US4224141A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Manufacture of aromatic compounds
Assignee: Mobil Oil AS
•
Filing: 1979-05-21
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Granted: 1980-09-23
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Expires: 1999-05-21
Abstract
Abstract Isomerization of xylenes admixed with other alkyl aromatics of at least eight carbon atoms is conducted at essentially atmospheric pressure at 800 DEG -1000 DEG F. with a zeolite like zeolite ZSM-5 of reduced acid activity.
Inventors
- 👤 Roger A. Morrison
- 👤 Samuel A. Tabak
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 21:50
CPC Classifications
C; C07; C07C; C07C15/00; C07C15/02; C07C15/067; C07C15/08; B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/40; C07C4/00; C07C4/08; C07C4/12; C07C4/14; C07C4/18; C07C5/00; C07C5/22; C07C5/27; C07C5/2729; C07C5/2732; C07C5/2737; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/36; B01J2229/42; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/40; C10; C10G; C10G2400/00; C10G2400/30; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52
Claims Analysis
Total Claims: 44
Claim 1
Independent Claim
271 words
A new use of known apparatus for simultaneously isomerizing xylenes and converting ethylbenzene to products readily separable by distillation from the mixture of C 8 aromatics by contacting a mixture of C 8 aromatics with a catalyst at conversion conditions of elevated temperature and low pressure in a loop comprising an isomerization reactor for the contact aforesaid, distillation means for separating C 8 aromatics from lower boiling and higher boiling hydrocarbons, means to transfer hydrocarbon effluent of said isomerization reactor to said distillation means, mixing means for mixing fresh feed C 8 aromatics containing xylenes and ethylbenzene with C 8 aromatics separated by said distillation means, a xylene separator for recovery of para xylene, means for transfer of mixed C 8 aromatics from said mixing means to said xylene separator, and means to transfer C 8 aromatics lean in para xylene from said xylene separator to said isomerization reactor, which new use comprises contacting, in the isomerization reactor of said known apparatus, a vapor phase mixture of said C 8 aromatics lean in para xylene and fresh charge material containing alkyl benzenes of more than eight carbon atoms with a zeolite catalyst at a temperature of about 800°-1000° F., a pressure of less than 100 pounds per square inch and a weight hourly space velocity between 1 and about 200; said zeolite catalyst having a constraint index of 1 to 12, a silica to alumina ratio greater than 12 and a reduced activity such that less than 2 weight percent of xylene is converted to other compounds when contacted with said catalyst at 900° F., 0 psig and LHSV of 5.
Claim 2
Dependent Claim
271 words
A new use of known apparatus for simultaneously isomerizing xylenes and converting ethylbenzene to products readily separable by distillation from the mixture of C 8 aromatics by contacting a mixture of C 8 aromatics with a catalyst at conversion conditions of elevated temperature and low pressure in a loop comprising an isomerization reactor for the contact aforesaid, distillation means for separating C 8 aromatics from lower boiling and higher boiling hydrocarbons, means to transfer hydrocarbon effluent of said isomerization reactor to said distillation means, mixing means for mixing fresh feed C 8 aromatics containing xylenes and ethylbenzene with C 8 aromatics separated by said distillation means, a xylene separator for recovery of para xylene, means for transfer of mixed C 8 aromatics from said mixing means to said xylene separator, and means to transfer C 8 aromatics lean in para xylene from said xylene separator to said isomerization reactor, which new use comprises contacting, in the isomerization reactor of said known apparatus, a vapor phase mixture of said C 8 aromatics lean in para xylene and fresh charge material containing alkyl benzenes of more than eight carbon atoms with a zeolite catalyst at a temperature of about 800°-1000° F., a pressure of less than 100 pounds per square inch and a weight hourly space velocity between 1 and about 200; said zeolite catalyst having a constraint index of 1 to 12, a silica to alumina ratio greater than 12 and a reduced activity such that less than 2 weight percent of xylene is converted to other compounds when contacted with said catalyst at 900° F., 0 psig and LHSV of 5.
Claim 3
Dependent Claim
15 words
The new use defined by claim 1 wherein said zeolite is in the acid form.
Claim 4
Dependent Claim
17 words
The new use defined by claim 1, wherein said silica to alumina ratio is greater than 200.
Claim 5
Dependent Claim
17 words
The new use defined by claim 1, wherein said silica to alumina ratio is greater than 500.
Claim 6
Dependent Claim
17 words
The new use defined by claim 1 wherein said contacting is conducted in the absence of hydrogen.
Claim 7
Dependent Claim
28 words
The new use defined by claim 1 wherein said zeolite is dispersed in a solid matrix which constitutes at least 90% of the composite of zeolite and matrix.
