no hydrogen bonded to the carbon which is beta to M; at a temperature of 20° to 100° C. and a pressure of 147 psi up to 5000 psi (0.1-34.5 MPa) such that the reaction medium contains liquid propylene, the improvement which comprises mixing the components of the catalyst system together, whereby they react to form said catalyst system, in a solvent consisting principally of liquid propylene and the elastomeric polymer is produced as a mobile slurry in said liquid propylene.
Claim 2
Dependent Claim 164 words
In the method of producing elastomeric polymers of propylene and up to about 5 mole % of another α-olefin by the polymerization of propylene in the presence of a catalyst system which is the reaction product of a metal oxide and an organometallic compound of the formula (RCH 2 ) 4 M, where M is Zr, Ti or Hf; R is aryl, aralkyl, tertiary alkyl or trialkylsilyl; the aforementioned alkyl groups are C 1 -C 12 ; and the RCH 2 group has no hydrogen bonded to the carbon which is beta to M; at a temperature of 20° to 100° C. and a pressure of 147 psi up to 5000 psi (0.1-34.5 MPa) such that the reaction medium contains liquid propylene, the improvement which comprises mixing the components of the catalyst system together, whereby they react to form said catalyst system, in a solvent consisting principally of liquid propylene and the elastomeric polymer is produced as a mobile slurry in said liquid propylene.
Claim 3
Dependent Claim 27 words
The method of claim 1 in which the polymerization is carried out at 40° to 90° C. and a pressure of less than 1000 psi (6.9 MPa).
Claim 4
Dependent Claim 18 words
The method of claim 1 in which the catalyst system is the reaction product of alumina and tetraneophylzirconium.
Claim 5
Dependent Claim 17 words
The method of claim 1 in which the polymerization is carried out in the presence of hydrogen.
Claim 6
Dependent Claim 20 words
The method of claim 1 in which the polymerization is carried out at a temperature of 60° to 90° C.
Claim 7
Dependent Claim 21 words
The method of claim 1 in which up to 5 mole percent of the propylene monomer is replaced with another α-olefin.
Claim 8
Dependent Claim 11 words
The method of claim 6 in which the α-olefin is ethylene.
Claim 9
Dependent Claim 18 words
The method of claim 2 in which the catalyst system is the reaction product of alumina and tetraneophylzirconium.
Claim 10
Dependent Claim 17 words
The method of claim 8 in which the polymerization is carried out in the presence of hydrogen.
Claim 11
Dependent Claim 20 words
The method of claim 9 in which up to 5 mole percent of the propylene monomer is replaced with ethylene.

References Cited (Backward Citations)

US3002961A Cited
GB909081A Cited
FR1389767A Cited
US3840508A Cited
US3694422A Cited
US3794628A Cited
US3875132A Cited
US3932307A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-10-14 1984-04-14 1984-10-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-10-14 1988-04-14 1988-10-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-10-14 1992-04-14 1992-10-14 $7700.00 Window Closed / Lapsed

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