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US4228064A Expired / Lapsed US ⏱️ 0.0 years remaining

Flame-retardant polyphenylene ether resin composition

Assignee: Asahi Kasei Corp
•
Filing: 1979-10-18
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Granted: 1980-10-14
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Expires: 1999-10-18
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Abstract

Abstract A flame-retardant polyphenylene ether resin composition comprising (I) 85 to 97% by weight of a resin consisting of (1) 20 to 90% by weight of a polyphenylene ether of the formula (A): ##STR1## where R 1 and R 2 are each alkyl of 1 to 4 carbon atoms and m is the degree of polymerization, and (2) 80 to 10% by weight of a styrene type polymer and (II) 3 to 15% by weight of at least one member of the group consisting of phosphorus-containing compounds of formula (B): ##STR2## where X is a hydrogen atom, a hydroxyl group, an amino group, a halogen atom, an alkyl group of 1 to 10 carbon atoms, an alkoxy group of 1 to 10 carbon atoms, an alkylthio of 1 to 10 carbon atoms, an aryloxy of 6 of 10 carbon atoms or hydroxy substituted aryloxy of 6 to 10 carbon atoms, Y 1 and Y 2 are each an alkyl of 1 to 8 carbon atoms, an alkoxy of 1 to 8 carbon atoms or an aryl group, Z is an oxygen or sulfur atom, n and p are each an integer of 0 to 4 and q is an integer of 0 or 1. Similar compositions are also prepared including styrene type compounded grafted to the polyphenylene ether and including organic phosphates and organic phosphites and/or melamine, benzoguanamine or their methylol or etherified methylol derivatives.

Inventors

  • 👤 Shinichi Izawa
  • 👤 Jun Sugiyama
  • 👤 Atsuo Nakanishi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 13:47
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/49; C08K5/51; C08K5/53

