Patent US4212787A successfully refreshed from Google Patents.
US4212787A
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Thermoplastic elastomer composition, blends of the composition with olefin plastic, and foamed products of the composition and the blends
Assignee: Mitsui Chemicals Inc
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Filing: 1978-05-26
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Granted: 1980-07-15
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Expires: 1998-05-26
Abstract
Abstract Dynamically partially cured composition comprising a peroxide-curable olefin copolymer rubber (such as EDPM) and a peroxide-decomposing olefin plastic (such as PE and PP) is improved by effecting the dynamic heat-treatment with addition of a peroxide-non-curable hydrocarbon rubber (such as PIB) and/or a mineral oil softener (process oil). The dynamic heat-treatment is preferably carried out not only in the presence of an organic peroxide but also in the presence of divinyl benzene. The elastomeric composition is thermoplastic and, with or without further blending with an olefin plastic, is processable by techniques conventionally used for thermoplastic resins. This elastomer composition and blends of the elastomer composition and olefin plastic can be used for producing foamed product in combination with decomposition type foaming agent (such as azodicarbonamide).
Inventors
- 👤 Akira Matsuda
- 👤 Shizuo Shimizu
- 👤 Shunji Abe
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 18:45
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/0061; C08K; C08K5/00; C08K5/04; C08K5/14; C08L; C08L23/00; C08L23/02; C08L23/10; C08L23/16; C08L23/18; C08L23/20; C08L23/22; C08L91/00; C08J2323/00; C08J2323/02; C08L2205/00; C08L2205/03; C08L2312/00; C08L2666/00; C08L2666/02; C08L2666/04
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
218 words
A thermoplastic composition which comprises: 100 to 5 parts by weight of (A) a partially cured elastomer composition obtained by dynamic heat-treatment, in the presence of an organic peroxide, of a mixture of 100 to 40 parts by weight of (a) peroxide-curable olefin copolymer rubber selected from the group consisting of ethylene-propylene copolymer rubber and ethylene-propylene-non conjugated diene terpolymer rubber, 0 to 60 parts by weight of (b) a peroxide-decomposing olefin plastic selected from the group consisting of isotactic polypropylene and propylene- alpha olefin copolymer. wherein the sum of the component (a) and the component (b) is 100 parts by weight, and 5 to 100 parts by weight of (c) at least one member of peroxide-non curable hydrocarbon rubbery material selected from the group consisting of polyisobutylene and butyl rubber, and (d) mineral oil softener; and 0 to 95 parts by weight of (B) an olefin plastic selected from the group consisting of hompolymers of an alpha olefin selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 3-methyl-1-butene, 1-hexene, 3-methyl-1-pentene, 4-methyl-1-pentene and 1-octene; copolymers therebetween; and copolymers thereof with 15 mole % or less of another copolymerizable monomer; wherein the sum of the component (b) and the component B account for not less than 5 parts by weight among 100 parts by weight of the final composition.
Claim 2
Dependent Claim
218 words
A thermoplastic composition which comprises: 100 to 5 parts by weight of (A) a partially cured elastomer composition obtained by dynamic heat-treatment, in the presence of an organic peroxide, of a mixture of 100 to 40 parts by weight of (a) peroxide-curable olefin copolymer rubber selected from the group consisting of ethylene-propylene copolymer rubber and ethylene-propylene-non conjugated diene terpolymer rubber, 0 to 60 parts by weight of (b) a peroxide-decomposing olefin plastic selected from the group consisting of isotactic polypropylene and propylene- alpha olefin copolymer. wherein the sum of the component (a) and the component (b) is 100 parts by weight, and 5 to 100 parts by weight of (c) at least one member of peroxide-non curable hydrocarbon rubbery material selected from the group consisting of polyisobutylene and butyl rubber, and (d) mineral oil softener; and 0 to 95 parts by weight of (B) an olefin plastic selected from the group consisting of hompolymers of an alpha olefin selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 3-methyl-1-butene, 1-hexene, 3-methyl-1-pentene, 4-methyl-1-pentene and 1-octene; copolymers therebetween; and copolymers thereof with 15 mole % or less of another copolymerizable monomer; wherein the sum of the component (b) and the component B account for not less than 5 parts by weight among 100 parts by weight of the final composition.
