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US3856872A Expired / Lapsed US ⏱️ 0.0 years remaining

Xylene isomerization

Assignee: Mobil Oil AS
•
Filing: 1973-09-13
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Granted: 1974-12-24
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Expires: 1993-09-13
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Abstract

Abstract An improved catalyst for use in Octafining plants is characterized by a zeolite of the ZSM-5 type of zeolite ZSM-12 or zeolite ZSM-21. With substitution of a zeolite catalyst for platinum on silica alumina, the process operates at very high space velocities as calculated with respect to the active zeolite component of the catalyst. Typically the space velocity with respect to zeolite component may be 1 to 200 unit weights of charge per unit weight of zeolite per hour.

Inventors

  • 👤 R Morrison

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 21:24
CPC Classifications
C; C07; C07C; C07C15/00; C07C15/02; C07C15/067; C07C15/073; C07C5/00; C07C5/22; C07C5/27; C07C5/2702; C07C5/2708; C07C5/2729; C07C5/2732; C07C5/2754; Y; Y10; Y10S; Y10S585/00; Y10S585/8995; Y10S585/905

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 251 words
A NEW USE OF THE KNOWN APPARATUS FOR SIMULTANEOUSLY ISOMERIZING XYLNES AND CONVERTING ETHYL BRNZENE TO PRODUCTS READILY SEPARABLE BY DISTILLATION FROM THE MIXTURE OF C8 AROMATICS BY CONTACTING A MIXTURE OF C8 AROMATICS AND HYDROGEN WITH A PLATINUM ON SILICA-ALUMINA CATALYST AT PRESSURE OF 175 TO 225 POUNDS PER SQUARE INCH, A TEMPERATURE OF 830 TO 900*F. AND LIQUID HOURLY SPACE VELOCITY OF 0.6 TO 1.6 LIQUID VOLUMES OF HYDROCARBON PER VOLUME OF CATALYST PER HOUR IN A LOOP COMPRISING AN ISOMERIZATION REACTOR FOR THE CONTACT AFORESAID, DISTILLATION MEANS FOR SEPARATING C8 AROMATICS FROM LOWER BOILING AND HIGHER BOILING HYDROCARBONS, MEANS TO TRANSFER HYDROCARBON EFFLUENT OF SAID ISOMERIZATION REACTOR TO SAID DISTILLATION MEANS, MIXING MEANS FOR MIXING FRESH FEED C8 AROMATICS CONTAINING XYLENE AND ETHYL BENZENE WITH C8 AROMATICS SEPARATED BY DISTILLATION MEANS, A XYLENE SEPARATOR FOR RECOVERY OF PAR XYLENE, MEANS FOR TRANSFER OF MIXED C8 AROMATICS FROM SAID MIXING MEANS TO SAID XYLENE SEPARATOR, AND MEANS TO TRANSFER C8 AROMATICS LEAN IN PARA XYLENE FROM SAID XYLENE SEPARATOR TO SAID ISOMERIZATION REACTOR; WHICH NEW USE COMPRISES CONTACTING, IN THE ISOMERIZATION REACTION OF SAID KNOWN APPARATUS, A VAPOR PHASE MIXTURE OF HYDROGEN AND SAID C8 AROMATICS LEAN IN PARA XYLENE WITH A ZEOLITE CATALYST OF THE ZSM-5 TYPE OR ZEOLITE ZSM-12 OR ZEOLITE ZSM-21 AT A TEMPERATURE OF 550 TO 900*F., A PRESSURE OF 150 TO 300 POUNDS PER SQUARE INCH AND A WEIGHT HOURLY SPACE VELOCITY WITH RESPECT TO SAID ZEOLITE ALONE BETWEEN ABOUT 1 AND ABOUT 200.
Claim 2
Dependent Claim 251 words
A NEW USE OF THE KNOWN APPARATUS FOR SIMULTANEOUSLY ISOMERIZING XYLNES AND CONVERTING ETHYL BRNZENE TO PRODUCTS READILY SEPARABLE BY DISTILLATION FROM THE MIXTURE OF C8 AROMATICS BY CONTACTING A MIXTURE OF C8 AROMATICS AND HYDROGEN WITH A PLATINUM ON SILICA-ALUMINA CATALYST AT PRESSURE OF 175 TO 225 POUNDS PER SQUARE INCH, A TEMPERATURE OF 830 TO 900*F. AND LIQUID HOURLY SPACE VELOCITY OF 0.6 TO 1.6 LIQUID VOLUMES OF HYDROCARBON PER VOLUME OF CATALYST PER HOUR IN A LOOP COMPRISING AN ISOMERIZATION REACTOR FOR THE CONTACT AFORESAID, DISTILLATION MEANS FOR SEPARATING C8 AROMATICS FROM LOWER BOILING AND HIGHER BOILING HYDROCARBONS, MEANS TO TRANSFER HYDROCARBON