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 203 words
A flame-retardant polyphenylene ether resin composition comprising (A) 85 to 97% by weight of a resin consisting of (1) 20 to 90% by weight of a polyphenylene ether of the generic formula (A): ##STR31## where R 1 and R 2 are each an alkyl of 1 to 4 carbon atoms and m is the degree of polymerization, and (2) 10 to 80% by weight of a styrene type polymer, and (B) 3 to 15% by weight of at least one member selected from the group consisting of phosphorus-containing compounds of the generic formula (B): ##STR32## where X is a hydrogen atom, a hydroxyl, an amino, a halogen, an alkyl of 1 to 10 carbon atoms, an alkoxy of 1 to 10 carbon atoms, an alkylthio of 1 to 10 carbon atoms, an aryloxy of 6 to 10 carbon atoms or a hydroxyl-substituted aryloxy of 6 to 10 carbon atoms, Y 1 and Y 2 are each an alkyl of 1 to 8 carbon atoms, an alkoxy of 1 to 8 carbon atoms or an aryl group, Z is an oxygen or sulfur atom, n and p are each an integer of 0 to 4 and q is an integer of 0 or 1.
Claim 2
Dependent Claim 203 words
A flame-retardant polyphenylene ether resin composition comprising (A) 85 to 97% by weight of a resin consisting of (1) 20 to 90% by weight of a polyphenylene ether of the generic formula (A): ##STR31## where R 1 and R 2 are each an alkyl of 1 to 4 carbon atoms and m is the degree of polymerization, and (2) 10 to 80% by weight of a styrene type polymer, and (B) 3 to 15% by weight of at least one member selected from the group consisting of phosphorus-containing compounds of the generic formula (B): ##STR32## where X is a hydrogen atom, a hydroxyl, an amino, a halogen, an alkyl of 1 to 10 carbon atoms, an alkoxy of 1 to 10 carbon atoms, an alkylthio of 1 to 10 carbon atoms, an aryloxy of 6 to 10 carbon atoms or a hydroxyl-substituted aryloxy of 6 to 10 carbon atoms, Y 1 and Y 2 are each an alkyl of 1 to 8 carbon atoms, an alkoxy of 1 to 8 carbon atoms or an aryl group, Z is an oxygen or sulfur atom, n and p are each an integer of 0 to 4 and q is an integer of 0 or 1.
Claim 3
Dependent Claim 17 words
The composition according to claim 1, wherein the phosphorus-containing compound is a compound of the formula: ##STR33##
Claim 4
Dependent Claim 17 words
The composition according to claim 1, wherein the phosphorus-containing compound is a compound of the formula: ##STR34##
Claim 5
Dependent Claim 17 words
The composition according to claim 1, wherein the phosphorus-containing compound is a compound of the formula: ##STR35##
Claim 6
Dependent Claim 17 words
The composition according to claim 1, wherein the phosphorus-containing compound is a compound of the formula: ##STR36##
Claim 7
Dependent Claim 17 words
The composition according to claim 1, wherein the phosphorus-containing compound is a compound of the formula: ##STR37##
Claim 8
Dependent Claim 17 words
The composition according to claim 1, wherein the phosphorus-containing compound is a compound of the formula: ##STR38##
Claim 9
Dependent Claim 17 words
The composition according to claim 1, wherein the phosphorus-containing compound is a compound of the formula: ##STR39##
Claim 10
Dependent Claim 18 words
The composition according to claim 1, wherein the polyphenylene ether is a compound of the generic formula: ##STR40##
Claim 11
Dependent Claim 19 words
The composition according to claim 1, wherein the styrene type polymer is polystyrene reinforced with a conjugated diene rubber.
Claim 12
Dependent Claim 251 words
A flame-retardant polyphenylene ether resin composition comprising (A) 80 to 98% by weight of a resin component and (B) 2 to 20% by weight of at least one compound selected from the group consisting of phosphorus-containing compounds of the generic formula (B): ##STR41## where X is a hydrogen atom, a hydroxyl, an amino, a halogen, an alkyl of 1 to 10 carbon atoms, an alkoxy of 1 to 10 carbon atoms, an alkylthio of 1 to 10 carbon atoms, an aryloxy of 6 to 10 carbon atoms or a hydroxyl-substituted aryloxy of 6 to 10 carbon atoms, Y 1 and Y 2 are each an alkyl of 1 to 8 carbon atoms, an alkoxy of 1 to 8 carbon atoms or aryl group, Z is an oxygen or sulfur atom, n and p are each an integer of the value of from 0 to 4 and q is an integer of the value of 0 or 1, said resin component comprising (1) a styrene type compound grafted polyphenylene ether copolymer and (2) a styrene type polymer and containing 20 to 80% by weight, based on the resin component, of a polyphenylene ether of the generic formula (A): ##STR42## where R 1 and R 2 are each an alkyl of 1 to 4 carbon atoms and m is the degree of polymerization, said styrene type compound grafted polyphenylene ether copolymer having 20 to 200 parts by weight of a styrene type compound grafted onto 100 parts by weight of said polyphenylene ether.
Claim 13
Dependent Claim 251 words
A flame-retardant polyphenylene ether resin composition comprising (A) 80 to 98% by weight of a resin component and (B) 2 to 20% by weight of at least one compound selected from the group consisting of phosphorus-containing compounds of the generic formula (B): ##STR41## where X is a hydrogen atom, a hydroxyl, an amino, a halogen, an alkyl of 1 to 10 carbon atoms, an alkoxy of 1 to 10 carbon atoms, an alkylthio of 1 to 10 carbon atoms, an aryloxy of 6 to 10 carbon atoms or a hydroxyl-substituted aryloxy of 6 to 10 carbon atoms, Y 1 and Y 2 are each an alkyl of 1 to 8 carbon atoms, an alkoxy of 1 to 8 carbon atoms or aryl group, Z is an oxygen or sulfur atom, n and p are each an integer of the value of from 0 to 4 and q is an integer of the value of 0 or 1, said resin component comprising (1) a styrene type compound grafted polyphenylene ether copolymer and (2) a styrene type polymer and containing 20 to 80% by weight, based on the resin component, of a polyphenylene ether of the generic formula (A): ##STR42## where R 1 and R 2 are each an alkyl of 1 to 4 carbon atoms and m is the degree of polymerization, said styrene type compound grafted polyphenylene ether copolymer having 20 to 200 parts by weight of a styrene type compound grafted onto 100 parts by weight of said polyphenylene ether.
Claim 14
Dependent Claim 17 words
The composition according to claim 11, wherein the phosphorus-containing compound is a compound of the formula: ##STR43##
Claim 15
Dependent Claim 17 words
The composition according to claim 11, wherein the phosphorus-containing compound is a compound of the formula: ##STR44##
Claim 16
Dependent Claim 17 words
The composition according to claim 11, wherein the phosphorus-containing compound is a compound of the formula: ##STR45##
Claim 17
Dependent Claim 17 words
The composition according to claim 11, wherein the phosphorus-containing compound is a compound of the formula: ##STR46##
Claim 18
Dependent Claim 18 words
The composition according to claim 11, wherein the polyphenylene ether is a compound of the generic formula: ##STR47##
Claim 19
Dependent Claim 19 words
The composition according to claim 11, wherein the styrene type polymer is a polystyrene reinforced with a conjugated rubber.

References Cited (Backward Citations)

US2916510A Cited
US3702878A Cited
US4113795A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-10-14 1984-04-14 1984-10-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-10-14 1988-04-14 1988-10-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-10-14 1992-04-14 1992-10-14 $7700.00 Window Closed / Lapsed

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