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US4214022A Expired / Lapsed US ⏱️ 0.0 years remaining

Coating metal by immersion

Assignee: Akzo NV
•
Filing: 1977-10-28
•
Granted: 1980-07-22
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Expires: 1997-10-28
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Abstract

Abstract A coating of a film-forming material is applied without electricity to a metal by immersing the metal in an aqueous dispersion which contains a film-forming material cationically dispersed in a cationic dispersion which contains a carboxylic acid radical capable of reacting with metal ions obtained by etching the metal to form a negatively charged complex in the dispersion.

Inventors

  • 👤 Jan Kunnen
  • 👤 Abraham C. Van Der Schee

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 13:19
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/08; C09D5/088; B; B05; B05D; B05D7/00; B05D7/14; B05D7/142

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 85 words
In an autodeposition process of applying a coating of film-forming material to an acid-etchable metal wherein the metal surface is contacted with an aqueous dispersion of the film-forming material which contains a metal-etching acid, followed by drying the coating, the improvement which comprises dispersing the film-forming material in a cationic dispersion containing at least 0.1% cationic surfactant and a carboxylic acid radical which along with the metal ions obtained by etching the metal surface is capable of forming a negatively charged complex in the dispersion.
Claim 2
Dependent Claim 85 words
In an autodeposition process of applying a coating of film-forming material to an acid-etchable metal wherein the metal surface is contacted with an aqueous dispersion of the film-forming material which contains a metal-etching acid, followed by drying the coating, the improvement which comprises dispersing the film-forming material in a cationic dispersion containing at least 0.1% cationic surfactant and a carboxylic acid radical which along with the metal ions obtained by etching the metal surface is capable of forming a negatively charged complex in the dispersion.
Claim 3
Dependent Claim 11 words
The process of claim 1 wherein the metal substrate is steel.
Claim 4
Dependent Claim 17 words
The process of claim 1 wherein the cationic dispersion contains a cationic or amphoteric surface active compound.
Claim 5
Dependent Claim 23 words
The process of claim 3 wherein the cationic polymer dispersion contains 0.1-15% by weight of surface active compound, based on the film-forming polymer.
Claim 6
Dependent Claim 18 words
The process of claim 1 wherein the pH of the cationic dispersion has a value below about 6.
Claim 7
Dependent Claim 19 words
The process of claim 1 wherein the acidic polymer dispersion contains a carboxylic acid radical derived from mandelic acid.
Claim 8
Dependent Claim 19 words
The process of claim 1 wherein the acidic polymer dispersion contains a carboxylic acid radical derived from malic acid.
Claim 9
Dependent Claim 19 words
The process of claim 1 wherein the acidic polymer dispersion contains a carboxylic acid radical derived from citric acid.
Claim 10
Dependent Claim 56 words
An autodeposition process for coating an acid-etchable metal with a polymer which comprises covering the metal with a cationic dispersion of a polymer in water containing a metal-etching acid and a carboxylic acid radical which forms a negatively charged complex with metal ions in the dispersion resulting from etching of the metal with said metal-etching acid.
Claim 11
Dependent Claim 56 words
An autodeposition process for coating an acid-etchable metal with a polymer which comprises covering the metal with a cationic dispersion of a polymer in water containing a metal-etching acid and a carboxylic acid radical which forms a negatively charged complex with metal ions in the dispersion resulting from etching of the metal with said metal-etching acid.

References Cited (Backward Citations)

US3585684A Cited
US3647567A Cited
US3709743A Cited
NL7208132A Cited
US3839097A Cited
US4160756A Cited
US4108817A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-07-22 1984-01-21 1984-07-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-07-22 1988-01-21 1988-07-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-07-22 1992-01-21 1992-07-22 $7700.00 Window Closed / Lapsed

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