Claim 8
Dependent Claim
150 words
In a process for isomerizing the xylene content of a charge mixture of eight carbon atoms aromatic hydrocarbon compounds which mixture contains xylene, and ethylbenzene by contact at conversion conditions with a catalyst comprising a zeolite having a silica/alumina ratio greater than 12 and a constraint index of 1 to 12, the improvement resulting in conversion of ethylbenzene to benzene and conversion of higher alkyl benzenes to benzene, toluene and xylene which comprises including in the charge mixture alkyl aromatics of more than eight carbon atoms, maintaining the conversion pressure at less than 100 pounds per square inch and the conversion temperature at about 800° F. to 1000° F. and using such catalyst comprising a zeolite of reduced acid activity such that less than 2 weight percent of xylene is converted to compounds other than xylene when contacted with said catalyst at 900° F. 0 psig and LHSV of 5.
Claim 9
Dependent Claim
150 words
In a process for isomerizing the xylene content of a charge mixture of eight carbon atoms aromatic hydrocarbon compounds which mixture contains xylene, and ethylbenzene by contact at conversion conditions with a catalyst comprising a zeolite having a silica/alumina ratio greater than 12 and a constraint index of 1 to 12, the improvement resulting in conversion of ethylbenzene to benzene and conversion of higher alkyl benzenes to benzene, toluene and xylene which comprises including in the charge mixture alkyl aromatics of more than eight carbon atoms, maintaining the conversion pressure at less than 100 pounds per square inch and the conversion temperature at about 800° F. to 1000° F. and using such catalyst comprising a zeolite of reduced acid activity such that less than 2 weight percent of xylene is converted to compounds other than xylene when contacted with said catalyst at 900° F. 0 psig and LHSV of 5.
Claim 10
Dependent Claim
14 words
A process according to claim 7 wherein said zeolite is in the acid form.
Claim 11
Dependent Claim
11 words
A process according to claim 7 wherein said zeolite is ZSM-5.
Claim 12
Dependent Claim
13 words
A process according to claim 7 wherein said zeolite comprising alkali meal cations.
Claim 13
Dependent Claim
15 words
A process according to claim 7 wherein said charge mixture is free of elemental hydrogen.
Claim 14
Dependent Claim
15 words
A process according to claim 7 wherein said zeolite is ZSM-5 which has been steamed.
Claim 15
Dependent Claim
27 words
A process according to claim 7 resulting in conversion of ethylbenzene to benzene at substantially no loss of xylene in the product as compared to the charge.
Claim 16
Dependent Claim
14 words
A process according to claim 7 wherein the said charge mixture contains paraffin hydrocarbons.
Claim 17
Dependent Claim
16 words
A process according to claim 7 wherein the said charge mixture consists essentially of aromatic hydrocarbons.
Claim 18
Dependent Claim
14 words
A process according to claim 7 wherein said silica/alumina ratio is greater than 200.
Claim 19
Dependent Claim
14 words
A process according to claim 7 wherein said silica/alumina ratio is greater than 500.
Claim 20
Dependent Claim
214 words
A process for the manufacture of aromatic hydrocarbons which comprises subjecting a hydrocarbon naphtha to catalytic reforming under conditions to convert naphthenes to aromatic hydrocarbons in a reformate reaction product, distilling said reformate to separate compounds of less than eight carbons from a heavy reformate, mixing said heavy reformate with a recycle steam hereafter defined, contacting the resultant mixture at pressure less than 100 pounds per square inch and a temperature of about 800°-1000° F. with a zeolite catalyst having a constraint index of 1 to 12, a silica/alumina ratio above about 12 and reduced acid activity such that less than 2 weight percent of xylene is converted to compounds other than xylene when contacted with said catalyst at 900° F., 0 psig and LHSV of 5, whereby to isomerize xylene content of said mixutre and to convert ethylbenzene and alkylbenzenes of more than eight carbon atoms to benzene, toluene and xylene, distilling the product of said contacting to separate compounds of less than eight carbon atoms and compounds of more than eight carbon atoms from a C 8 fraction, recovering at least one xylene isomer from said C 8 fraction to provide a stream lean in said recovered isomer and mixing said lean stream with said heavy reformate as the recycle steam aforesaid.
Claim 21
Dependent Claim
214 words
A process for the manufacture of aromatic hydrocarbons which comprises subjecting a hydrocarbon naphtha to catalytic reforming under conditions to convert naphthenes to aromatic hydrocarbons in a reformate reaction product, distilling said reformate to separate compounds of less than eight carbons from a heavy reformate, mixing said heavy reformate with a recycle steam hereafter defined, contacting the resultant mixture at pressure less than 100 pounds per square inch and a temperature of about 800°-1000° F. with a zeolite catalyst having a constraint index of 1 to 12, a silica/alumina ratio above about 12 and reduced acid activity such that less than 2 weight percent of xylene is converted to compounds other than xylene when contacted with said catalyst at 900° F., 0 psig and LHSV of 5, whereby to isomerize xylene content of said mixutre and to convert ethylbenzene and alkylbenzenes of more than eight carbon atoms to benzene, toluene and xylene, distilling the product of said contacting to separate compounds of less than eight carbon atoms and compounds of more than eight carbon atoms from a C 8 fraction, recovering at least one xylene isomer from said C 8 fraction to provide a stream lean in said recovered isomer and mixing said lean stream with said heavy reformate as the recycle steam aforesaid.
