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Asphaltic concrete compositions comprising diene/vinyl aromatic copolymers

Assignee: Phillips Petroleum Co
•
Filing: 1977-09-30
•
Granted: 1980-08-12
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Expires: 1997-09-30
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Abstract

Abstract Improved asphalt-containing compositions having excellent flexural fatigue test characteristics are prepared by incorporating into the mix during its preparation at least one diene/vinyl aromatic copolymer, said copolymer being a radial teleblock copolymer wherein the teleblock copolymer has a diene/vinyl aromatic weight ratio of about 60/40 to about 90/10 and a weight average molecular weight range of from about 130,000 to 300,000.

Inventors

  • 👤 Clarence R. Bresson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 09:36
CPC Classifications
E; E01; E01C; E01C7/00; E01C7/08; E01C7/18; E01C7/26; E01C7/265; C; C08; C08L; C08L95/00

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 54 words
An asphaltic concrete composition comprising an asphalt, a mineral aggregate, and a radial teleblock copolymer of a conjugated diene and a monovinyl aromatic monomer wherein the teleblock copolymer has a diene/monovinyl aromatic monomer weight ratio of at least about 75/25 to about 90/10 and a weight average molecular weight range of from about 150,000-300,000.
Claim 2
Dependent Claim 54 words
An asphaltic concrete composition comprising an asphalt, a mineral aggregate, and a radial teleblock copolymer of a conjugated diene and a monovinyl aromatic monomer wherein the teleblock copolymer has a diene/monovinyl aromatic monomer weight ratio of at least about 75/25 to about 90/10 and a weight average molecular weight range of from about 150,000-300,000.
Claim 3
Dependent Claim 38 words
A composition according to claim 1 wherein the diene/monovinyl aromatic weight ratio of the teleblock copolymer is within the approximate range 80/20 to 85/15 and the weight average molecular weight is in the approximate range 190,000 to 300,000.
Claim 4
Dependent Claim 25 words
A composition according to claim 1 wherein the conjugated diene is selected from 1,3-butadiene and isoprene or mixtures thereof and the monovinyl monomer is styrene.
Claim 5
Dependent Claim 31 words
A composition according to claim 1 wherein the asphalt and the copolymer are admixed to obtain a homogeneous dispersion whereupon the mineral aggregate is then admixed with the dispersion thus obtained.
Claim 6
Dependent Claim 19 words
A composition according to claim 1 wherein the polymer weight average molecular weight is in the approximate range 130,000-300,000.
Claim 7
Dependent Claim 34 words
A composition according to claim 1 wherein the ingredients of the composition are as follows: ______________________________________ Ingredient Weight Percent ______________________________________ Mineral Aggregate 96.95-77.0 Asphalt 3.0-20.0 Radial Teleblock Copolymer (2-15 parts per hundred asphalt) ______________________________________
Claim 8
Dependent Claim 35 words
A composition according to claim 1 wherein the ingredients of the composition are as follows: ______________________________________ Ingredient Weight Percent ______________________________________ Mineral Aggregate 95.3-91.2 Asphalt 4.5-8.0 Radial Teleblock Copolymer 0.20-0.80 (5-10 parts per hundred asphalt) ______________________________________
Claim 9
Dependent Claim 34 words
A composition according to claim 2 wherein the ingredients of the composition are as follows: ______________________________________ Ingredient Weight Percent ______________________________________ Mineral Aggregate 96.95-77.0 Asphalt 3.0-20.0 Radial Teleblock Copolymer (2-15 parts per hundred asphalt) ______________________________________
Claim 10
Dependent Claim 35 words
A composition according to claim 2 wherein the ingredients of the composition are as follows: ______________________________________ Ingredient Weight Percent ______________________________________ Mineral Aggregate 95.3-91.2 Asphalt 4.5-8.0 Radial Teleblock Copolymer 0.20-0.80 (5-10 parts per hundred asphalt) ______________________________________
Claim 11
Dependent Claim 34 words
A composition according to claim 3 wherein the ingredients of the composition are as follows: ______________________________________ Ingredient Weight Percent ______________________________________ Mineral Aggregate 96.95-77.0 Asphalt 3.0-20.0 Radial Teleblock Copolymer (2-15 parts per hundred asphalt) ______________________________________
Claim 12
Dependent Claim 35 words
A composition according to claim 3 wherein the ingredients of the composition are as follows: ______________________________________ Ingredient Weight Percent ______________________________________ Mineral Aggregate 95.3-91.2 Asphalt 4.5-8.0 Radial Teleblock Copolymer 0.20-0.80 (5-10 parts per hundred asphalt) ______________________________________
Claim 13
Dependent Claim 34 words
A composition according to claim 4 wherein the ingredients of the composition are as follows: ______________________________________ Ingredient Weight Percent ______________________________________ Mineral Aggregate 96.95-77.0 Asphalt 3.0-20.0 Radial Teleblock Copolymer (2-15 parts per hundred asphalt) ______________________________________
Claim 14
Dependent Claim 15 words
A composition according to claim 4 wherein the ingredients of the composition are as follows:
Claim 15
Dependent Claim 34 words
A composition according to claim 5 wherein the ingredients of the composition are as follows: ______________________________________ Ingredient Weight Percent ______________________________________ Mineral Aggregate 96.95-77.0 Asphalt 3.0-20.0 Radial Teleblock Copolymer (2-15 parts per hundred asphalt) ______________________________________
Claim 16
Dependent Claim 35 words
A composition according to claim 5 wherein the ingredients of the composition are as follows: ______________________________________ Ingredient Weight Percent ______________________________________ Mineral Aggregate 95.3-91.2 Asphalt 4.5-8.0 Radial Teleblock Copolymer 0.20-0.80 (5-10 parts per hundred asphalt) ______________________________________
Claim 17
Dependent Claim 22 words
A composition according to claim 1 wherein the copolymer has been prepared using a coupling agent selected from silicon tetrachloride and polyepoxide.
Claim 18
Dependent Claim 24 words
A composition according to claim 2 wherein the diene is selected from 1,3-butadiene and isoprene or mixtures thereof and the monovinyl monomer is styrene.
Claim 19
Dependent Claim 21 words
A composition according to claim 3 wherein the copolymer is prepared using a coupling agent selected from silicon tetrachloride and polyepoxide.
Claim 20
Dependent Claim 34 words
A composition according to claim 1 wherein the conjugated diene is 1,3-butadiene, the monovinyl aromatic monomer is styrene and wherein silicon tetrachloride is used as a coupling agent in the preparation of the copolymer.
Claim 21
Dependent Claim 34 words
A composition according to claim 16 wherein the ingredients of the composition are as follows: ______________________________________ Ingredient Weight Percent ______________________________________ Mineral Aggregate 96.95-77.0 Asphalt 3.0-20.0 Radial Teleblock Copolymer (2-15 parts per hundred asphalt) ______________________________________
Claim 22
Dependent Claim 35 words
A composition according to claim 19 wherein the ingredients of the composition are as follows: ______________________________________ Ingredient Weight Percent ______________________________________ Mineral Aggregate 95.3-91.2 Asphalt 4.5-8.0 Radial Teleblock Copolymer 0.20-0.80 (5-10 parts per hundred asphalt) ______________________________________

References Cited (Backward Citations)

CA740027A Cited
US3763074A Cited
US3778397A Cited
US3900692A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-08-12 1984-02-11 1984-08-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-08-12 1988-02-11 1988-08-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-08-12 1992-02-11 1992-08-12 $7700.00 Window Closed / Lapsed

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