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US4216102A
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US
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High dielectric constant type ceramic composition consisting essentially of Pb(Fe1/2 Nb1/2)O3 -Pb(Mg1/3 Nb2/3)O3
Assignee: TDK Corp
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Filing: 1979-04-06
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Granted: 1980-08-05
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Expires: 1999-04-06
Abstract
Abstract A novel ceramic composition exhibiting a solid solution structure of Pb(Fe1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3, can be sintered at a low sintering temperature; have a high insulation resistance; have a relatively high dielectric constant in the high dielectric type ceramic dielectrics, and; have a low dielectric loss. A particular amount of the additives, i.e., pb(Mn1/2W1/2)O3, Pb(Mn1/3Nb2/3)O3, MnO, Pb(Mn1/3Ta2/3)O3 Li2O, Cr2O3 and CeO2, is added into the composition mentioned above.
Inventors
- 👤 Kiyoshi Furukawa
- 👤 Shinobu Fujiwara
- 👤 Nobuaki Kikuchi
- 👤 Osamu Iizawa
- 👤 Hitoshi Tanaka
- 👤 Hisayoshi Ueoka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 18:30
CPC Classifications
H; H01; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/06; H01G4/08; H01G4/12; C; C04; C04B; C04B35/00; C04B35/01; C04B35/495; C04B35/497
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
61 words
A high dielectric constant type-, ceramic composition, hereinafter referred to as the basic ceramic composition, consisting essentially of from 67.99 to 68.58% of PbO, from 0.61 to 8.51% of Fe 2 O 3 , from 1.23 to 3.92% of MgO and from 22.27 to 26.89% of Nb 2 O 5 , all percentages being by weight based on the basic composition.
Claim 2
Dependent Claim
61 words
A high dielectric constant type-, ceramic composition, hereinafter referred to as the basic ceramic composition, consisting essentially of from 67.99 to 68.58% of PbO, from 0.61 to 8.51% of Fe 2 O 3 , from 1.23 to 3.92% of MgO and from 22.27 to 26.89% of Nb 2 O 5 , all percentages being by weight based on the basic composition.
Claim 3
Dependent Claim
40 words
A high dielectric constant type-, ceramic composition according to claim 1, wherein the dielectric constant of the basic composition is from 6000 to 14000 and the dielectric loss (tan δ at 1 KH z ) is from 0.1 to 2.1%.
Claim 4
Dependent Claim
48 words
A high dielectric constant type-, ceramic composition according to claim 1, wherein the basic composition comprises from 68.26 to 68.58% of PbO, from 0.61 to 4.88% of Fe 2 O 3 , 2.47 to 3.92% of MgO, and from 24.39 to 26.89% of Nb 2 O 5 .
Claim 5
Dependent Claim
43 words
A high dielectric constant type-, ceramic composition according to claim 1, wherein said ceramic composition further comprises Pb(Mn 2/3 W 5/8 )O 3 in an amount of from 0.05 to 5.0 parts by weight based on 100 weight parts of the basic composition.
Claim 6
Dependent Claim
47 words
A high dielectric constant type-, ceramic composition according to claim 4, wherein said ceramic composition exhibits a dielectric constant of from approximately 5000 to 13000, a dielectric loss (tan δ at 1 KHz) of from 0.07 to 2.0%, and an insulation resistance of 7×10 10 or more.
Claim 7
Dependent Claim
92 words
A high dielectric constant type-, ceramic composition according to claim 4, wherein said Pb(Mn 2/3 W 1/3 )O 3 content is from 0.05 to 0.5 part by weight, and the basic composition is from 68.35 to 68.58% of PbO, from 0.61 to 3.67% of Fe 2 O 3 , from 25.10 to 26.89% of Nb 2 O 5 and from 2.88 to 3.92% of MgO, and said ceramic composition exhibits a dielectric loss (tan δ at 1 KHz) of 0.5% or less and an insulation resistance of 10 11 Ω or more.
Claim 8
Dependent Claim
43 words
A high dielectric onstant type-, ceramic composition according to claim 1, wherein said ceramic composition further comprises Pb(Mn 1/2 W 1/2 )O 3 in an amount of from 0.05 to 5.0 parts by weight based on 100 weight parts of the basic composition.
Claim 9
Dependent Claim
49 words
A high dielectric constant type-, ceramic composition according to claim 7, wherein said composition exhibits a dielectric constant (ε s ) of from approximately 5000 to 13000, a dielectric loss (tan δ at 1 KHz) of from 0.07 to 2.0%, and an insulation resistance of 7×10 10 or more.
Claim 10
Dependent Claim
94 words
A high dielectric constant type-, ceramic composition according to claim 7, the content of said Pb(Mn 1/2 W 1/2 )O 3 is from 0.05 to 0.5 part by weight, and the basic composition is from 68.35 to 68.58% of PbO, from 0.61 to 3.67% of Fe 2 O 3 , from 25.10 to 26.89% of Nb 2 O 5 , and from 2.88 to 3.92% of MgO, and said ceramic composition exhibits a dielectric loss (tan δ at 1 KHz) of 1.0% or less and the insulation resistance of 10 11 Ω or more.
Claim 11
Dependent Claim
65 words
A high dielectric constant type-, ceramic composition according to claim 9, wherein the basic composition comprises from 68.5 to 68.6% of PbO, from 0.61 to 1.0% of Fe 2 O 3 , from 26.0 to 26.89% of Nb 2 O 5 and from 3.5 to 3.92% of MgO and said ceramic composition exhibits a dielectric constant (tan δ at 1 KHz) of less than 0.1%.