Claim 22
Dependent Claim
11 words
A process according to claim 18 wherein said zeolite is ZSM-5.
Claim 23
Dependent Claim
14 words
A process according to claim 18 wherein said zeolite is in the acid form.
Claim 24
Dependent Claim
16 words
A process according to claim 18 wherein said contacting is conducted in the absence of hydrogen.
Claim 25
Dependent Claim
19 words
A process according to claim 18 wherein said heavy reformate is treated with a solvent to separate paraffins therefrom.
Claim 26
Dependent Claim
13 words
A process according to claim 18 wherein said heavy reformate contains paraffin hydrocarbons.
Claim 27
Dependent Claim
14 words
A process according to claim 18 wherein said silica/alumina ratio is greater than 200.
Claim 28
Dependent Claim
14 words
A process according to claim 18 wherein said silica/alumina ratio is greater than 500.
Claim 29
Dependent Claim
187 words
In a process for manufacture of a desired xylene isomer which comprises separating the desired xylene isomer from a mixture containing the three xylene isomers, isomerizing the resultant mixture lean in at least one isomer to generate additional amounts of said desired isomer, separating compounds of boiling point higher and lower than xylenes from the isomerization product to provide a recycle stream, mixing said recycle stream with additional aromatic compounds of eight carbon atoms including the three xylene isomers and supplying the resultant mixture to the step aforesaid of separating a desired isomer, the improvement which comprises isomerizing the said mixture lean in a desired isomer at a temperature of about 800°-1000° F., a pressure less than 100 pounds per square inch and a weight hourly space velocity between 1 and about 200 by contact with a zeolite catalyst having a constraint index of 1 to 12, a silica to alumina ratio greater than 12 and a reduced activity such that less than 2 weight percent of xylene is converted to other compounds when contacts with said catalyst at 900° F., 0 psig and LHSV of 5.
Claim 30
Dependent Claim
187 words
In a process for manufacture of a desired xylene isomer which comprises separating the desired xylene isomer from a mixture containing the three xylene isomers, isomerizing the resultant mixture lean in at least one isomer to generate additional amounts of said desired isomer, separating compounds of boiling point higher and lower than xylenes from the isomerization product to provide a recycle stream, mixing said recycle stream with additional aromatic compounds of eight carbon atoms including the three xylene isomers and supplying the resultant mixture to the step aforesaid of separating a desired isomer, the improvement which comprises isomerizing the said mixture lean in a desired isomer at a temperature of about 800°-1000° F., a pressure less than 100 pounds per square inch and a weight hourly space velocity between 1 and about 200 by contact with a zeolite catalyst having a constraint index of 1 to 12, a silica to alumina ratio greater than 12 and a reduced activity such that less than 2 weight percent of xylene is converted to other compounds when contacts with said catalyst at 900° F., 0 psig and LHSV of 5.
Claim 31
Dependent Claim
13 words
The process of claim 26 wherein said zeolite is in the acid form.
Claim 32
Dependent Claim
15 words
The process of claim 26 wherein said silica to alumina ratio is greater than 200.
Claim 33
Dependent Claim
15 words
The process of claim 26 wherein said silica to alumina ratio is greater than 500.
Claim 34
Dependent Claim
16 words
The process of claim 26 wherein said zeolite has been steamed to achieve said reduced activity.
Claim 35
Dependent Claim
30 words
The process of claim 26 wherein said zeolite is composited with an inert matrix material in an amount such that the inert matrix constitutes at least 90% of the composite.
Claim 36
Dependent Claim
12 words
The process of claim 26 wherein said zeolite contains alkali metal cations.
Claim 37
Dependent Claim
22 words
The process of claim 1 wherein the pressure of contacting said fresh charge material with said zeolite catalyst is below 50 psig.
Claim 38
Dependent Claim
14 words
The process of claim 7 wherein the said conversion pressure is below 50 psig.
Claim 39
Dependent Claim
21 words
The process of claim 18 wherein the pressure of contacting said resultant mixture with a zeolite catalyst is below 50 psig.
Claim 40
Dependent Claim
16 words
The process of claim 26 wherein the pressure of isomerizing said mixture is below 50 psig.
Claim 41
Dependent Claim
24 words
The process of claim 1 wherein the pressure of contacting said fresh charge material with said zeolite catalyst is at or below one atmosphere.
Claim 42
Dependent Claim
16 words
The process of claim 7 wherein the said conversion pressure is at or below one atmosphere.
Claim 43
Dependent Claim
23 words
The process of claim 18 wherein the pressure of contacting said resultant mixture with a zeolite catalyst is at or below one atmosphere.
Claim 44
Dependent Claim
18 words
The process of claim 26 wherein the pressure of isomerizing said mixture is at or below one atmosphere.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-09-23 | 1984-03-24 | 1984-09-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-09-23 | 1988-03-24 | 1988-09-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-09-23 | 1992-03-24 | 1992-09-23 | $7700.00 | Window Closed / Lapsed |