US4225652A
Expired / Lapsed
US
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Transparent sheet material
Assignee: 3M Co
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Filing: 1979-04-09
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Granted: 1980-09-30
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Expires: 1999-04-09
Abstract
Abstract Transparent sheet material comprising a transparent backing having an ink-receptive stratum thereon. The ink-receptive stratum comprises either a mixture of two polymers or individual layers of each polymer. One polymer is the reaction product of an epoxidized, water-insoluble, neutral rubbery polymer and a water-soluble secondary mono amine and the second polymer contains the repeating units ##STR1##
Inventors
- 👤 Elizabeth A. Mercer
- 👤 John F. Eisele
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 18:13
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B05; B05D; B05D5/00; B05D5/04; B32B7/00; B32B7/04; B32B7/12; B41; B41M; B41M5/00; B41M5/50; B41M5/502; B41M5/506; B41M5/52; C; C08; C08J; C08J7/00; C08J7/04; C08J7/043; B32B2307/00; B32B2307/40; B32B2307/412; B41M5/508; B41M5/5236; B41M5/5254; C08J2323/00; C08J2323/02; C08J2323/04; C08J2323/06; C08J2429/00; C08J2429/02; C08J2429/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31924
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
204 words
A sheet material useful in preparing visual transparencies comprising (a) a thin backing which is transparent to visible light; and (b) a continuous ink-receptive stratum on one major surface of said backing wherein said stratum is transparent to visible light and employs (a) a first polymer that is water-soluble, rubbery, alkaline in aqueous solution and consists essentially of the reaction product of a water-soluble secondary mono amine and an epoxidized water-insoluble, neutral, rubbery polymer selected from cis-1,4-polybutadiene, butadiene:styrene copolymer, butadiene:acrylonitrile copolymer and cis-1,4-polyisoprene, and (b) a second polymer that has a weight average molecular weight of at least about 50,000 and contains the repeating units ##STR3## wherein the weight ratio of type I units to type II units in said second polymer is in the range of about 2:1 to 6:1; and wherein said ink-receptive stratum is selected from (i) a single layer comprising a mixture of from about 30% to 70% by weight of said first polymer and from about 70% to 30% by weight of said second polymer, and (ii) a multiple layer comprising a first continuous layer of said first polymer on said backing and a second continuous layer of said second polymer on said first continuous layer of first polymer.
Claim 2
Dependent Claim
204 words
A sheet material useful in preparing visual transparencies comprising (a) a thin backing which is transparent to visible light; and (b) a continuous ink-receptive stratum on one major surface of said backing wherein said stratum is transparent to visible light and employs (a) a first polymer that is water-soluble, rubbery, alkaline in aqueous solution and consists essentially of the reaction product of a water-soluble secondary mono amine and an epoxidized water-insoluble, neutral, rubbery polymer selected from cis-1,4-polybutadiene, butadiene:styrene copolymer, butadiene:acrylonitrile copolymer and cis-1,4-polyisoprene, and (b) a second polymer that has a weight average molecular weight of at least about 50,000 and contains the repeating units ##STR3## wherein the weight ratio of type I units to type II units in said second polymer is in the range of about 2:1 to 6:1; and wherein said ink-receptive stratum is selected from (i) a single layer comprising a mixture of from about 30% to 70% by weight of said first polymer and from about 70% to 30% by weight of said second polymer, and (ii) a multiple layer comprising a first continuous layer of said first polymer on said backing and a second continuous layer of said second polymer on said first continuous layer of first polymer.
Claim 3
Dependent Claim
18 words
A sheet material according to claim 1 wherein said ink-receptive stratum comprises said multiple layer on said backing.
Claim 4
Dependent Claim
38 words
A sheet material according to claim 1 wherein said ink-receptive stratum is a mixture comprising from about 30% to 70% by weight of said first polymer and from about 70% to 30% by weight of said second polymer.
Claim 5
Dependent Claim
21 words
A sheet material according to claim 3 wherein an adhesion promoting layer is interposed between said backing and said ink-receptive stratum.
Claim 6
Dependent Claim
35 words
A sheet material according to claim 3 wherein said ink-receptive stratum comprises from about 50% to 70% by weight of said first polymer and from about 50% to 30% by weight of said second polymer.
Claim 7
Dependent Claim
29 words
A sheet material according to claim 5 wherein said ink-receptive stratum comprises about 65% by weight of said first polymer and about 35% by weight of said second polymer.
Claim 8
Dependent Claim
25 words
A sheet material according to claim 1 wherein said first polymer consists essentially of the reaction product of a water-soluble secondary mono amine and cis-1,4-polybutadiene.
Claim 9
Dependent Claim
14 words
A sheet material according to claim 7 wherein said secondary mono amine is dimethylamine.
Claim 10
Dependent Claim
34 words
A sheet material according to claim 8 wherein the weight ratio of said type I units to said type II units in said second polymer is in the range of about 3:1 to 4:1.
Claim 11
Dependent Claim
20 words
A sheet material according to claim 9 wherein the weight average molecular weight of said second polymer is about 125,000.
References Cited (Backward Citations)
US3661874A
Cited
US4079160A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-09-30 | 1984-03-31 | 1984-09-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-09-30 | 1988-03-31 | 1988-09-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-09-30 | 1992-03-31 | 1992-09-30 | $7700.00 | Window Closed / Lapsed |