Claim 3
Dependent Claim
95 words
A thermoplastic composition according to claim 1, which comprises a partially cured elastomer composition obtained by dynamic heat-treatment in the presence of an organic peroxide of a mixture of 90 to 40 parts by weight of said (a) peroxide-curable olefin copolymer rubber, 10 to 60 parts by weight of said (b) peroxide-decomposing olefin plastic, wherein the sum of said component (a) and said component (b) is 100 parts by weight, and 5 to 100 parts by weight of at least one member of said (c) peroxide-non-curable hydrocarbon rubbery material and said (d) mineral oil softener.
Claim 4
Dependent Claim
142 words
A thermoplastic composition according to claim 1, which comprises 100 parts by weight of (A) a partially cured elastomer composition obtained by dynamic heat-treatment in the presence of an organic peroxide of a mixture of 100 to 5 parts by weight of said (a) peroxide-curable olefin copolymer rubber, 0 to 50 parts by weight of said (b) peroxide-decomposing olefin plastic, wherein the sum of said component (a) and said component (b) is 100 parts by weight, and 5 to 100 parts by weight of at least one member of said (c) peroxide-non-curable hydrocarbon rubbery material and said (d) mineral oil softener; and 0 to 95 parts by weight of said (B) olefin plastic, wherein the sum of said component (b) and said component (B) account for not less than 5 parts by weight among 100 parts by weight of the final composition.
Claim 5
Dependent Claim
117 words
A thermoplastic composition according to claim 1, which comprises: 5 to 95 parts by weight (A) a partially cured elastomer composition obtained by dynamic heat-treatment in the presence of an organic peroxide of a mixture of 90 to 50 parts by weight of said (a) peroxide curable olefin copolymer rubber, 10 to 50 parts by weight of said (b) peroxide-decomposing olefin plastic, wherein the sum of said component (a) and said component (b) is 100 parts by weight, and 5 to 50 parts by weight of at least one member of said (c) peroxide non curable hydrocarbon rubbery material and said (d) mineral oil softener; and 95 to 5 parts by weight of said (B) olefin plastic.
Claim 6
Dependent Claim
22 words
A composition according to claim 1, 2, 3 or 4, wherein said ethylene-propylene non-conjugated diene copolymer rubber is ethylene-propylene-ethylidene norbornene copolymer rubber.
Claim 7
Dependent Claim
35 words
A composition according to claim 1, 2, 3 or 4, wherein the mooney viscosity ML 1+4 (100 c) of the said (a) peroxide curable olefin copolymer rubber is in the range of 40 to 80.
Claim 8
Dependent Claim
19 words
A composition according to claim 1, 2, 3 or 4, wherein the (b) peroxide-decomposing olefin plastic is propylene-alpha-olefin copolymer.
Claim 9
Dependent Claim
44 words
A composition according to claim 1, 2, 3 or 4, wherein said (c) peroxide-non-curable hydrocarbon rubbery material is mixed in an amount of 5 to 20 parts by weight with 100 parts by weight in total of said component (a) and said component (b).
Claim 10
Dependent Claim
43 words
A composition according to claim 1, 2, 3 or 4, wherein said (d) mineral oil softener is mixed in an amount of 10 to 40 parts by weight with 100 parts by weight in total of said component (a) and said component (b).
Claim 11
Dependent Claim
56 words
A composition according to claim 1, 2, 3 or 4, wherein the Melt Index (ASTM D-1238-65T) of said (B) olefin plastic is from 10 to 50 measured at 230° C. when said olefin plastic is a propylene homopolymer or a copolymer wherein the predominant monomer is propylene; and 190° C. for other of said olefin plastics.
Claim 12
Independent Claim
217 words
A method of producing a thermoplastic composition, which comprises dynamically heat-treating, in the presence of an organic peroxide, a mixture of 100 to 40 parts by weight of (a) a peroxide-curable olefin copolymer rubber selected from the group consisting of ethylene-propylene copolymer rubber and ethylene-propylene-non conjugated diene terpolymer rubber, 0 to 60 parts by weight of (b) a peroxide-decomposing olefin plastic selected from the group consisting of isotactic polypropylene and propylene-alpha olefin copolymer, wherein the sum of component (a) and component (b) is 100 parts by weight, 5 to 100 parts by weight of at least one member of (c) peroxide-non-curable hydrocarbon rubbery material selected from polyisobutylene and butyl rubber, and (d) mineral oil softeners; to obtain a thermoplastic elastomer composition (A); and then, homogeneously blending 100 to 5 parts by weight of said composition (A) and 0 to 95 parts by weight of (B) an olefin plastic selected from the group consisting of homopolymers of an alpha olefin selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 3-methyl-1-butene, 1-hexene, 3-methyl-1-pentene, 4-methyl-1-pentene and 1-octene; copolymers therebetween; and copolymers thereof with 15 mole % or less of another copolymerizable monomer; wherein the sum of said component (b) and said component (B) account for not less than 5 parts by weight among 100 parts of the final product.
