US3856872A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Xylene isomerization
Assignee: Mobil Oil AS
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Filing: 1973-09-13
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Granted: 1974-12-24
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Expires: 1993-09-13
Abstract
Abstract An improved catalyst for use in Octafining plants is characterized by a zeolite of the ZSM-5 type of zeolite ZSM-12 or zeolite ZSM-21. With substitution of a zeolite catalyst for platinum on silica alumina, the process operates at very high space velocities as calculated with respect to the active zeolite component of the catalyst. Typically the space velocity with respect to zeolite component may be 1 to 200 unit weights of charge per unit weight of zeolite per hour.
Inventors
- 👤 R Morrison
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 21:24
CPC Classifications
C; C07; C07C; C07C15/00; C07C15/02; C07C15/067; C07C15/073; C07C5/00; C07C5/22; C07C5/27; C07C5/2702; C07C5/2708; C07C5/2729; C07C5/2732; C07C5/2754; Y; Y10; Y10S; Y10S585/00; Y10S585/8995; Y10S585/905
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
251 words
A NEW USE OF THE KNOWN APPARATUS FOR SIMULTANEOUSLY ISOMERIZING XYLNES AND CONVERTING ETHYL BRNZENE TO PRODUCTS READILY SEPARABLE BY DISTILLATION FROM THE MIXTURE OF C8 AROMATICS BY CONTACTING A MIXTURE OF C8 AROMATICS AND HYDROGEN WITH A PLATINUM ON SILICA-ALUMINA CATALYST AT PRESSURE OF 175 TO 225 POUNDS PER SQUARE INCH, A TEMPERATURE OF 830 TO 900*F. AND LIQUID HOURLY SPACE VELOCITY OF 0.6 TO 1.6 LIQUID VOLUMES OF HYDROCARBON PER VOLUME OF CATALYST PER HOUR IN A LOOP COMPRISING AN ISOMERIZATION REACTOR FOR THE CONTACT AFORESAID, DISTILLATION MEANS FOR SEPARATING C8 AROMATICS FROM LOWER BOILING AND HIGHER BOILING HYDROCARBONS, MEANS TO TRANSFER HYDROCARBON EFFLUENT OF SAID ISOMERIZATION REACTOR TO SAID DISTILLATION MEANS, MIXING MEANS FOR MIXING FRESH FEED C8 AROMATICS CONTAINING XYLENE AND ETHYL BENZENE WITH C8 AROMATICS SEPARATED BY DISTILLATION MEANS, A XYLENE SEPARATOR FOR RECOVERY OF PAR XYLENE, MEANS FOR TRANSFER OF MIXED C8 AROMATICS FROM SAID MIXING MEANS TO SAID XYLENE SEPARATOR, AND MEANS TO TRANSFER C8 AROMATICS LEAN IN PARA XYLENE FROM SAID XYLENE SEPARATOR TO SAID ISOMERIZATION REACTOR; WHICH NEW USE COMPRISES CONTACTING, IN THE ISOMERIZATION REACTION OF SAID KNOWN APPARATUS, A VAPOR PHASE MIXTURE OF HYDROGEN AND SAID C8 AROMATICS LEAN IN PARA XYLENE WITH A ZEOLITE CATALYST OF THE ZSM-5 TYPE OR ZEOLITE ZSM-12 OR ZEOLITE ZSM-21 AT A TEMPERATURE OF 550 TO 900*F., A PRESSURE OF 150 TO 300 POUNDS PER SQUARE INCH AND A WEIGHT HOURLY SPACE VELOCITY WITH RESPECT TO SAID ZEOLITE ALONE BETWEEN ABOUT 1 AND ABOUT 200.
