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Polyesteramides derived from bis-oxamidodiols and dicarboxylic acids

Assignee: Ethicon Inc
•
Filing: 1978-05-12
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Granted: 1980-06-24
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Expires: 1998-05-12
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Abstract

Abstract Alternating esteramide polymers are obtained from the reaction of bis-oxamidodiols such as N,N'-bis(ω-hydroxyalkylene)oxamide with a dicarboxylic acid or diesters such as diethyl oxalate, diethyl succinate, diethyl suberate, or dimethyl terephthalate. The polymers are obtained in good yield and have film- and fiber-forming properties. Some polymers are absorbable in biological systems and are useful as absorbable surgical devices. Other of these polymers are nonabsorbable and are useful as textile fibers.

Inventors

  • 👤 Shalaby W. Shalaby
  • 👤 Dennis D. Jamiolkowski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 16:52
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/44; A; A61; A61L; A61L17/00; A61L17/06; A61L17/10; A61L17/105; A61L27/00; A61L27/14; A61L27/18

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 78 words
Alternating esteramide polymer having repeating units represented by ##STR4## wherein R is a divalent aliphatic or aromatic hydrocarbon radical having from 3 to about 8 carbon atoms, R' is a divalent hydrocarbon radical having from 1 to about 8 carbon atoms, A is a divalent oxyalkylene radical having from 4 to 8 carbon atoms, m is 0 or 1, n is 0 or 1, and x is the degree of polymerization resulting in a film-forming or fiber-forming polymer.
Claim 2
Dependent Claim 78 words
Alternating esteramide polymer having repeating units represented by ##STR4## wherein R is a divalent aliphatic or aromatic hydrocarbon radical having from 3 to about 8 carbon atoms, R' is a divalent hydrocarbon radical having from 1 to about 8 carbon atoms, A is a divalent oxyalkylene radical having from 4 to 8 carbon atoms, m is 0 or 1, n is 0 or 1, and x is the degree of polymerization resulting in a film-forming or fiber-forming polymer.
Claim 3
Dependent Claim 20 words
The polymer of claim 1 wherein R is selected from the group consisting of alkylene cycloalkylene, alkylene-cycloalkylene, arylene, and alkylarylene.
Claim 4
Dependent Claim 9 words
The polymer of claim 1 wherein n is 0.
Claim 5
Dependent Claim 22 words
The polymer of claim 3 wherein R is C 3 to C 8 alkylene, C 6 to C 8 cycloalkylene or alkylarylene.
Claim 6
Dependent Claim 10 words
The polymer of claim 3 which is poly N,N'-bis(trimethylene)oxamido oxalate.
Claim 7
Dependent Claim 10 words
The polymer of claim 3 which is poly N,N'-bis(pentamethylene)oxamido oxalate.
Claim 8
Dependent Claim 10 words
The polymer of claim 3 which is poly N,N'-bis(hexamethylene)oxamido oxalate.
Claim 9
Dependent Claim 17 words
The polymer of claim 1 wherein m is 1 and A is --O-(CH 2 ) 6 --.
Claim 10
Dependent Claim 21 words
The polymer of claim 1 wherein n is 1 and R' is C 1-6 alkylene or C 6 H 4 arylene.
Claim 11
Dependent Claim 17 words
The polymer of claim 1 wherein n is 1 and R' is --(CH 2 ) 2 --.
Claim 12
Dependent Claim 10 words
The polymer of claim 10 which is poly N,N'-bis(hexamethylene)oxamido succinate.
Claim 13
Dependent Claim 17 words
The polymer of claim 1 wherein n is 1 and R' is --(CH 2 ) 6 --.
Claim 14
Dependent Claim 10 words
The polymer of claim 12 which is poly N,N'-bis(hexamethylene)oxamido suberate.
Claim 15
Dependent Claim 16 words
The polymer of claim 1 wherein n is 1 and R' is the p-phenylene divalent radical.
Claim 16
Dependent Claim 10 words
The polymer of claim 14 which is poly N,N'-bis(hexamethylene)oxamido terephthalate.

References Cited (Backward Citations)

US2659713A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-06-24 1983-12-24 1984-06-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-06-24 1987-12-24 1988-06-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-06-24 1991-12-24 1992-06-24 $7700.00 Window Closed / Lapsed

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