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US3709743A Expired / Lapsed US ⏱️ 0.0 years remaining

Acidic deposition process

Assignee: Hi Tek Polymers Inc
•
Filing: 1971-06-16
•
Granted: 1973-01-09
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Expires: 1991-06-16
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Abstract

Abstract A metallic article is coated with an adherent polymer film by contacting the metallic article with an aqueous bath containing an anionic surfactant stabilized emulsion of a synthetic resinous film forming composition and an oxidizing acid. Interaction of the oxidizing acid and the metallic article produces ions at the surface of the article which ions in turn cause coagulation of the emulsion polymer at the bath-article interface and, thereby, the formation of a coating of the polymer on the surface of the article.

Inventors

  • 👤 J Dalton
  • 👤 R Graver

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 04:40
CPC Classifications
B; B05; B05D; B05D7/00; B05D7/14; B05D7/142; C; C09; C09D; C09D5/00; C09D5/08; C09D5/088

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 52 words
The process of claim 1 wherein the resinous film-forming composition is present in the amount of 5 to 20% by weight based on the total weight of the bath and the nitric acid is present in the amount of 0.5 - 2% by weight based on the total weight of the bath.
Claim 2
Dependent Claim 14 words
nitric acid in the amount of 0.1 to 5 weight of the bath and
Claim 3
Dependent Claim 37 words
water: B. removing the article from contact with the bath; C. rinsing the article with water and D. heating the article at about 150* F. to about 450* F. for a time sufficient to dry the coating.
Claim 4
Dependent Claim 20 words
The process of claim 1 wherein the resinous film-forming composition is a homopolymer or copolymer of ethylenically unsaturated polymerizable monomers.
Claim 5
Dependent Claim 16 words
The process of claim 1 wherein pigments are added to the bath to produce pigmented coatings.
Claim 6
Dependent Claim 26 words
The process of claim 1 wherein the emulsion is stabilized with 50 to 100 weight percent anionic surfactant and 0 to 50 weight percent nonionic surfactant.
Claim 7
Dependent Claim 21 words
The process of claim 1 wherein the synthetic resinous film-forming composition is a homopolymer or copolymer of ethylenically unsaturated polymerizable monomers.
Claim 8
Dependent Claim 29 words
The process of claim 6 wherein the copolymer contains 0.25 to 5.0 weight percent based on the copolymer of a polymerizable acid which contains three to four carbon atoms.
Claim 9
Dependent Claim 65 words
A process for coating ferriferous, zincferrous and stanniferrous metal articles which comprises: A. contacting the articles for a time sufficient to form a coating thereon with an aqueous emulsion containing bath which chemically attacks the surface of the metal article and generates ions which render the emulsion unstable adjacent to the surface and cause coagulation of the emulsion onto the surface, wherein said bath contains
Claim 10
Dependent Claim 63 words
The process of claim 8 wherein the resinous film-forming composition is a homopolymer or copolymer of ethylenically unsaturated polymerizable monomers and is present in the amount of 5 to 20 weight percent based on the total weight of the bath and the nitric acid is present in the amount of 0.5 to 2 weight percent based on the total weight of the bath.
Claim 11
Dependent Claim 16 words
The process of claim 9 wherein pigments are added to the bath to produce pigmented coatings.
Claim 12
Dependent Claim 26 words
The process of claim 9 wherein the emulsion is stabilized with 50 to 100 weight percent anionic surfactant and 0 to 50 weight percent nonionic surfactant.

References Cited (Backward Citations)

US2902390A Cited
US3053692A Cited
US3185596A Cited
US3021228A Cited
US3397077A Cited
US3519542A Cited
US3585084A Cited
US3592699A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-01-09 1976-07-10 1977-01-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-01-09 1980-07-10 1981-01-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-01-09 1984-07-10 1985-01-09 $7700.00 Window Closed / Lapsed

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