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US4226952A
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US
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Thermoplastic elastomer blends of alpha-olefin polymers and hydrogenated medium and high vinyl butadiene polymers
Assignee: Bridgestone Firestone Inc
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Filing: 1979-08-20
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Granted: 1980-10-07
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Expires: 1999-08-20
Abstract
Abstract Thermoplastic elastomer blends of alpha-olefin polymers and copolymers, such as polypropylene, polyethylene, etc., having a melting point of at least 90 DEG C. with hydrogenated butadiene medium and high vinyl polymers have good physical properties such as low brittle point, good impact resistance at low temperatures, minimum creep at high temperatures, and good elongation. The blends can be repeatedly processed and still maintain good physical properties. The amount of alpha-olefin polymer or copolymer in the blend may range from about 10 percent to about 60 percent with the amount of the hydrogenated polybutadiene correspondingly ranging from about 90 percent to about 40 percent based on the combined weight of the two components. The blends are mixed at temperatures at least as high as the melting point of the alpha-olefin polymer or copolymer. These blends have excellent ozone resistance and aging properties, as well as excellent paint adhesion.
Inventors
- 👤 Adel F. Halasa
- 👤 David W. Carlson
- 👤 James E. Hall
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 06:17
CPC Classifications
C; C08; C08L; C08L9/00; C08L23/00; C08L23/02; C08L15/00; C08L23/04; C08L23/06; C08L23/10; C08L23/12; C08L23/16
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
104 words
A thermoplastic elastomer composition comprising a blend of (a) a hydrogenated polybutadiene having, prior to hydrogenation, 40-100 percent 1,2-microstructure and said hydrogenation having been effected to remove at least 85 percent of the original unsaturation, and (b) a polymer of at least one alpha-olefin having 2-20 carbon atoms, said alpha-olefin polymer having a melting point of at least 90° C. and having at least 45 percent crystalline structure therein; the amount of said hydrgenated polybutadiene comprising 40-90 percent by weight and the amount of alpha-olefin polymer comprising 10-60 percent by weight, said percentage being based on the combined weight of components (a) and (b).
Claim 2
Dependent Claim
104 words
A thermoplastic elastomer composition comprising a blend of (a) a hydrogenated polybutadiene having, prior to hydrogenation, 40-100 percent 1,2-microstructure and said hydrogenation having been effected to remove at least 85 percent of the original unsaturation, and (b) a polymer of at least one alpha-olefin having 2-20 carbon atoms, said alpha-olefin polymer having a melting point of at least 90° C. and having at least 45 percent crystalline structure therein; the amount of said hydrgenated polybutadiene comprising 40-90 percent by weight and the amount of alpha-olefin polymer comprising 10-60 percent by weight, said percentage being based on the combined weight of components (a) and (b).
Claim 3
Dependent Claim
17 words
The thermoplastic elastomer composition of claim 1 in which said alpha-olefin polymer is a homopolymer of propylene.
Claim 4
Dependent Claim
17 words
The thermoplastic elastomer composition of claim 1 in which said alpha-olefin polymer is a hompolymer of ethylene.
Claim 5
Dependent Claim
19 words
The thermoplastic elastomer composition of claim 1 in which said alpha-olefin polymer is a copolymer of propylene and ethylene.
Claim 6
Dependent Claim
20 words
The thermoplastic elastomer composition of claim 4 in which said copolymer comprises at least 50 percent by weight of propylene.
Claim 7
Dependent Claim
25 words
The thermoplastic elastomer composition of claim 1 in which said hydrogenated polybutadiene is the hydrogenation product of a polybutadiene having at least 50 percent 1,2-microstructure.
Claim 8
Dependent Claim
31 words
The thermoplastic elastomer composition of claim 1 in which the amount of said hydrogenated polybutadiene comprises 52-85 percent by weight and the amount of alpha-olefin polymer comprises 15-48 percent by weight.
Claim 9
Dependent Claim
17 words
The thermoplastic elastomer composition of claim 6 in which said alpha-olefin polymer is a homopolymer of propylene.
Claim 10
Dependent Claim
17 words
The thermoplastic elastomer composition of claim 1 in which said alpha-olefin polymer is isotactic homopolymer of propylene.
Claim 11
Dependent Claim
27 words
The thermoplastic elastomer composition of claim 7 in which there is also present 2-20 parts by weight of polyisobutylene per 100 parts by weight of said blend.
Claim 12
Dependent Claim
22 words
The thermoplastic elastomer composition of claim 1 in which said hydrogenated polybutadiene blend has a melt flow index of at least 1.0.
Claim 13
Dependent Claim
19 words
The thermoplastic elastomer of claim 1 in which said alpha-olefin polymer comprises 30-42 percent by weight of said blend.
Claim 14
Dependent Claim
16 words
The thermoplastic elastomer of claim 12 in which said alpha-olefin polymer is a homopolymer of propylene.
Claim 15
Dependent Claim
27 words
The thermoplastic elastomer of claim 12 in which said alpha-olefin polymer is a copolymer of propylene and ethylene containing at least 50 percent by weight of propylene.
Claim 16
Dependent Claim
38 words
The process for making the thermoplastic elastomer composition of claim 1 comprising the steps of: (1) mixing said alpha-olefin polymer and said hydrogenated polybutadiene polymer and (2) heating said mixture at a temperature of at least 90° C.
Claim 17
Dependent Claim
18 words
The process of claim 15 in which said blend has a melt flow index of at least 1.0.
References Cited (Backward Citations)
US2877206A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-10-07 | 1984-04-07 | 1984-10-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-10-07 | 1988-04-07 | 1988-10-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-10-07 | 1992-04-07 | 1992-10-07 | $7700.00 | Window Closed / Lapsed |