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US4224183A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of a titanium component for polymerization catalysts of the Ziegler-Natta type

Assignee: BASF SE
•
Filing: 1979-07-05
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Granted: 1980-09-23
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Expires: 1999-07-05
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Abstract

Abstract A special process for the preparation of a titanium component for polymerization catalysts of the Ziegler-Natta type, wherein (1) in a first stage (1.1) an alcoholate of the formula Mr(OR) 2 , where R is lower alkyl and (1.2) a chlorotoluene of the formula ##STR1## where X is chlorine or hydrogen, are milled together in a particular molar ratio in a vibratory ball mill under particular milling conditions, especially a relatively low temperature, in the absence of a diluent, thereafter (2) in a second stage (2.1) the material resulting from stage (1) is brought together with (2.2) titanium tetrachloride in a particular ratio, the batch is kept for some time at an elevated temperature, with constant mixing, and the resulting solid is isolated, excess titanium tetrachloride being separated off, and finally (3) in a third stage (3.1) the solid resulting from stage (2) is again brought together with (3.2) titanium tetrachloride in a particular ratio, the batch is again kept for some time at an elevated temperature, with constant mixing, and the resulting solid, constituting the novel titanium component, is isolated, excess titanium tetrachloride being removed. The novel titanium compound permits the production of polymers of α-monoolefins not only in high yield but also with high isotacticity.

Inventors

  • 👤 Gerhard Staiger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 13:29
CPC Classifications
C; C08; C08F; C08F10/00

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 256 words
A process for the preparation of a titanium component for polymerization catalysts of the Ziegler-Natta type, wherein (1) in a first stage (1.1) 100 parts by weight of an alcoholate of the general formula Mg(OR) 2 , where R is alkyl of 1 to 6 carbon atoms, are milled with (1.2) the appropriate number of parts by weight of a chlorotoluene of the formula ##STR3## where X is chlorine or hydrogen, to correspond to a molar ratio of alcoholate (1.1):chlorine in the chlorotoluene (1.2) of from 100:1 to 100:100 in a vibratory ball mill under a milling acceleration of from 30 to 80 m×sec -2 for a period of from 5 to 100 hours at from -50° to +10° C. in the absence of a diluent, thereafter (2) in a second stage (2.1) 100 parts by weight of the material resulting from stage (1) and (2.2) from 300 to 1,800 parts by weight of titanium tetrachloride are brought together, the batch is kept for from 0.1 to 5 hours at from 40° to 180° C., with constant mixing, and the resulting solid is isolated, excess titanium tetrachloride being separated off, and finally (3) in a third stage (3.1) 100 parts by weight of the solid resulting from stage (2) are again brought together with (3.2) from 300 to 1,800 parts by weight of titanium tetrachloride, the batch is kept for from 0.1 to 5 hours at from 40 to 180° C., with constant mixing, and the resulting solid is isolated, excess titanium tetrachloride being separated off.
Claim 2
Dependent Claim 256 words
A process for the preparation of a titanium component for polymerization catalysts of the Ziegler-Natta type, wherein (1) in a first stage (1.1) 100 parts by weight of an alcoholate of the general formula Mg(OR) 2 , where R is alkyl of 1 to 6 carbon atoms, are milled with (1.2) the appropriate number of parts by weight of a chlorotoluene of the formula ##STR3## where X is chlorine or hydrogen, to correspond to a molar ratio of alcoholate (1.1):chlorine in the chlorotoluene (1.2) of from 100:1 to 100:100 in a vibratory ball mill under a milling acceleration of from 30 to 80 m×sec -2 for a period of from 5 to 100 hours at from -50° to +10° C. in the absence of a diluent, thereafter (2) in a second stage (2.1) 100 parts by weight of the material resulting from stage (1) and (2.2) from 300 to 1,800 parts by weight of titanium tetrachloride are brought together, the batch is kept for from 0.1 to 5 hours at from 40° to 180° C., with constant mixing, and the resulting solid is isolated, excess titanium tetrachloride being separated off, and finally (3) in a third stage (3.1) 100 parts by weight of the solid resulting from stage (2) are again brought together with (3.2) from 300 to 1,800 parts by weight of titanium tetrachloride, the batch is kept for from 0.1 to 5 hours at from 40 to 180° C., with constant mixing, and the resulting solid is isolated, excess titanium tetrachloride being separated off.

References Cited (Backward Citations)

US3560146A Cited
US4079175A Cited
US4168361A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-09-23 1984-03-24 1984-09-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-09-23 1988-03-24 1988-09-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-09-23 1992-03-24 1992-09-23 $7700.00 Window Closed / Lapsed

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