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US4221882A Expired / Lapsed US ⏱️ 0.0 years remaining

High impact melt-flowable dual continuum melt mixed polymer blends of polypropylene, polyethylene, and ethylene-propylene rubber

Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1979-01-31
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Granted: 1980-09-09
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Expires: 1999-01-31
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Abstract

Abstract Melt mixed, melt-flowable blends of polypropylene, at least about 30% polyethylene and from about 4 to about 11% ethylene-propylene copolymer rubber, and method for making same, are disclosed. Such blends possess higher low temperature Izod and Gardner impact strength than conventional impact polypropylene blends, while having a comparable or higher flexural modulus.

Inventors

  • 👤 Terrence Huff

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:34
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/06; C08L23/10; C08L23/12; C08L2205/00; C08L2205/02; C08L2205/03; C08L2205/035; C08L23/16; C08L2310/00

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 76 words
A melt-flowable, high impact strength, melt mixed blend of polypropylene, ethylenepropylene copolymer rubber and polyethylene wherein the ratio by weight of the polypropylene component to the combined polyethylene and ethylenepropylene copolymer rubber components is from about 1.0 to about 2.0; and the polyethylene component is at least about 30% by weight of the total blend and the ethylene-propylene copolymer rubber component is from at least about 4% to about 11% by weight of the total blend.
Claim 2
Dependent Claim 76 words
A melt-flowable, high impact strength, melt mixed blend of polypropylene, ethylenepropylene copolymer rubber and polyethylene wherein the ratio by weight of the polypropylene component to the combined polyethylene and ethylenepropylene copolymer rubber components is from about 1.0 to about 2.0; and the polyethylene component is at least about 30% by weight of the total blend and the ethylene-propylene copolymer rubber component is from at least about 4% to about 11% by weight of the total blend.
Claim 3
Dependent Claim 29 words
The high impact blend of claim 1, wherein said ethylene-propylene copolymer rubber component is present from at least about 4% to about 8% by weight of the total blend.
Claim 4
Dependent Claim 20 words
The high impact blend of claim 1, wherein said polyethylene component has a density of at least about 0.950 g/cc.
Claim 5
Dependent Claim 22 words
The high impact blend of claim 3, wherein said polyethylene component has a melt index of from about 0.1 to about 20.
Claim 6
Dependent Claim 51 words
The high impact blend of claim 4, wherein when said polypropylene component has a melt flow rate greater than 1, the polyethylene component is at least about 37% by weight of the total blend and said ethylene-propylene copolymer rubber component is at least about 5.5% by weight of the total blend.
Claim 7
Dependent Claim 22 words
The high impact blend of claim 5, wherein said polyethylene component has a melt index of from about 1 to about 5.
Claim 8
Dependent Claim 28 words
The high impact blend of claim 1, wherein said ethylene-propylene copolymer rubber has a mooney viscosity greater than 20 and an ethylene content greater than 30% by weight.
Claim 9
Dependent Claim 20 words
The high impact blend of claim 7, wherein the ethylene content is between about 40 to about 60% by weight.
Claim 10
Dependent Claim 23 words
The high impact blend of claim 7, wherein said polypropylene component has a melt flow rate of from about 0.3 to about 12.0.
Claim 11
Dependent Claim 37 words
The high impact blend of claim 1, suitable for film applications, wherein said polyethylene component has a density of from about 0.910 to about 0.929 g/cc, and a melt index of from about 0.3 to about 20.
Claim 12
Dependent Claim 116 words
A pellet mixture for making melt mixed melt-flowable, high impact strength blends comprising: a pelletized blend, of a polypropylene component and an ethylene-propylene copolymer rubber component, produced by high shear mixing, and a pelletized polyethylene component; wherein said pelletized blend of polypropylene and ethylene-propylene is mixed with said pelletized polyethylene in proportions sufficient to produce a total pellet mixture wherein the ratio by weight of polypropylene to the total amount of polyethylene and ethylene-propylene copolymer rubber is from about 1.0 to about 2.0, the polyethylene is at least about 30% by weight of the pellet mixture, and the ethylene-propylene copolymer rubber is from at least about 4% to about 11% by weight of the pellet mixture.
