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US4228036A
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Alumina-aluminum phosphate-silica-zeolite catalyst
Assignee: Chevron USA Inc
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Filing: 1979-06-18
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Granted: 1980-10-14
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Expires: 1999-06-18
Abstract
Abstract A catalyst for cracking gasoline feedstock with greater selectivity to gasoline production and greater metals tolerance comprising an alumina-aluminum phosphate-silica matrix composited with a zeolite having cracking activity.
Inventors
- 👤 Harold E. Swift
- 👤 John J. Stanulonis
- 👤 Elizabeth H. Reynolds
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 08:18
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/08; B01J29/085; B01J29/088; C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C10G11/05; B01J2229/00; B01J2229/30; B01J2229/42
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
144 words
A catalyst for increasing the gasoline yield and quality in a petroleum cracking reaction under catalytic cracking conditions comprising an alumina-aluminum phosphate-silica matrix characterized after calcination at 500° C. for 16 hours as amorphous, and having an average pore radius of from about 10 A to about 200 A; a surface area ranging from about 50 m 2 /g to about 300 m 2 /g; a pore volume of from about 0.1 cc/g to about 1.2 cc/g; and wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio of from about 15:80:5 to about 60:10:30 and wherein said matrix retains at least 70% of its surface area when the matrix is additionally calcined at a temperature up to about 900° C. for about 16 hours; said matrix being composited with from about 5 to about 50 weight percent of a zeolite having cracking activity.
Claim 2
Dependent Claim
144 words
A catalyst for increasing the gasoline yield and quality in a petroleum cracking reaction under catalytic cracking conditions comprising an alumina-aluminum phosphate-silica matrix characterized after calcination at 500° C. for 16 hours as amorphous, and having an average pore radius of from about 10 A to about 200 A; a surface area ranging from about 50 m 2 /g to about 300 m 2 /g; a pore volume of from about 0.1 cc/g to about 1.2 cc/g; and wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio of from about 15:80:5 to about 60:10:30 and wherein said matrix retains at least 70% of its surface area when the matrix is additionally calcined at a temperature up to about 900° C. for about 16 hours; said matrix being composited with from about 5 to about 50 weight percent of a zeolite having cracking activity.
Claim 3
Dependent Claim
25 words
The composition according to claim 1 wherein the alumina-aluminum phosphate-silica matrix has an average pore radius of from about 75 A to about 150 A.
Claim 4
Dependent Claim
27 words
The composition of claim 1 wherein the alumina-aluminum phosphate-silica matrix has a surface area of from about 125 m 2 /g to about 275 m 2 /g.
Claim 5
Dependent Claim
24 words
The composition according to claim 1 wherein the alumina-aluminum phosphate-silica matrix has a pore volume of from about 0.6 cc/g to about 1.0 cc/g.
Claim 6
Dependent Claim
23 words
The composition of claim 1 wherein the alumina-aluminum phosphate-silica matrix has a mole percent ratio range of from about 25:65:10 to about 50:30:20.
Claim 7
Dependent Claim
11 words
The composition of claim 1 wherein said zeolite is a REY-zeolite.
Claim 8
Dependent Claim
23 words
The composition according to claim 6 wherein from about 5 to about 35 weight percent REY-zeolite is composited with the alumina-aluminum phosphate-silica matrix.
Claim 9
Dependent Claim
38 words
The composition of claim 6 wherein the REY-zeolite contains a rare earth metal selected from the group consisting of cerium, lanthanum, praseodymium, neodymium, illinium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, scandium, yttrium, lutecium and mixtures thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-10-14 | 1984-04-14 | 1984-10-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-10-14 | 1988-04-14 | 1988-10-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-10-14 | 1992-04-14 | 1992-10-14 | $7700.00 | Window Closed / Lapsed |