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US4218307A
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Hydrocarbon cracking catalyst
Assignee: WR Grace and Co Conn
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Filing: 1979-01-09
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Granted: 1980-08-19
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Expires: 1999-01-09
Abstract
Abstract A zeolite containing hydrocarbon cracking catalyst characterized by exceptionally high catalytic acitivity, superior coke selectivity and relatively low rate earth content. The catalyst is prepared by combining into a suitable matrix a zeolite prepared by a combination of thermal stabilization, de-alumination and rare earth ion exchange.
Inventors
- 👤 Carl V. McDaniel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 13:23
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/08; B01J29/084; B01J20/00; B01J20/02; B01J20/10; B01J20/16; B01J20/18; B01J20/186; C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C10G11/05; B01J2229/00; B01J2229/10; B01J2229/16
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
214 words
In an improved method for catalytically cracking hydrocarbons wherein the production of coke is minimized, the improvement comprising contacting a hydrocarbon feedstock with a catalyst comprising a catalytically active, coke selective zeolite admixed with an inorganic oxide matrix, and recovering cracked hydrocarbons of lower molecular weight, said zeolite being prepared by: a. exchanging a sodium Y zeolite having a silica to alumina ratio of about 3.5 to 6 with an ammonium salt to reduce the Na 2 O content thereof to less than 4 percent by weight; b. exchanging said zeolite with a solution of rare earth ions to provide a rare earth content expresses as rare earth oxide of about 0.5 to 4 percent by weight; c. washing said zeolite to remove excess salts; d. heating said zeolite to a temperature of about 700° to 1600° F.; e. contacting said zeolite with a dilute solution of a mineral acid to remove alumina therefrom and thereby increase the silica to alumina ratio to a range of about 7 to 20; f. exchanging the zeolite of step e. with a solution of metal ions selected from the group consisting of rare earth and magnesium ions to provide a total metal ion content expressed as metal oxides of from about 1 to 10 percent by weight.
Claim 2
Dependent Claim
214 words
In an improved method for catalytically cracking hydrocarbons wherein the production of coke is minimized, the improvement comprising contacting a hydrocarbon feedstock with a catalyst comprising a catalytically active, coke selective zeolite admixed with an inorganic oxide matrix, and recovering cracked hydrocarbons of lower molecular weight, said zeolite being prepared by: a. exchanging a sodium Y zeolite having a silica to alumina ratio of about 3.5 to 6 with an ammonium salt to reduce the Na 2 O content thereof to less than 4 percent by weight; b. exchanging said zeolite with a solution of rare earth ions to provide a rare earth content expresses as rare earth oxide of about 0.5 to 4 percent by weight; c. washing said zeolite to remove excess salts; d. heating said zeolite to a temperature of about 700° to 1600° F.; e. contacting said zeolite with a dilute solution of a mineral acid to remove alumina therefrom and thereby increase the silica to alumina ratio to a range of about 7 to 20; f. exchanging the zeolite of step e. with a solution of metal ions selected from the group consisting of rare earth and magnesium ions to provide a total metal ion content expressed as metal oxides of from about 1 to 10 percent by weight.
Claim 3
Dependent Claim
14 words
The method of claim 1 wherein said dilute acid solution is dilute nitric acid.
Claim 4
Dependent Claim
20 words
The method of claim 1 wherein said catalyst contains from about 5 to 50 percent by weight of said zeolite.
Claim 5
Dependent Claim
22 words
The method of claim 3 wherein the inorganic oxide matrix is selected from the group comprising clay, silica, alumina and silica-alumina hydrogels.
Claim 6
Dependent Claim
24 words
The method of claim 1 wherein said zeolite contains about 1.5 percent by weight rare-earth oxide and about 1 percent by weight magnesium oxide.
References Cited (Backward Citations)
US3591488A
Cited
US3957623A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-08-19 | 1984-02-18 | 1984-08-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-08-19 | 1988-02-18 | 1988-08-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-08-19 | 1992-02-18 | 1992-08-19 | $7700.00 | Window Closed / Lapsed |