EFFLUENT OF SAID ISOMERIZATION REACTOR TO SAID DISTILLATION MEANS, MIXING MEANS FOR MIXING FRESH FEED C8 AROMATICS CONTAINING XYLENE AND ETHYL BENZENE WITH C8 AROMATICS SEPARATED BY DISTILLATION MEANS, A XYLENE SEPARATOR FOR RECOVERY OF PAR XYLENE, MEANS FOR TRANSFER OF MIXED C8 AROMATICS FROM SAID MIXING MEANS TO SAID XYLENE SEPARATOR, AND MEANS TO TRANSFER C8 AROMATICS LEAN IN PARA XYLENE FROM SAID XYLENE SEPARATOR TO SAID ISOMERIZATION REACTOR; WHICH NEW USE COMPRISES CONTACTING, IN THE ISOMERIZATION REACTION OF SAID KNOWN APPARATUS, A VAPOR PHASE MIXTURE OF HYDROGEN AND SAID C8 AROMATICS LEAN IN PARA XYLENE WITH A ZEOLITE CATALYST OF THE ZSM-5 TYPE OR ZEOLITE ZSM-12 OR ZEOLITE ZSM-21 AT A TEMPERATURE OF 550 TO 900*F., A PRESSURE OF 150 TO 300 POUNDS PER SQUARE INCH AND A WEIGHT HOURLY SPACE VELOCITY WITH RESPECT TO SAID ZEOLITE ALONE BETWEEN ABOUT 1 AND ABOUT 200.
Claim 3
Dependent Claim 15 words
The new use defined by claim 1 wherein said zeolite is in the acid form.
Claim 4
Dependent Claim 24 words
The new use defined by claim 1 wherein a metal of Group VIII or a compound of such metal is associated with said zeolite.
Claim 5
Dependent Claim 16 words
The new use defined by claim 1 wherein said zeolite is dispersed in a solid matrix.
Claim 6
Dependent Claim 28 words
The new use defined by claim 4 wherein the composite of zeolite and matrix is admixed with a greater volume of discrete particles of an inert, solid diluent.
Claim 7
Dependent Claim 82 words
A process for the isomerization of xylenes in a mixture of xylenes with ethyl benzene which comprises contacting a C8 aromatic fraction containing both xylenes and ethyl benzene in vapor phase admixed with hydrogen with a zeolite catalyst of the ZSM-5 type or zeolite ZSM-12 or zeolite ZSM-21 at a temperature of 550* to 900*F., a pressure of 150 to 300 pounds per square inch and a weight hourly space velocity with respect to said zeolite alone betwen 1 and about 200.
Claim 8
Dependent Claim 82 words
A process for the isomerization of xylenes in a mixture of xylenes with ethyl benzene which comprises contacting a C8 aromatic fraction containing both xylenes and ethyl benzene in vapor phase admixed with hydrogen with a zeolite catalyst of the ZSM-5 type or zeolite ZSM-12 or zeolite ZSM-21 at a temperature of 550* to 900*F., a pressure of 150 to 300 pounds per square inch and a weight hourly space velocity with respect to said zeolite alone betwen 1 and about 200.
Claim 9
Dependent Claim 14 words
The process defined by claim 6 wherein said zeolite is in the acid form.
Claim 10
Dependent Claim 22 words
The process defined by claim 6 wherein a metal of Group VIII or a compound of such metal is associated with zeolite.
Claim 11
Dependent Claim 16 words
The process defined by claim 6 wherein said zeolite is dispersed in a solid porous matrix.
Claim 12
Dependent Claim 27 words
The process defined by claim 9 wherein the composite of zeolite and matrix is admixed with a greater volume of discrete particles in an inert solid diluent.

References Cited (Backward Citations)

US2795630A Cited
US3790471A Cited
US3646236A Cited
US3691247A Cited
US3751504A Cited
US3756942A Cited
US3761389A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-23 1978-06-24 1978-12-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-23 1982-06-24 1982-12-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-23 1986-06-24 1986-12-24 $7700.00 Window Closed / Lapsed

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