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Anti-yellowing composition

Assignee: Adeka Corp
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Filing: 1978-07-03
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Granted: 1980-09-09
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Expires: 1998-07-03
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Abstract

Abstract An anti-yellowing additive is provided for environmentally acceptable stabilized vinyl chloride polymer compositions from which arsenic, cadmium, lead, mercury, and thallium are substantially excluded, comprising at least one basic inorganic compound of lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, titanium, aluminum, zirconium, or tin, and a 1,3-diketone compound represented by the formula <IMAGE> in which R is a hydrocarbon group having 1 to 18 carbon atoms, R' is a hydrogen atom, an acyl group <IMAGE> or a hydrocarbon group having 1 to 18 carbon atoms, R' is a hydrogen atom or a hydrocarbon group having 1 to 18 carbon atoms, M is a hydrogen or one of the metals lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, aluminum, and antimony, and n is the valence of the metal from 1 to 3.

Inventors

  • 👤 Motonobu Minagawa
  • 👤 Tetsuo Sekiguchi
  • 👤 Kenji Nakazawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 02:19
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/07; C08K3/00; C08K3/10

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 226 words
An anti-yellowing additive for minimizing the yellowing tendency when heated at 190° C. of environmentally acceptable stabilized vinyl chloride polymer compositions from which arsenic, cadmium, lead, mercury, and thallium are substantially excluded, comprising in combination (A) at least one basic inorganic oxide, hydroxide, phosphate, phosphite, nitrate, nitrite, or sulfate of at least one of the metals lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, titanium, aluminum, zirconium, or tin having in the presence of 100 parts of water per part a pH in the range of 7.4 to 13; and (B) for each part by weight of basic inorganic compound 0.01 to 1 part by weight of a 1,3-diketone compound represented by the formula ##STR52## in which R is a hydrocarbon group, a halohydrocarbon group, an alkoxyhydrocarbon group or an alkylenedioxyhydrocarbon group or an alkylenedioxyhydrocarbon group having 1 to 18 carbon atoms; R' is a hydrogen atom, an acyl group ##STR53## where R"' is alkyl or a hydrocarbon group having 1 to 18 carbon atoms; R" is a hydrogen atom or a hydrocarbon group, a halohydrocarbon group, an alkoxyhydrocarbon group, or an alkylenedioxyhydrocarbon group having 1 to 18 carbon atoms; M is hydrogen or a metal selected from the group consisting of lithium, sodium, potassium, strontium, barium, zinc, aluminum, and antimony; and n is an integer from 1 to 3 depending on the valence of M.
Claim 2
Dependent Claim 226 words
An anti-yellowing additive for minimizing the yellowing tendency when heated at 190° C. of environmentally acceptable stabilized vinyl chloride polymer compositions from which arsenic, cadmium, lead, mercury, and thallium are substantially excluded, comprising in combination (A) at least one basic inorganic oxide, hydroxide, phosphate, phosphite, nitrate, nitrite, or sulfate of at least one of the metals lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, titanium, aluminum, zirconium, or tin having in the presence of 100 parts of water per part a pH in the range of 7.4 to 13; and (B) for each part by weight of basic inorganic compound 0.01 to 1 part by weight of a 1,3-diketone compound represented by the formula ##STR52## in which R is a hydrocarbon group, a halohydrocarbon group, an alkoxyhydrocarbon group or an alkylenedioxyhydrocarbon group or an alkylenedioxyhydrocarbon group having 1 to 18 carbon atoms; R' is a hydrogen atom, an acyl group ##STR53## where R"' is alkyl or a hydrocarbon group having 1 to 18 carbon atoms; R" is a hydrogen atom or a hydrocarbon group, a halohydrocarbon group, an alkoxyhydrocarbon group, or an alkylenedioxyhydrocarbon group having 1 to 18 carbon atoms; M is hydrogen or a metal selected from the group consisting of lithium, sodium, potassium, strontium, barium, zinc, aluminum, and antimony; and n is an integer from 1 to 3 depending on the valence of M.
