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US4223147A Expired / Lapsed US ⏱️ 0.0 years remaining

Methylol derivatives of 2,2,6,6-tetraalkylpiperidines and their production

Assignee: Bayer AG
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Filing: 1977-09-19
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Granted: 1980-09-16
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Expires: 1997-09-19
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Abstract

Abstract The invention relates to new methylol derivatives of 2,2,6,6-tetraalkylpiperidines, to their production and to their use as chemically attached stabilizers for polymers containing reactive OH- and NH-groups.

Inventors

  • 👤 Harald Oertel
  • 👤 Paul Uhrhan
  • 👤 Reinhard Lantzsch
  • 👤 Ernst Roos
  • 👤 Hans Schroer
  • 👤 Dieter Arlt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 14:17
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/83; C08G18/833; C07; C07D; C07D211/00; C07D211/04; C07D211/06; C07D211/36; C07D211/56; C07D211/58; C07D211/60; C07D211/62; C07D211/66; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 131 words
A compound of the formula ##STR143## wherein A is ##STR144## wherein R 3 is C 1 -C 20 -alkyl, hydrogen, C 5 -C 12 -cycloalkyl or C 7 -C 12 -aralkyl and E is a direct bond; Z is hydrogen or C 1 -C 14 -alkyl; R is hydrogen, C 1 -C 20 -alkyl, C 3 -C 5 -alkenyl; C 7 -C 12 -aralkyl; CH--CHR 6 --OH, wherein R 6 is hydrogen, methyl, or phenyl; --CH 2 CH 2 CN; --CH 2 --CH 2 --COOC 1-2 alkyl; or ##STR145## R 1 and R 2 independently of one another are C 1 -C 6 -alkyl, or R 1 and R 2 together with the ring carbon atom to which they are attached form C 1 -C 7 -cycloalkyl; and X is hydrogen.
Claim 2
Dependent Claim 131 words
A compound of the formula ##STR143## wherein A is ##STR144## wherein R 3 is C 1 -C 20 -alkyl, hydrogen, C 5 -C 12 -cycloalkyl or C 7 -C 12 -aralkyl and E is a direct bond; Z is hydrogen or C 1 -C 14 -alkyl; R is hydrogen, C 1 -C 20 -alkyl, C 3 -C 5 -alkenyl; C 7 -C 12 -aralkyl; CH--CHR 6 --OH, wherein R 6 is hydrogen, methyl, or phenyl; --CH 2 CH 2 CN; --CH 2 --CH 2 --COOC 1-2 alkyl; or ##STR145## R 1 and R 2 independently of one another are C 1 -C 6 -alkyl, or R 1 and R 2 together with the ring carbon atom to which they are attached form C 1 -C 7 -cycloalkyl; and X is hydrogen.
Claim 3
Dependent Claim 23 words
The compound of claim 1, wherein R is hydrogen or methyl; R 1 and R 2 are each methyl; and Z is methyl.
Claim 4
Dependent Claim 17 words
The compound of claim 1 wherein R 3 is hydrogen, C 1 -C 8 -alkyl or cyclohexyl.
Claim 5
Dependent Claim 11 words
The compound of claim 1, wherein Z is H or methyl.
Claim 6
Dependent Claim 74 words
A process for the production of the compound of claim 1, comprising reacting a compound of the formula ##STR146## with (a) cyanic acid and then (b) formaldehyde to react each NH group not attached to the ring with cyanic acid to form first a --N--CO--NH 2 -- group and subsequently an --N--CO--NH--CH 2 OH group or (c) additionally etherifying the --N--CO--NH--CH 2 OH group with an alcohol of the formula ZOH in acid medium.

References Cited (Backward Citations)

US3684765A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-09-16 1984-03-17 1984-09-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-09-16 1988-03-17 1988-09-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-09-16 1992-03-17 1992-09-16 $7700.00 Window Closed / Lapsed

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