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Semipermeable membranes of heterocyclic copolyamides

Assignee: Bayer AG
•
Filing: 1978-07-24
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Granted: 1980-09-09
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Expires: 1998-07-24
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Abstract

Abstract The invention relates to semipermeable membranes with a water absorption capacity of from 4.5 to 11% by weight, preferably from 4.5 to 8% by weight, as measured on approximately 40μ thick symmetrical films at room temperature and at 65% relative air humidity, a throughflow of 130 to 200 l/m 2 d for a desalination level of 94.6 to 99.5% and consisting of an aromatic heterocycle-containing copolyamide with a relative viscosity of ≧1.4, as measured on a 0.5% N-methyl pyrrolidone solution at a temperature of 20° C.

Inventors

  • 👤 Klaus Elfert
  • 👤 Gerhard D. Wolf
  • 👤 Francis Bentz
  • 👤 Hans E. Kunzel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 15:43
CPC Classifications
B; B01; B01D; B01D71/00; B01D71/06; B01D71/56; C; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/32

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 179 words
A semipermeable membrane with a water absorption capacity of from 4.5 to 11% by weight, as measured on an approximately 40μ thick symmetrical film at room temperature at 65% relative air humidity, a throughflow of from 130 to 200 l/m 2 d for a desalination level of from 94.6 to 99.5% and consisting of an aromatic heterocycle-containing copolyamide (A) 10 to 95 mole% of one or more units corresponding to Formulae I-IV below: ##STR21## in which R, R', R", R"', R IV , R V , R VI and R VII which are the same or different represent hydrogen, C 1-4 -alkyl or halogen; Ar represents an alkyl- or halogen-substituted bivalent aromatic radical or an unsubstituted bivalent aromatic radical; and X, Y and Z, each represent a direct bond or a bridge member selected from the group consisting of ##STR22## and of (B) 5 to 90 mole% of units corresponding to the formula (V) --HN--T--NH--OC--Ar--CO-- (V), in which Ar is as just defined and T represents a bivalent heterocyclic radical which contains one or more aromatic or heterocyclic radicals.
Claim 2
Dependent Claim 179 words
A semipermeable membrane with a water absorption capacity of from 4.5 to 11% by weight, as measured on an approximately 40μ thick symmetrical film at room temperature at 65% relative air humidity, a throughflow of from 130 to 200 l/m 2 d for a desalination level of from 94.6 to 99.5% and consisting of an aromatic heterocycle-containing copolyamide (A) 10 to 95 mole% of one or more units corresponding to Formulae I-IV below: ##STR21## in which R, R', R", R"', R IV , R V , R VI and R VII which are the same or different represent hydrogen, C 1-4 -alkyl or halogen; Ar represents an alkyl- or halogen-substituted bivalent aromatic radical or an unsubstituted bivalent aromatic radical; and X, Y and Z, each represent a direct bond or a bridge member selected from the group consisting of ##STR22## and of (B) 5 to 90 mole% of units corresponding to the formula (V) --HN--T--NH--OC--Ar--CO-- (V), in which Ar is as just defined and T represents a bivalent heterocyclic radical which contains one or more aromatic or heterocyclic radicals.
Claim 3
Dependent Claim 29 words
A semipermeable membrane as claimed in claim 1, consisting of 50 to 90 mole % of the units (A) and 10 to 50 mole % of the units (B).
Claim 4
Dependent Claim 31 words
A semipermeable membrane as claimed in claim 1 wherein bivalent aromatic radical AR is selected from the group consiting of m-phenylene, o-phenylene, naphthalene, biphenylene and a radical of the formula ##STR23##
Claim 5
Dependent Claim 104 words
A semipermeable membrane as claimed in claim 1, consisting of an aromatic heterocyclecontaining copolyamide of (A) 10 to 95 mole % of one or more unit(s) corresponding to formulae I to IV, in which Ar represents m- or p-phenylene and R, R', R", R"', R IV , R V , R VI and R VII which may be the same or different represent hydrogen, methyl or chlorine, and of (B) 5 to 90 mole % of units corresponding to formula V, in which Ar represents m- or p-phenylene and T represents a bivalent heterocyclic radical which contains one or more aromatic of heterocyclic radicals.
Claim 6
Dependent Claim 18 words
A semipermeable membrane as claimed in claim 1, wherein X in Formula (II) represents --O--, --CONH-- or --NHOC--.
Claim 7
Dependent Claim 25 words
A semipermeable membrane as claimed in claim 1, wherein X and Y in formula (III) independently represents --O--, --NHOC--, --CONH--, NHCOO--, --COO--, --OOC--, or --NHCONH--.
Claim 8
Dependent Claim 28 words
A semipermeable membrane as claimed in claim 1, wherein X and Y in formula (IV) represent --O--, --CONH-- or --NHOC-- and Z represents --SO 2 -- or ##STR24##
Claim 9
Dependent Claim 23 words
A semipermeable membrane as claimed in claim 1, wherein T in formula (V) is derived from a diamine with a quinazolin dione structure.
Claim 10
Dependent Claim 38 words
A semipermeable membrane as claimed in claim 1, consisting of a copolyamide of 10 to 95 mole % of units corresponding to the formulae ##STR25## and 5 to 90 mole % of units corresponding to the formula ##STR26##
Claim 11
Dependent Claim 38 words
A semipermeable membrane as claimed in claim 1, consisting of a copolyamide of 10 to 95 mole % of units corresponding to the formula ##STR27## and 5 to 90 mole % of units corresponding to the formula ##STR28##
Claim 12
Dependent Claim 38 words
A semipermeable membrane as claimed in claim 1, consisting of a copolyamide of 10 to 95 mole % of units corresponding to the formula ##STR29## and 5 to 90 mole % of units corresponding to the formula ##STR30##
Claim 13
Dependent Claim 14 words
A semipermeable membrane as claimed in claim 1, in the form of a film.

References Cited (Backward Citations)

US3567632A Cited
US3696031A Cited
US3664986A Cited
US4123424A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-09-09 1984-03-10 1984-09-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-09-09 1988-03-10 1988-09-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-09-09 1992-03-10 1992-09-09 $7700.00 Window Closed / Lapsed

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