Claim 3
Dependent Claim 18 words
An anti-yellowing additive according to claim 1 in which the basic inorganic compound is a basic aluminum sulfate.
Claim 4
Dependent Claim 18 words
An anti-yellowing additive according to claim 2 in which the basic inorganic compound is a basic calcium phosphate.
Claim 5
Dependent Claim 18 words
An anti-yellowing additive according to claim 2 in which the basic inorganic compound is a basic barium phosphate.
Claim 6
Dependent Claim 18 words
An anti-yellowing additive according to claim 2 in which the basic inorganic compound is a basic barium nitrite.
Claim 7
Dependent Claim 21 words
An anti-yellowing additive according to claim 1 in which the basic inorganic compound is a Group II metal oxide or hydroxide.
Claim 8
Dependent Claim 16 words
An anti-yellowing additive according to claim 6 in which the basic inorganic compound is magnesium oxide.
Claim 9
Dependent Claim 16 words
An anti-yellowing additive according to claim 6 in which the basic inorganic compound is calcium oxide.
Claim 10
Dependent Claim 16 words
An anti-yellowing additive according to claim 6 in which the basic inorganic compound is calcium hydroxide.
Claim 11
Dependent Claim 16 words
An anti-yellowing additive according to claim 6 in which the basic inorganic compound is barium oxide.
Claim 12
Dependent Claim 16 words
An anti-yellowing additive according to claim 6 in which the basic inorganic compound is barium hydroxide.
Claim 13
Dependent Claim 16 words
An anti-yellowing additive according to claim 6 in which the basic inorganic compound is zinc oxide.
Claim 14
Dependent Claim 19 words
An anti-yellowing additive according to claim 1 in which in the formula of the 1,3-diketone compound M is hydrogen.
Claim 15
Dependent Claim 19 words
An anti-yellowing additive according to claim 1 in which in the formula of the 1,3-diketone compound M is zinc.
Claim 16
Dependent Claim 21 words
An anti-yellowing additive according to claim 1 in which in the formula of the 1,3-diketone compound M is an alkali metal.
Claim 17
Dependent Claim 21 words
An anti-yellowing additive according to claim 1 in which the formula of the 1,3-diketone compound R and R" are alkyl groups.
Claim 18
Dependent Claim 25 words
An anti-yellowing additive according to claim 1 in which the formula of the 1,3-diketone compound at least one of R andR" is an aryl group.
Claim 19
Dependent Claim 26 words
An anti-yellowing additive according to claim 1 in which the 1,3-diketone compound is a lithium, sodium, potassium, strontium, barium, zinc, aluminum, or antimony compound of dibenzoylmethane.
Claim 20
Dependent Claim 62 words
An enviromentally acceptable stabilized vinyl chloride polymer composition protected against yellowing and from which arsenic, cadmium, lead, mercury, and thallium are substantially excluded, comprising a vinyl chloride polymer, a stabilizing amount of at least one heat stabilizer, and from 0.02 to 20 parts by weight per 100 parts by weight of vinyl chloride polymer of an anti-yellowing additive according to claim 1.
Claim 21
Dependent Claim 21 words
A vinyl chloride polymer composition according to claim 19 in which the vinyl chloride polymer is a homopolymer of vinyl chloride.
Claim 22
Dependent Claim 40 words
A vinyl chloride polymer composition according to claim 19 in which the vinyl chloride polymer is a copolymer of vinyl chloride and a comonomer selected from the group consisting of propylene, ethylene, 1-hexene, vinyl acetate, diethyl maleate, and diethyl fumarate.
Claim 23
Dependent Claim 43 words
A vinyl chloride polymer composition according to claim 19 in which the heat stabilizer is a barium, calcium, magnesium, or zinc salt of a non-nitrogenous monocarboxylic acid having 6 to 24 carbon atoms or a hydrocarbon-substituted phenol having 10 to 30 carbon atoms.
Claim 24
Dependent Claim 18 words
A vinyl chloride polymer composition according to claim 19 in which the heat stabilizer is an epoxidized triglyceride.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-09-09 1984-03-10 1984-09-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-09-09 1988-03-10 1988-09-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-09-09 1992-03-10 1992-09-09 $7700.00 Window Closed / Lapsed

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