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US4206270A Expired / Lapsed US ⏱️ 0.0 years remaining

Cathodes for molten carbonate fuel cells

Assignee: RTX Corp
•
Filing: 1978-12-14
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Granted: 1980-06-03
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Expires: 1998-12-14
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Abstract

Abstract Porous cathodes for molten carbonate type fuel cells are made from perovskites. The perovskites tested to date all appear to be good cathode catalysts for the reduction of oxygen in molten carbonate electrolyte and are also stable in the electrolyte.

Inventors

  • 👤 H. Russell Kunz
  • 👤 Lawrence J. Bregoli
  • 👤 Francis J. Luczak

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 14:49
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/86; H01M4/8605; H01M4/8621; H01M4/90; H01M4/9016; H01M2004/8678; H01M2004/8689; H01M8/00; H01M8/14; H01M2008/147; H01M2300/00; H01M2300/0017; H01M2300/0048; H01M2300/0051; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 54 words
A fuel cell including an alkali metal carbonate electrolyte which is molten during operation of the fuel cell, an anode electrode in contact with said electrolyte, and a porous perovskite cathode electrode spaced from said anode electrode and also in contact with said electrolyte, the perovskite having an electrical resistivity of less than 10.0Ω-cm.
Claim 2
Dependent Claim 54 words
A fuel cell including an alkali metal carbonate electrolyte which is molten during operation of the fuel cell, an anode electrode in contact with said electrolyte, and a porous perovskite cathode electrode spaced from said anode electrode and also in contact with said electrolyte, the perovskite having an electrical resistivity of less than 10.0Ω-cm.
Claim 3
Dependent Claim 48 words
The fuel cell according to claim 1 wherein said perovskite is selected from the group consisting of La x K y MnO 3 , La x Zr y CoO 3 , La x Sr y MnO 3 , and La x Sr y CoO 3 , where x+y=1.0.
Claim 4
Dependent Claim 60 words
The fuel cell according to claim 1 wherein said perovskite is selected from the group consisting of La 0 .9 K 0 .1 MnO 3 , La 0 .95 Zr 0 .05 CoO 3 , LaMnO 3 , La 0 .9 Sr 0 .1 MnO 3 , La 0 .9 Sr 0 .1 CoO 3 , and LaCoO 3 .
Claim 5
Dependent Claim 27 words
The fuel cell according to claim 1 wherein the perovskite material of which said cathode electrode is made has an electrical resistivity of no more than 1.0Ω-cm.
Claim 6
Dependent Claim 20 words
The fuel cell according to claim 1 wherein said electrolyte is a binary eutectic of lithium carbonate and potassium carbonate.
Claim 7
Dependent Claim 107 words
A fuel cell including a binary eutectic electrolyte of lithium carbonate and potassium carbonate which is molten during operation of the fuel cell, an anode electrode in contact with said electrolyte, and a porous perovskite cathode electrode spaced from said anode electrode and also in contact with said electrolyte, said perovskite being selected from the group consisting of LaMnO 3 , LaCoO 3 , La x K y MnO 3 , La x Zr y CoO 3 , La x Sr y MnO 3 , and La x Sr y CoO 3 , where x+y=1.0 and said perovskite has an electrical resistivity of no more than 1.0Ω-cm.
Claim 8
Dependent Claim 107 words
A fuel cell including a binary eutectic electrolyte of lithium carbonate and potassium carbonate which is molten during operation of the fuel cell, an anode electrode in contact with said electrolyte, and a porous perovskite cathode electrode spaced from said anode electrode and also in contact with said electrolyte, said perovskite being selected from the group consisting of LaMnO 3 , LaCoO 3 , La x K y MnO 3 , La x Zr y CoO 3 , La x Sr y MnO 3 , and La x Sr y CoO 3 , where x+y=1.0 and said perovskite has an electrical resistivity of no more than 1.0Ω-cm.

References Cited (Backward Citations)

US3268365A Cited
US3400054A Cited
US3644147A Cited
US3959018A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-06-03 1983-12-03 1984-06-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-06-03 1987-12-03 1988-06-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-06-03 1991-12-03 1992-06-03 $7700.00 Window Closed / Lapsed

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