Claim 13
Dependent Claim 116 words
A pellet mixture for making melt mixed melt-flowable, high impact strength blends comprising: a pelletized blend, of a polypropylene component and an ethylene-propylene copolymer rubber component, produced by high shear mixing, and a pelletized polyethylene component; wherein said pelletized blend of polypropylene and ethylene-propylene is mixed with said pelletized polyethylene in proportions sufficient to produce a total pellet mixture wherein the ratio by weight of polypropylene to the total amount of polyethylene and ethylene-propylene copolymer rubber is from about 1.0 to about 2.0, the polyethylene is at least about 30% by weight of the pellet mixture, and the ethylene-propylene copolymer rubber is from at least about 4% to about 11% by weight of the pellet mixture.
Claim 14
Dependent Claim 97 words
A process for making a melt-flowable high impact melt mixed blend of polypropylene, ethylene-propylene copolymer rubber and polyethylene comprising the steps of: (a) high shear mixing of a polypropylene component with an ethylene-propylene copolymer rubber component; and (b) melt mixing the polypropylene and ethylenepropylene copolymer rubber of (a) with a polyethylene component to form a final blend of from about 4 to about 11% by weight ethylene-propylene rubber, at least about 30% by weight of polyethylene; wherein the ratio by weight of polypropylene to the combined ethylene-propylene rubber and polyethylene is from about 1 to about 2.
Claim 15
Dependent Claim 97 words
A process for making a melt-flowable high impact melt mixed blend of polypropylene, ethylene-propylene copolymer rubber and polyethylene comprising the steps of: (a) high shear mixing of a polypropylene component with an ethylene-propylene copolymer rubber component; and (b) melt mixing the polypropylene and ethylenepropylene copolymer rubber of (a) with a polyethylene component to form a final blend of from about 4 to about 11% by weight ethylene-propylene rubber, at least about 30% by weight of polyethylene; wherein the ratio by weight of polypropylene to the combined ethylene-propylene rubber and polyethylene is from about 1 to about 2.
Claim 16
Dependent Claim 106 words
A process for making a melt-flowable high impact melt mixed blend of polypropylene, ethylene-propylene copolymer rubber and polyethylene comprising the steps of: (a) high shear mixing of a first portion of polypropylene with an ethylene-propylene copolymer rubber component; and (b) melt mixing the polypropylene and ethylenepropylene copolymer rubber of (a) with a second portion of polypropylene and a polyethylene component to form a final blend of from about 4 to about 11% by weight ethylene-propylene rubber, at least about 30% by weight polyethylene; wherein the ratio by weight of polypropylene to the combined amount of ethylene-propylene rubber and polyethylene is from about 1 to about 2.
Claim 17
Dependent Claim 106 words
A process for making a melt-flowable high impact melt mixed blend of polypropylene, ethylene-propylene copolymer rubber and polyethylene comprising the steps of: (a) high shear mixing of a first portion of polypropylene with an ethylene-propylene copolymer rubber component; and (b) melt mixing the polypropylene and ethylenepropylene copolymer rubber of (a) with a second portion of polypropylene and a polyethylene component to form a final blend of from about 4 to about 11% by weight ethylene-propylene rubber, at least about 30% by weight polyethylene; wherein the ratio by weight of polypropylene to the combined amount of ethylene-propylene rubber and polyethylene is from about 1 to about 2.
Claim 18
Dependent Claim 20 words
The high impact blend of claim 1, wherein said polyethylene component has a density of at least about 0.919 g/cc.

References Cited (Backward Citations)

US3256366A Cited
US3137672A Cited
US3256367A Cited
US3957919A Cited
US4087485A Cited
US4088714A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-09-09 1984-03-10 1984-09-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-09-09 1988-03-10 1988-09-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-09-09 1992-03-10 1992-09-09 $7700.00 Window Closed / Lapsed

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