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Reactive complex chromium-bearing azo dyestuffs

Assignee: Produits Chimiques Ugine Kuhlmann
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Filing: 1976-11-26
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Granted: 1980-08-19
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Expires: 1996-11-26
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Abstract

Abstract Complex chromium-bearing dyestuffs of formula: ##STR1## where A represents a diazotizable amine residue, B represents the residue of a coupling agent, Y 1 represents a --O-- or ##STR2## residue, Y 2 represents a --O-- or ##STR3## residue, E represents the residue of a monoanionic bifunctional chelating agent, Y 1 and Y 2 are respectively in the ortho position with respect to the --N═N-- group, G represents a neutral monofunctional ligand, and Z represents a reactive group attached to A or B directly or via a bridging group such as ##STR4## --SO 2 NH-- or --CO--NH--, R denoting hydrogen or an alkyl radical having 1 to 2 carbon atoms; their process of preparation, and their application for dyeing of a variety of natural or synthetic fibers and fabrics including regenerated cellulose, wool, silk, synthetic polyamides. They may also be used for the dyeing of leather.

Inventors

  • 👤 Claude M. H. E. Brouard
  • 👤 Claude L. E. Moerel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 08:46
CPC Classifications
C; C09; C09B; C09B62/00; C09B62/002; C09B62/006; C09B62/012

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 201 words
A complex chromium bearing dyestuff of the formula: ##STR177## wherein A represents a phenylene or naphthylene nucleus; B represents a coupling component selected from the group consisting of acetoacetarylide, aniline, phenol, 5-pyrazolone, naphthylamine and naphthol, A and B being unsubstituted or substituted by one or more of sulfo, halogen, nitro, alkyl having 1-4 carbon atoms, alkoxy having 1-4 carbon atoms, acetylamino, unsubstituted phenylamino, phenylamino substituted by sulfo, unsubstituted phenylazo or naphthylazo, phenylazo or naphthylazo substituted by one or more of nitro, halogen, carboxy, sulfo or alkoxy having 1-4 carbon atoms, unsubstituted phenyl or phenyl substituted by one or more of sulfo or halogen, at least one --SO 3 H group being present per atom of chromium; Y 1 represents the residue --O-- or ##STR178## Y 2 represents the residue --O-- or --NH--; Y 1 and Y 2 are respectively in the ortho position with respect to the --N═N-- group; E represents the residue of a monoanionic bifunctional chelating agent; G represents a neutral monofunctional ligand; and Z represents a reactive group attached to A or to B directly or via a bridging group ##STR179## --SO 2 NH-- or --CONH-- wherein R is hydrogen or alkyl having 1 to 2 carbon atoms.
Claim 2
Dependent Claim 201 words
A complex chromium bearing dyestuff of the formula: ##STR177## wherein A represents a phenylene or naphthylene nucleus; B represents a coupling component selected from the group consisting of acetoacetarylide, aniline, phenol, 5-pyrazolone, naphthylamine and naphthol, A and B being unsubstituted or substituted by one or more of sulfo, halogen, nitro, alkyl having 1-4 carbon atoms, alkoxy having 1-4 carbon atoms, acetylamino, unsubstituted phenylamino, phenylamino substituted by sulfo, unsubstituted phenylazo or naphthylazo, phenylazo or naphthylazo substituted by one or more of nitro, halogen, carboxy, sulfo or alkoxy having 1-4 carbon atoms, unsubstituted phenyl or phenyl substituted by one or more of sulfo or halogen, at least one --SO 3 H group being present per atom of chromium; Y 1 represents the residue --O-- or ##STR178## Y 2 represents the residue --O-- or --NH--; Y 1 and Y 2 are respectively in the ortho position with respect to the --N═N-- group; E represents the residue of a monoanionic bifunctional chelating agent; G represents a neutral monofunctional ligand; and Z represents a reactive group attached to A or to B directly or via a bridging group ##STR179## --SO 2 NH-- or --CONH-- wherein R is hydrogen or alkyl having 1 to 2 carbon atoms.
Claim 3
Dependent Claim 37 words
A complex chromium bearing dyestuff as set forth in claim 1 wherein the monoanionic bifunctional chelating agent E-H corresponding to the residue E is a beta-diketone, an acetoacetarylide, an o-hydroxyaldehyde, an o-nitrosophenol or naphthol or a peri-hydroxyquinone.
Claim 4
Dependent Claim 24 words
A complex chromium bearing dyestuff as set forth in claim 1 in which the neutral ligand G represents water, ammonia or an organic base.
Claim 5
Dependent Claim 22 words
A complex chromium bearing dyestuff as set forth in claim 3 in which the organic base is pyridine, laurylamine, ethylamine or ethanolamine
Claim 6
Dependent Claim 121 words
A complex chromium bearing dyestuff as set forth in claim 1 wherein Z is --SO 2 --CH 2 --CH 2 --OSO 3 H, --SO 2 --NH--CH 2 --CH 2 OSO 3 H, --SO 2 --CH═CH 2 , --SO 2 --CH 2 --CH 2 Cl, --SO 2 --NH--CH 2 --CH 2 Cl or is of the formula: ##STR180## wherein T is chlorine, amino, unsubstituted phenylamino, phenylamino substituted by one or more of sulfo, alkyl having 1-4 carbon atoms or halogen, or a residue of the formula: ##STR181## in which A', B', E', G', Y' 1 and Y' 2 have the significance defined above for A, B, E, G, Y 1 and Y 2 and NH is attached to A or to B.
Claim 7
Dependent Claim 14 words
A complex chromium bearing dyestuff according to claim 5 corresponding to the formula: ##STR182##
Claim 8
Dependent Claim 14 words
A complex chromium bearing dyestuff according to claim 5 corresponding to the formula: ##STR183##
Claim 9
Dependent Claim 14 words
A complex chromium bearing dyestuff according to claim 5 corresponding to the formula: ##STR184##
Claim 10
Dependent Claim 13 words
A complex, chromium-bearing dyestuff according to claim 22 corresponding to the formula: ##STR185##
Claim 11
Dependent Claim 13 words
A complex, chromium-bearing dyestuff according to claim 5 corresponding to the formula: ##STR186##

References Cited (Backward Citations)

FR1310178A Cited
US3354140A Cited
US3308114A Cited
US3538073A Cited
US3544546A Cited
US3526617A Cited
US3878158A Cited
DE2318412A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-08-19 1984-02-18 1984-08-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-08-19 1988-02-18 1988-08-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-08-19 1992-02-18 1992-08-19 $7700.00 Window Closed / Lapsed

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