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US4207157A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for controlling halogen ion concentration in a photographic processing solution

Assignee: Fujifilm Holdings Corp
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Filing: 1978-08-21
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Granted: 1980-06-10
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Expires: 1998-08-21
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Abstract

Abstract The concentration of halogen ions in a photographic developer is controlled at an almost constant value by determining the concentration of halogen ions in the developer by detecting the change in electric potential caused by the addition of silver ions to the solution, and controlling the electrical current supplied to a halogen ion removing means, such as an electrodialysis or an electrolysis unit having an anion exchange membrane, based on the result of the determination of halogen ions. By this method the amount of complementary developer added to a fatigued developer solution can be greatly reduced.

Inventors

  • 👤 Hiroyuki Hirai
  • 👤 Sachio Matsushita
  • 👤 Isao Tsuyuki
  • 👤 Kazumi Watase

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 14:59
CPC Classifications
G; G03; G03D; G03D3/00; G03D3/02; G03D3/06; G03D3/065; G03C; G03C5/00; G03C5/26; G03C5/29; G03C5/31

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 84 words
A method of controlling the halogen ion concentration of a photographic processing solution, comprising the steps of: (a) determining the concentration of halogen ions in a photographic processing solution by adding silver ions in a titration reaction with said halogen ions, wherein an endpoint of said reaction is detected by sensing a change in electrical potential of said reaction system by means of a halogen ion sensitive electrode system, and (b) controlling the removal of halogen ions as a function of the concentration determination.
Claim 2
Independent Claim 84 words
A method of controlling the halogen ion concentration of a photographic processing solution, comprising the steps of: (a) determining the concentration of halogen ions in a photographic processing solution by adding silver ions in a titration reaction with said halogen ions, wherein an endpoint of said reaction is detected by sensing a change in electrical potential of said reaction system by means of a halogen ion sensitive electrode system, and (b) controlling the removal of halogen ions as a function of the concentration determination.
Claim 3
Dependent Claim 24 words
The method of claim 1, wherein the silver ions are added to the photographic processing solution by adding thereto an aqueous silver nitrate solution.
Claim 4
Dependent Claim 25 words
The method of claim 1, wherein the silver ions are added to the photographic processing solution as silver ions from a silver electrode by electrolysis.
Claim 5
Dependent Claim 25 words
The method of claim 1, wherein the silver ions are added to the photographic processing solution according to the halogen ion content in the solution.
Claim 6
Dependent Claim 13 words
The method of claim 1, wherein the halogen ions are removed by electrodialysis.
Claim 7
Dependent Claim 18 words
The method of claim 1, wherein the halogen ions are removed by electrolysis through an anion exchange membrane.

References Cited (Backward Citations)

US1602595A Cited
US2767135A Cited
US2937126A Cited
US3647422A Cited
US4060419A Cited
US4102758A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-06-10 1983-12-10 1984-06-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-06-10 1987-12-10 1988-06-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-06-10 1991-12-10 1992-06-10 $7700.00 Window Closed / Lapsed

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