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US4213838A Expired / Lapsed US ⏱️ 0.0 years remaining

Corona reaction system

Assignee: Linde GmbH
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Filing: 1979-04-09
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Granted: 1980-07-22
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Expires: 1999-04-09
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Abstract

Abstract A corona reaction system of the type wherein substantially all of the heat generated by corona discharge is removed from the system by gas flow therethrough. A corona discharge gas flow path is provided which is between 2.0 and 10 inches in length and bounded by discharge electrodes spaced apart at a distance of between 0.01 and 0.250 inch, whereby low pressure drop over the gas flow path is maintained under conditions of high power density and gas temperature.

Inventors

  • 👤 Frank E. Lowther

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 15:27
CPC Classifications
C; C01; C01B; C01B13/00; C01B13/10; C01B13/11; B; B01; B01J; B01J19/00; B01J19/08; B01J19/087; B01J19/088; H; H01; H01T; H01T19/00; B01J2219/00; B01J2219/08; B01J2219/0803; B01J2219/0805; B01J2219/0845; B01J2219/0849; C01B2201/00; C01B2201/10; C01B2201/12; C01B2201/40; C01B2201/70; C01B2201/72; C01B2201/74; C01B2201/76

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 151 words
A method for generating ozone by corona discharge, comprising the steps of: (a) providing a corona discharge gas flow path between 2.0 and 10 inches in length, bounded by discharge electrodes spaced apart at distance of between 0.01 and 0.250 inch; (b) generating substantially uniform corona along the length of said gas flow path at power density of between 3.5 and 33 watts/in 2 of electrode surface area; and (c) flowing an oxygen-containing gas along said corona discharge gas flow path from the inlet end to the outlet end thereof for said ozone generation, at flow rate sufficient for the gas flow to remove substantially all of the heat generated by said corona discharge from said gas flow path, and discharging ozone-containing gas from said outlet end of said gas flow path, such that the pressure drop over said gas flow path is maintained between 0.1 and 2 lbs/in 2 .
Claim 2
Independent Claim 151 words
A method for generating ozone by corona discharge, comprising the steps of: (a) providing a corona discharge gas flow path between 2.0 and 10 inches in length, bounded by discharge electrodes spaced apart at distance of between 0.01 and 0.250 inch; (b) generating substantially uniform corona along the length of said gas flow path at power density of between 3.5 and 33 watts/in 2 of electrode surface area; and (c) flowing an oxygen-containing gas along said corona discharge gas flow path from the inlet end to the outlet end thereof for said ozone generation, at flow rate sufficient for the gas flow to remove substantially all of the heat generated by said corona discharge from said gas flow path, and discharging ozone-containing gas from said outlet end of said gas flow path, such that the pressure drop over said gas flow path is maintained between 0.1 and 2 lbs/in 2 .
Claim 3
Dependent Claim 29 words
A method according to claim 1 wherein said corona is generated at voltage of between 2600 and 75,000 volts and frequency of between 60 and 100,000 cycles per second.
Claim 4
Dependent Claim 20 words
A method according to claim 1 wherein the length of said gas flow path is between 2 and 5 inches.
Claim 5
Dependent Claim 34 words
A method according to claim 1 wherein said oxygen-containing gas is flowed sequentially along a plurality of series-connected corona discharge gas flow paths as described in (a), in accordance with steps (b) and (c).
Claim 6
Dependent Claim 24 words
A method according to claim 4 wherein voltage is varied in at least one of said corona discharge gas flow paths in the series.
Claim 7
Dependent Claim 39 words
A method according to claim 4 wherein the product of the pressure of said oxygen-containing gas along each said corona discharge gas flow path and the electrode spacing for said flow path is maintained substantially constant in the series.
Claim 8
Dependent Claim 46 words
A method according to claim 2 comprising the further step of cooling the ozone-containing gas between adjacent corona discharge gas flow paths to remove heat generated along each flow path from said ozone-containing gas before flowing same along the next successive corona discharge gas flow path.
Claim 9
Independent Claim 238 words