Claim 2
Dependent Claim
251 words
A NEW USE OF THE KNOWN APPARATUS FOR SIMULTANEOUSLY ISOMERIZING XYLNES AND CONVERTING ETHYL BRNZENE TO PRODUCTS READILY SEPARABLE BY DISTILLATION FROM THE MIXTURE OF C8 AROMATICS BY CONTACTING A MIXTURE OF C8 AROMATICS AND HYDROGEN WITH A PLATINUM ON SILICA-ALUMINA CATALYST AT PRESSURE OF 175 TO 225 POUNDS PER SQUARE INCH, A TEMPERATURE OF 830 TO 900*F. AND LIQUID HOURLY SPACE VELOCITY OF 0.6 TO 1.6 LIQUID VOLUMES OF HYDROCARBON PER VOLUME OF CATALYST PER HOUR IN A LOOP COMPRISING AN ISOMERIZATION REACTOR FOR THE CONTACT AFORESAID, DISTILLATION MEANS FOR SEPARATING C8 AROMATICS FROM LOWER BOILING AND HIGHER BOILING HYDROCARBONS, MEANS TO TRANSFER HYDROCARBON EFFLUENT OF SAID ISOMERIZATION REACTOR TO SAID DISTILLATION MEANS, MIXING MEANS FOR MIXING FRESH FEED C8 AROMATICS CONTAINING XYLENE AND ETHYL BENZENE WITH C8 AROMATICS SEPARATED BY DISTILLATION MEANS, A XYLENE SEPARATOR FOR RECOVERY OF PAR XYLENE, MEANS FOR TRANSFER OF MIXED C8 AROMATICS FROM SAID MIXING MEANS TO SAID XYLENE SEPARATOR, AND MEANS TO TRANSFER C8 AROMATICS LEAN IN PARA XYLENE FROM SAID XYLENE SEPARATOR TO SAID ISOMERIZATION REACTOR; WHICH NEW USE COMPRISES CONTACTING, IN THE ISOMERIZATION REACTION OF SAID KNOWN APPARATUS, A VAPOR PHASE MIXTURE OF HYDROGEN AND SAID C8 AROMATICS LEAN IN PARA XYLENE WITH A ZEOLITE CATALYST OF THE ZSM-5 TYPE OR ZEOLITE ZSM-12 OR ZEOLITE ZSM-21 AT A TEMPERATURE OF 550 TO 900*F., A PRESSURE OF 150 TO 300 POUNDS PER SQUARE INCH AND A WEIGHT HOURLY SPACE VELOCITY WITH RESPECT TO SAID ZEOLITE ALONE BETWEEN ABOUT 1 AND ABOUT 200.
Claim 3
Dependent Claim
15 words
The new use defined by claim 1 wherein said zeolite is in the acid form.
Claim 4
Dependent Claim
24 words
The new use defined by claim 1 wherein a metal of Group VIII or a compound of such metal is associated with said zeolite.
Claim 5
Dependent Claim
16 words
The new use defined by claim 1 wherein said zeolite is dispersed in a solid matrix.
Claim 6
Dependent Claim
28 words
The new use defined by claim 4 wherein the composite of zeolite and matrix is admixed with a greater volume of discrete particles of an inert, solid diluent.
Claim 7
Dependent Claim
82 words
A process for the isomerization of xylenes in a mixture of xylenes with ethyl benzene which comprises contacting a C8 aromatic fraction containing both xylenes and ethyl benzene in vapor phase admixed with hydrogen with a zeolite catalyst of the ZSM-5 type or zeolite ZSM-12 or zeolite ZSM-21 at a temperature of 550* to 900*F., a pressure of 150 to 300 pounds per square inch and a weight hourly space velocity with respect to said zeolite alone betwen 1 and about 200.
Claim 8
Dependent Claim
82 words
A process for the isomerization of xylenes in a mixture of xylenes with ethyl benzene which comprises contacting a C8 aromatic fraction containing both xylenes and ethyl benzene in vapor phase admixed with hydrogen with a zeolite catalyst of the ZSM-5 type or zeolite ZSM-12 or zeolite ZSM-21 at a temperature of 550* to 900*F., a pressure of 150 to 300 pounds per square inch and a weight hourly space velocity with respect to said zeolite alone betwen 1 and about 200.
Claim 9
Dependent Claim
14 words
The process defined by claim 6 wherein said zeolite is in the acid form.
Claim 10
Dependent Claim
22 words
The process defined by claim 6 wherein a metal of Group VIII or a compound of such metal is associated with zeolite.
Claim 11
Dependent Claim
16 words
The process defined by claim 6 wherein said zeolite is dispersed in a solid porous matrix.
Claim 12
Dependent Claim
27 words
The process defined by claim 9 wherein the composite of zeolite and matrix is admixed with a greater volume of discrete particles in an inert solid diluent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1977-12-23 | 1978-06-24 | 1978-12-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1981-12-23 | 1982-06-24 | 1982-12-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1985-12-23 | 1986-06-24 | 1986-12-24 | $7700.00 | Window Closed / Lapsed |