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US4228036A Expired / Lapsed US ⏱️ 0.0 years remaining

Alumina-aluminum phosphate-silica-zeolite catalyst

Assignee: Chevron USA Inc
•
Filing: 1979-06-18
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Granted: 1980-10-14
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Expires: 1999-06-18
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Abstract

Abstract A catalyst for cracking gasoline feedstock with greater selectivity to gasoline production and greater metals tolerance comprising an alumina-aluminum phosphate-silica matrix composited with a zeolite having cracking activity.

Inventors

  • 👤 Harold E. Swift
  • 👤 John J. Stanulonis
  • 👤 Elizabeth H. Reynolds

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 08:18
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/08; B01J29/085; B01J29/088; C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C10G11/05; B01J2229/00; B01J2229/30; B01J2229/42

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 144 words
A catalyst for increasing the gasoline yield and quality in a petroleum cracking reaction under catalytic cracking conditions comprising an alumina-aluminum phosphate-silica matrix characterized after calcination at 500° C. for 16 hours as amorphous, and having an average pore radius of from about 10 A to about 200 A; a surface area ranging from about 50 m 2 /g to about 300 m 2 /g; a pore volume of from about 0.1 cc/g to about 1.2 cc/g; and wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio of from about 15:80:5 to about 60:10:30 and wherein said matrix retains at least 70% of its surface area when the matrix is additionally calcined at a temperature up to about 900° C. for about 16 hours; said matrix being composited with from about 5 to about 50 weight percent of a zeolite having cracking activity.
Claim 2
Dependent Claim 144 words
A catalyst for increasing the gasoline yield and quality in a petroleum cracking reaction under catalytic cracking conditions comprising an alumina-aluminum phosphate-silica matrix characterized after calcination at 500° C. for 16 hours as amorphous, and having an average pore radius of from about 10 A to about 200 A; a surface area ranging from about 50 m 2 /g to about 300 m 2 /g; a pore volume of from about 0.1 cc/g to about 1.2 cc/g; and wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio of from about 15:80:5 to about 60:10:30 and wherein said matrix retains at least 70% of its surface area when the matrix is additionally calcined at a temperature up to about 900° C. for about 16 hours; said matrix being composited with from about 5 to about 50 weight percent of a zeolite having cracking activity.
Claim 3
Dependent Claim 25 words
The composition according to claim 1 wherein the alumina-aluminum phosphate-silica matrix has an average pore radius of from about 75 A to about 150 A.
Claim 4
Dependent Claim 27 words
The composition of claim 1 wherein the alumina-aluminum phosphate-silica matrix has a surface area of from about 125 m 2 /g to about 275 m 2 /g.
Claim 5
Dependent Claim 24 words
The composition according to claim 1 wherein the alumina-aluminum phosphate-silica matrix has a pore volume of from about 0.6 cc/g to about 1.0 cc/g.
Claim 6
Dependent Claim 23 words
The composition of claim 1 wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio range of from about 25:65:10 to about 50:30:20.
Claim 7
Dependent Claim 11 words
The composition of claim 1 wherein said zeolite is a REY-zeolite.
Claim 8
Dependent Claim 23 words
The composition according to claim 6 wherein from about 5 to about 35 weight percent REY-zeolite is composited with the alumina-aluminum phosphate-silica matrix.
Claim 9
Dependent Claim 38 words
The composition of claim 6 wherein the REY-zeolite contains a rare earth metal selected from the group consisting of cerium, lanthanum, praseodymium, neodymium, illinium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, scandium, yttrium, lutecium and mixtures thereof.

References Cited (Backward Citations)

US3271299A Cited
US3213035A Cited
US3342750A Cited
US3944482A Cited
US3904550A Cited
US4128592A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-10-14 1984-04-14 1984-10-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-10-14 1988-04-14 1988-10-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-10-14 1992-04-14 1992-10-14 $7700.00 Window Closed / Lapsed

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