A method for generating ozone by corona discharge, comprising the steps of: (a) providing a plurality of series-connected corona discharge gas flow paths each between 2.0 and 10 inches in length, bounded by discharge electrodes spaced apart at a distance of between 0.01 and 0.250 inch; (b) generating substantially uniform corona along the length of each said gas flow path at power density of between 3.5 and 33 watts/in 2 of electrode surface area; (c) sequentially flowing an oxygen-containing gas along each said corona discharge gas flow path in series from the inlet end to the outlet end of each for said ozone generation, at flow rate sufficient for the gas flow to remove substantially all of the heat generated by said corona discharge from each said gas flow path, discharging ozone-containing gas from said outlet end of each said gas flow path and introducing same to the next successive gas flow path in the series with discharge of final ozone-containing gas from the outlet end of the final gas flow path in the series, such that the pressure drop over each said gas flow path is maintained between 0.1 and 2 lbs/in 2 ; and (d) cooling the ozone-containing gas between adjacent corona discharge gas flow paths in the series to remove heat generated along each flow path from said ozone-containing gas before flowing same along the next successive corona discharge gas flow path in the series.
Claim 10
Independent Claim 238 words
A method for generating ozone by corona discharge, comprising the steps of: (a) providing a plurality of series-connected corona discharge gas flow paths each between 2.0 and 10 inches in length, bounded by discharge electrodes spaced apart at a distance of between 0.01 and 0.250 inch; (b) generating substantially uniform corona along the length of each said gas flow path at power density of between 3.5 and 33 watts/in 2 of electrode surface area; (c) sequentially flowing an oxygen-containing gas along each said corona discharge gas flow path in series from the inlet end to the outlet end of each for said ozone generation, at flow rate sufficient for the gas flow to remove substantially all of the heat generated by said corona discharge from each said gas flow path, discharging ozone-containing gas from said outlet end of each said gas flow path and introducing same to the next successive gas flow path in the series with discharge of final ozone-containing gas from the outlet end of the final gas flow path in the series, such that the pressure drop over each said gas flow path is maintained between 0.1 and 2 lbs/in 2 ; and (d) cooling the ozone-containing gas between adjacent corona discharge gas flow paths in the series to remove heat generated along each flow path from said ozone-containing gas before flowing same along the next successive corona discharge gas flow path in the series.
Claim 11
Independent Claim 162 words
A method for generating ozone by corona discharge, comprising the steps of: (a) providing a corona discharge gas flow path between 2.0 and 10 inches in length, bounded by spaced-apart discharge electrodes, with a ratio of the length of said electrodes to the spacing between said electrodes of from 8 to 1000; (b) generating substantially uniform corona along the length of said gas flow path at power density of between 3.5 and 33 watts/in 2 of electrode surface area; and (c) flowing an oxygen-containing gas along said corona discharge gas flow path from the inlet end to the outlet end thereof for said ozone generation, at flow rate sufficient for the gas flow to remove substantially all of the heat generated by said corona discharge from said gas flow path, and discharging ozone-containing gas from said outlet end of said gas flow path, such that the pressure drop over said gas flow path is maintained between 0.1 and 2 lbs/in 2 .
Claim 12
Independent Claim 162 words
A method for generating ozone by corona discharge, comprising the steps of: (a) providing a corona discharge gas flow path between 2.0 and 10 inches in length, bounded by spaced-apart discharge electrodes, with a ratio of the length of said electrodes to the spacing between said electrodes of from 8 to 1000; (b) generating substantially uniform corona along the length of said gas flow path at power density of between 3.5 and 33 watts/in 2 of electrode surface area; and (c) flowing an oxygen-containing gas along said corona discharge gas flow path from the inlet end to the outlet end thereof for said ozone generation, at flow rate sufficient for the gas flow to remove substantially all of the heat generated by said corona discharge from said gas flow path, and discharging ozone-containing gas from said outlet end of said gas flow path, such that the pressure drop over said gas flow path is maintained between 0.1 and 2 lbs/in 2 .

References Cited (Backward Citations)

CA689301A Cited
US3551321A Cited
US3663418A Cited
US3833492A Cited
US3996122A Cited
US3872313A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-07-22 1984-01-21 1984-07-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-07-22 1988-01-21 1988-07-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-07-22 1992-01-21 1992-07-22 $7700.00 Window Closed / Lapsed

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