Claim 12
Dependent Claim
43 words
A high dielectric constant type-, ceramic composition according to claim 1, wherein said ceramic composition further comprises Pb(Mn 1/3 Ta 2/3 )O 3 in an amount of from 0.05 to 5.0 parts by weight based on 100 weight parts of the basic composition.
Claim 13
Dependent Claim
48 words
A high dielectric constant type-, ceramic composition according to claim 11, wherein said ceramic composition exhibits a dielectric constant of from approximately 4900 to 12000, a dielectric loss (tan δ at 1 KHz) of from 0.1 to 1.6%, and an insulation resistance of 4×10 11 Ω or more.
Claim 14
Dependent Claim
39 words
A high dielectric constant type-, ceramic composition according to claim 1, wherein said ceramic composition further comprises MnO in an amount of from 0.001 to 1.0 part by weight based on 100 weight parts of the basic ceramic composition.
Claim 15
Dependent Claim
50 words
A high dielectric constant type-, ceramic composition according to claim 13, wherein said ceramic composition exhibits a dielectric onstant of from approximately 5200 to 12600, a dielectric loss (tan δ at 1 KHz) of from 0.2 to 1.1%, and an insulation resistance of from 1×10 10 to 1×10 11 Ω.
Claim 16
Dependent Claim
45 words
A high dielectric constant type-, ceramic composition according to claim 13, wherein the content of said MnO is from 0.001 to less than 0.5 part by weight, and said ceramic composition exhibits a dielectric loss (tan δ at 1 KHz) of approximately 1% or less.
Claim 17
Dependent Claim
44 words
A high dielectric constant type-, ceramic composition according to claim 1, wherein said ceramic composition further comprises Pb(Mn 1/3 Nb 2/3 )O 3 in an amount of from 0.05 to 5.0 parts by weight based on 100 weight parts of the basic ceramic composition.
Claim 18
Dependent Claim
49 words
A high dielectric constant type-, ceramic composition according to claim 16, said ceramic composition exhibits a dielectric constant of from approximately 4200 to 11000, a dielectric loss (tan δ at 1 KHz) of from 0.1 to 0.9%, and an insulation resistance of from 2×10 10 to 4×10 11 Ω.
Claim 19
Dependent Claim
56 words
A high dielectric constant type-, ceramic composition according to claim 16, wherein the content of said Pb(Mn 1/3 Nb 2/3 )O 3 is from 0.05 to 0.5 part by weight and said ceramic composition exhibits a dielectric loss (tan δ at 1 KHz) of 0.2% or less, an insulation resistance of 10 11 Ω or more.
Claim 20
Dependent Claim
40 words
A high dielectric constant type-, ceramic composition according to claim 1, wherein said ceramic composition further comprises Li 2 O in an amount of from 0.01 to 2.0 parts by weight based on 100 weight parts of the basic composition.
Claim 21
Dependent Claim
36 words
A high dielectric constant type-, ceramic composition according to claim 19, wherein said ceramic composition exhibits a dielectric constant of from 4700 to 12800 dielectric loss (tan δ at 1 KHz) of from 0.3 to 1.5%.
Claim 22
Dependent Claim
55 words
A high dielectric constant type-, ceramic composition according to claim 19, wherein the content of said Li 2 O is from 0.05 to 0.1 part by weight, and said ceramic composition exhibits a dielectric loss (tan δ at 1 KHz) of 0.7% or less and an insulation resistance of from 1×10 11 Ω or more.
Claim 23
Dependent Claim
53 words
A high dielectric constant type-, ceramic composition according to claim 1, wherein said ceramic composition further comprises at least one member selected from the group consisting of Cr 2 O 3 and CeO 2 in an amount of from 0.05 to 2.0 parts by weight based on 100 parts of the basic composition.
Claim 24
Dependent Claim
50 words
A high dielectric constant type-, ceramic composition according to claim 22, wherein said ceramic composition exhibits a dielectric constant of from approximately 5600 to 13600, a dielectric loss (tan δ at 1 KHz) of from 0.2 to 2.8%, and an insulation resistance of from 6×10 9 to 8×10 11 Ω.
Claim 25
Dependent Claim
87 words
A high dielectric constant type-, ceramic composition according to claim 22, wherein the content of said at least one member is from 0.05 to 0.5 part by weight, and the basic composition is from 68.17 to 68.58% of PbO, from 0.61 to 6.10% of Fe 2 O 3 , from 23.68 to 26.89% of Nb 2 O 5 and from 2.05 to 3.92% of MgO, and said ceramic composition exhibits a dielectric loss of 2.0% or less and an insulation resistance of 3×10 10 Ω or more.
Claim 26
Dependent Claim
75 words
A high dielectric constant type-, ceramic composition according to claim 23, wherein the basic composition is from 68.5 to 68.58% of PbO, from 0.61 to 1.0% of Fe 2 O 3 , from 26.0 to 26.89% of Nb 2 O 5 , and from 3.0 to 3.92% of MgO, and said ceramic composition exhibits a dielectric constant is of more than 13000 and a dielectric loss (tan δ at 1 KHz) of less than 0.5%.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-08-05 | 1984-02-04 | 1984-08-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-08-05 | 1988-02-04 | 1988-08-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-08-05 | 1992-02-04 | 1992-08-05 | $7700.00 | Window Closed / Lapsed |