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US4228151A Expired / Lapsed US ⏱️ 0.0 years remaining

Cosmetic composition for imparting to human skin a coloration resembling a natural tan

Assignee: L'Oréal SA
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Filing: 1977-05-03
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Granted: 1980-10-14
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Expires: 1997-05-03
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Abstract

Abstract A cosmetic composition for imparting to human skin after exposure to sunlight a coloration resembling a natural tan comprises a cosmetic vehicle suitable for topical application to the skin and an effective amount of at least one compound of the formula <IMAGE> wherein R1 and R2 each independently represent hydrogen, an aliphatic radical having 1-18 carbon atoms, carbalkoxy having 2-5 carbon atoms, acyl having 2-5 carbon atoms, aryl, aryl substituted by alkyl having 1-4 carbon atoms or hydroxy, a heterocycle containing 4-6 members, substituted or not by alkyl having 1-4 carbon atoms, halogen or hydroxy, or R1 and R2 together form a saturated ring containing 4-12 chains, optionally substituted by alkyl having 1-4 carbon atoms, halogen or hydroxy, or bridged and containing a heteroatom selected from N, O or S; and R3 represents hydrogen, a lower aliphatic group containing 1-6 carbon atoms, lower alkoxy containing 1-4 carbon atoms or halogen, with the proviso that R1, R2 and R3 are not hydrogen simultaneously; and an acid addition salt thereof.

Inventors

  • 👤 Gerard Lang
  • 👤 Serge Forestier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 11:54
CPC Classifications
A; A61; A61Q; A61Q17/00; A61Q17/04; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/49; A61K8/494