Claim 13
Independent Claim
217 words
A method of producing a thermoplastic composition, which comprises dynamically heat-treating, in the presence of an organic peroxide, a mixture of 100 to 40 parts by weight of (a) a peroxide-curable olefin copolymer rubber selected from the group consisting of ethylene-propylene copolymer rubber and ethylene-propylene-non conjugated diene terpolymer rubber, 0 to 60 parts by weight of (b) a peroxide-decomposing olefin plastic selected from the group consisting of isotactic polypropylene and propylene-alpha olefin copolymer, wherein the sum of component (a) and component (b) is 100 parts by weight, 5 to 100 parts by weight of at least one member of (c) peroxide-non-curable hydrocarbon rubbery material selected from polyisobutylene and butyl rubber, and (d) mineral oil softeners; to obtain a thermoplastic elastomer composition (A); and then, homogeneously blending 100 to 5 parts by weight of said composition (A) and 0 to 95 parts by weight of (B) an olefin plastic selected from the group consisting of homopolymers of an alpha olefin selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 3-methyl-1-butene, 1-hexene, 3-methyl-1-pentene, 4-methyl-1-pentene and 1-octene; copolymers therebetween; and copolymers thereof with 15 mole % or less of another copolymerizable monomer; wherein the sum of said component (b) and said component (B) account for not less than 5 parts by weight among 100 parts of the final product.
Claim 14
Dependent Claim
14 words
A method according to claim 11, wherein said organic peroxide is 1,3-bis(tert.-butyl peroxyisopropyl) benzene
Claim 15
Dependent Claim
28 words
A method according to claim 11, wherein said organic peroxide is used in an amount of 0.05 to 1.0% by weight based on the mixture to be heat-treated.
Claim 16
Dependent Claim
21 words
A method according to claim 11, wherein said mixture is heat-treated in the presence of an organic peroxide and divinyl benzene.
Claim 17
Dependent Claim
26 words
A method according to claim 14, wherein divinyl benzene is used in amount of 0.1 to 2% by weight based on the mixture to be heat-treated.
Claim 18
Dependent Claim
21 words
A method according to claim 14, wherein said organic peroxide is added to said mixture as a dispersion in divinyl benzene.
Claim 19
Independent Claim
89 words
A method of producing a thermoplastic elastomer composition, which comprises dynamically heat-treating, in the presence of an organic peroxide and divinyl benzene, a mixture of 90 to 40 parts by weight of (a) a peroxide-curable olefin copolymer rubber selected from the group consisting of ethylene-propylene copolymer rubber and ethylene-propylene-non conjugated diene copolymer rubber and 10 to 60 parts by weight of (b) a peroxide-decomposing olefin plastic selected from the group consisting of isotactic polypropylene and propylene-alpha olefin copolymer, wherein the sum of these components is 100 parts by weight.
Claim 20
Independent Claim
89 words
A method of producing a thermoplastic elastomer composition, which comprises dynamically heat-treating, in the presence of an organic peroxide and divinyl benzene, a mixture of 90 to 40 parts by weight of (a) a peroxide-curable olefin copolymer rubber selected from the group consisting of ethylene-propylene copolymer rubber and ethylene-propylene-non conjugated diene copolymer rubber and 10 to 60 parts by weight of (b) a peroxide-decomposing olefin plastic selected from the group consisting of isotactic polypropylene and propylene-alpha olefin copolymer, wherein the sum of these components is 100 parts by weight.
Claim 21
Dependent Claim
26 words
A method according to claim 17, wherein divinyl benzene is used in an amount of 0.1 to 2.0% by weight of the mixture to be heat-treated.
Claim 22
Dependent Claim
21 words
A method according to claim 14, wherein said organic peroxide is added to said mixture as a dispersion in divinyl benzene.
Claim 23
Dependent Claim
19 words
A method according to claim 11 or 17, wherein the temperature of said heat-treatment is 150° to 280° C.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-07-15 | 1984-01-14 | 1984-07-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-07-15 | 1988-01-14 | 1988-07-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-07-15 | 1992-01-14 | 1992-07-15 | $7700.00 | Window Closed / Lapsed |