US4224181A
Expired / Lapsed
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Ziegler type catalyst system
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1979-03-07
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Granted: 1980-09-23
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Expires: 1999-03-07
Abstract
Abstract A new improved Ziegler type catalyst system for alpha-olefin type polymerization includes R'3Y or R'2YX and mixtures thereof, at least one Group IVB -VIII transition metal halide and an alkyl metal compound selected from R'2YNR2 and R'XYNR2, wherein Y is Al, Ga or In and at least one Lewis base. The improved catalyst system provides increased polymerization activity without significantly affecting the crystallinity of the polymer.
Inventors
- 👤 Arthur W. Langer, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 21:18
CPC Classifications
C; C08; C08F; C08F10/00; C08F4/00; C08F4/02; C08F4/022
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
230 words
A catalyst composition which comprises a mixture of: (a) at least one supported Group IVB to VIII transition metal halide; (b) a trialkyl metal cocatalyst, said trialkyl metal cocatalyst having the structure of R' 3 Y wherein R' is selected from the group consisting of C 1 to C 20 primary alkyl, secondary alkyl, tertiary alkyl, neopentyl alkyl, branched alkyl, naphthenic or aralkyl groups and Y is selected from the group consisting of aluminum, gallium and indium; (c) a nitrogen-containing metal alkyl compound, the structure of said nitrogen-containing metal alkyl compound being selected from the group consisting of R'.sub.2 YNR.sub.2 or R'XYNR.sub.2 wherein Y is selected from the group consisting of Al, Ga and In, X is a halide and R' is a C 1 to C 20 primary alkyl, secondary alkyl, tertiary alkyl, neopentyl alkyl, branched alkyl, naphthenic or aralkyl group and R is selected from the group consisting of C 3 to C 20 bulky alkyl, cycloalkyl, aryl, the proviso that the two R groups can be taken with N to form a pyrrolidyl or piperidyl and the alkyl substituted derivatives of pyrrolidyl and piperidyl, said compound being in a mole ratio of about 0.5 to about 200 of said compound to said transition metal compound, and (d) at least one Lewis base said Lewis base not causing excessive cleavage of metal-carbon bonds or loss of active sites.
Claim 2
Dependent Claim
230 words
A catalyst composition which comprises a mixture of: (a) at least one supported Group IVB to VIII transition metal halide; (b) a trialkyl metal cocatalyst, said trialkyl metal cocatalyst having the structure of R' 3 Y wherein R' is selected from the group consisting of C 1 to C 20 primary alkyl, secondary alkyl, tertiary alkyl, neopentyl alkyl, branched alkyl, naphthenic or aralkyl groups and Y is selected from the group consisting of aluminum, gallium and indium; (c) a nitrogen-containing metal alkyl compound, the structure of said nitrogen-containing metal alkyl compound being selected from the group consisting of R'.sub.2 YNR.sub.2 or R'XYNR.sub.2 wherein Y is selected from the group consisting of Al, Ga and In, X is a halide and R' is a C 1 to C 20 primary alkyl, secondary alkyl, tertiary alkyl, neopentyl alkyl, branched alkyl, naphthenic or aralkyl group and R is selected from the group consisting of C 3 to C 20 bulky alkyl, cycloalkyl, aryl, the proviso that the two R groups can be taken with N to form a pyrrolidyl or piperidyl and the alkyl substituted derivatives of pyrrolidyl and piperidyl, said compound being in a mole ratio of about 0.5 to about 200 of said compound to said transition metal compound, and (d) at least one Lewis base said Lewis base not causing excessive cleavage of metal-carbon bonds or loss of active sites.
Claim 3
Dependent Claim
9 words
The composition of claim 1 wherein Y is aluminum.
Claim 4
Dependent Claim
37 words
The composition of claim 1 wherein said trialkyl metal cocatalyst is a trialkyl aluminum cocatalyst at a molar ratio of about 1 to 50 to about 50 to 1 based on said nitrogen containing metal alkyl compound.
Claim 5
Dependent Claim
15 words
The composition of claim 1 wherein said nitrogen containing metal alkyl compound is diethylaluminum diisopropylamide.
Claim 6
Dependent Claim
15 words
The composition of claim 1 wherein said nitrogen containing metal alkyl compound is diethylaluminum dicyclohexylamide.
Claim 7
Dependent Claim
29 words
The composition of claim 1 wherein said transition metal compound is selected from the group consisting essentially of TiCl 3 on a support and TiCl 4 on a support.
Claim 8
Dependent Claim
12 words
The composition of claim 1 wherein said support is MgCl 2 .
Claim 9
Dependent Claim
22 words
The composition of claim 1 wherein said Lewis base is selected from the group consisting of amines, esters, phosphines, ethers, and amides.
Claim 10
Dependent Claim
12 words
The composition of claim 1 wherein said Lewis base is an ester.
Claim 11
Dependent Claim
14 words
The composition of claims 4 or 5 wherein said Lewis base is ethyl benzoate.
Claim 12
Dependent Claim
11 words
The composition of claim 1 wherein said Lewis base is hindered.
Claim 13
Dependent Claim
27 words
The composition of claim 1 wherein said Lewis base is selected from the group consisting of sulfoxides, phosphine oxides, phosphates, phosphites, epoxides and saturated and unsaturated heterocycles.
Claim 14
Dependent Claim
27 words
The composition of claim 11 wherein said Lewis base is selected from the group consisting of piperidines, pyrrolidines, ketones, tetrahydrofurans, secondary and tertiary aliphatic and aromatic amines.
Claim 15
Dependent Claim
15 words
The composition of claim 1 wherein said nitrogen containing metal alkyl compound is diethylaluminum 2,2,6,6-tetramethylpiperidide.
Claim 16
Dependent Claim
17 words
The composition of claim 1 wherein said nitrogen containing metal alkyl compound is diethyl aluminum diorthotolyl amide.
Claim 17
Dependent Claim
11 words
The composition of claim 1 wherein said R groups are aryl.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-09-23 | 1984-03-24 | 1984-09-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-09-23 | 1988-03-24 | 1988-09-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-09-23 | 1992-03-24 | 1992-09-23 | $7700.00 | Window Closed / Lapsed |