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 281 words
A process for coloring human skin comprising applying to the skin in an amount sufficient to impart to said skin after exposure to ultraviolet rays a coloration resembling a natural tan a composition comprising a cosmetic vehicle suitable for topical application to the skin selected from the group consisting of (1) a hydroalcoholic solution containing 10-90 weight percent alcohol, (2) a glycerin-alcoholic solution containing 10-90 weight percent alcohol, (3) a glycerin-hydroalcoholic solution containing 10-90 weight percent alcohol, (4) an oleo-alcohol composition containing a vegetable oil, a lower alkyl ester and a lower alcohol having 1-4 carbon atoms, (5) an aqueous gel including a surfactant and a gel forming agent, and (6) an oil-in-water emulsion including a surfactant, an oil, a thickening agent and a humectant, and at least one compound selected from the group consisting of (a) a compound of the formula ##STR3## wherein R 1 and R 2 each independently represent hydrogen, a linear or branched alkyl having 1-18 carbon atoms, carbalkoxy having 2-5 carbon atoms, acyl having 2-5 carbon atoms, phenyl and phenyl substituted by a member selected from the group consisting of alkyl having 1-4 carbon atoms and hydroxy, and R 3 represents hydrogen, lower alkyl containing 1-6 carbon atoms, lower alkoxy containing 1-4 carbon atoms or halogen, with the proviso that R 1 , R 2 and R 3 are not hydrogen simultaneously; and (b) an acid addition salt of the compound in (a), said compound being present in an amount of 0.5-10 percent by weight of said composition, and said composition having a pH between 3 and 8.5, and exposing the skin to ultraviolet rays for a time effective to develop said color on said skin.
Claim 2
Dependent Claim 281 words
A process for coloring human skin comprising applying to the skin in an amount sufficient to impart to said skin after exposure to ultraviolet rays a coloration resembling a natural tan a composition comprising a cosmetic vehicle suitable for topical application to the skin selected from the group consisting of (1) a hydroalcoholic solution containing 10-90 weight percent alcohol, (2) a glycerin-alcoholic solution containing 10-90 weight percent alcohol, (3) a glycerin-hydroalcoholic solution containing 10-90 weight percent alcohol, (4) an oleo-alcohol composition containing a vegetable oil, a lower alkyl ester and a lower alcohol having 1-4 carbon atoms, (5) an aqueous gel including a surfactant and a gel forming agent, and (6) an oil-in-water emulsion including a surfactant, an oil, a thickening agent and a humectant, and at least one compound selected from the group consisting of (a) a compound of the formula ##STR3## wherein R 1 and R 2 each independently represent hydrogen, a linear or branched alkyl having 1-18 carbon atoms, carbalkoxy having 2-5 carbon atoms, acyl having 2-5 carbon atoms, phenyl and phenyl substituted by a member selected from the group consisting of alkyl having 1-4 carbon atoms and hydroxy, and R 3 represents hydrogen, lower alkyl containing 1-6 carbon atoms, lower alkoxy containing 1-4 carbon atoms or halogen, with the proviso that R 1 , R 2 and R 3 are not hydrogen simultaneously; and (b) an acid addition salt of the compound in (a), said compound being present in an amount of 0.5-10 percent by weight of said composition, and said composition having a pH between 3 and 8.5, and exposing the skin to ultraviolet rays for a time effective to develop said color on said skin.
Claim 3
Dependent Claim 59 words
The process of claim 1, wherein said compound is selected from the group consisting of: 3-methyl quinoxaline di-N-oxide, 2,3-dimethyl quinoxaline di-N-oxide, 2-methyl-3-phenyl quinoxaline di-N-oxide, 2-methyl-3-p-hydroxyphenyl quinoxaline di-N-oxide, 2-ethyl-3-methyl quinoxaline di-N-oxide, 2-isopropyl-3-methyl quinoxaline di-N-oxide, 2-decyl-3-methyl-quinoxaline di-N-oxide, 2-hexadecyl-3-methyl quinoxaline di-N-oxide, 2-carbethoxy-3-methyl quinoxaline di-N-oxide, 2-acetyl-3-methyl quinoxaline di-N-oxide, 2,3-dimethyl-6-methoxy quinoxaline di-N-oxide, 2,3-dimethyl-6-chloro quinoxaline di-N-oxide, 2-ethyl-3,6-dimethyl quinoxaline di-N-oxide, and the acid addition salts thereof.
Claim 4
Dependent Claim 26 words
The process of claim 1, wherein said acid addition salt is a hydrochloride, a sulfate, an acetate, a tartrate, a perchlorate, a citrate or a stearate.
Claim 5
Dependent Claim 22 words
The process of claim 1 wherein said composition also includes a solar filter in an amount of 0.5-5 percent by weight thereof.
Claim 6
Dependent Claim 43 words
The process of claim 4 wherein said solar filter is selected from the group consisting of benzylidene camphor, ethyl hexyl p-methoxy cinnamate, amyl p-dimethylamino benzoate, 5-benzoyl-4-hydroxy-2-methoxy benzene sulfonic acid, hydroxypropylenated derivative of a p-amino benzoate and the diethanolamine salt of p-methoxy cinnamic acid.
Claim 7
Dependent Claim 49 words
The process of claim 1 wherein said cosmetic vehicle is (4) and wherein said vegetable oil is present in an amount of 5-40 weight percent, the alcohol is present in an amount of 35-80 weight percent and the alkyl ester is present in an amount of 5-40 weight percent.
Claim 8
Dependent Claim 43 words
The process of claim 1 where, in the said composition, the said cosmetic vehicle is (5) and wherein said surfactant is present in an amount of 1-25 weight percent and said gel forming agent is present in an amount of 0.5-4 weight percent.
Claim 9
Dependent Claim 22 words
The process of claim 7 wherein the composition also includes a silicone oil in an amount up to about two weight percent.
Claim 10
Dependent Claim 64 words
The process of claim 1 wherein, in the said composition, the said cosmetic vehicle is (6) and wherein said surfactant is present in an amount of 2-20 weight percent, said oil is present in an amount of 10-50 weight percent, said thickening agent is present in an amount of 0-6 weight percent and said humectant is present in an amount of 0-15 weight percent.
Claim 11
Dependent Claim 21 words
The process of claim 6 wherein said vegetable oil is colza oil, olive oil, peanut oil, coconut oil or palm oil.
Claim 12
Dependent Claim 15 words
The process of claim 6 wherein said alkyl ester is isopropyl myristate or isopropyl palmitate.
Claim 13
Dependent Claim 10 words
The process of claim 6 wherein said alcohol is ethanol.
Claim 14
Dependent Claim 37 words
The process of claim 7 wherein said surfactant is a fatty alcohol having 12-18 carbon atoms oxyethylenated with 4-15 moles of ethylene oxide, nonylphenol oxyethylenated with 6-12 moles of ethylene oxide or a carboxylic derivative of imidazole.
Claim 15
Dependent Claim 20 words
The process of claim 7 wherein said gel forming agent is cellulose ether, carboxy methyl cellulose or crosslinked polyacrylic acid.
Claim 16
Dependent Claim 43 words
The process of claim 9 wherein said surfactant is a fatty alcohol having 12-18 carbon atoms oxyethylenated with 10-15 moles of ethylene oxide, isopropyl palmitate, isopropyl myristate, glycerol monostearate, polyoxyethylenated sorbitan monostearate, partially sulfated or partially oxyethylenated cetyl-stearyl alcohol, or a mixture thereof.
Claim 17
Dependent Claim 43 words
The process of claim 9 wherein said oil is light petrolatum oil, perhydrosqualene, sweet almond oil, ricin oil, colza oil, olive oil, peanut oil, coconut oil, palm oil, fatty alcohol having 7 carbon atoms or a saturated fatty acid having 18 carbon atoms.
Claim 18
Dependent Claim 18 words
The process of claim 9 wherein said thickening agent is starch, crosslinked polyacrylic acid or diethylene glycol stearate.
Claim 19
Dependent Claim 10 words
The process of claim 9 wherein said humectant is glycerin.
Claim 20
Dependent Claim 12 words
The process of claim 1 wherein said compound is 2,3-dimethyl quinoxaline di-N-oxide.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-10-14 1984-04-14 1984-10-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-10-14 1988-04-14 1988-10-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-10-14 1992-04-14 1992-10-14 $7700.00 Window Closed / Lapsed

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