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US4204014A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid coating compositions containing little or no solvent

Assignee: Huels AG
•
Filing: 1979-05-07
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Granted: 1980-05-20
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Expires: 1999-05-07
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Abstract

Abstract In a liquid coating composition comprising a small amount of solvent or no solvent, a binder and optionally conventional auxiliary agents, wherein the binder consists essentially of: (A) 45-10% by weight of an aminoplast, the low molecular weight precursors thereof, or mixtures thereof; and (B) 55-90% by weight of an at least difunctional polyester or a mixture of such polyesters; wherein the polyester component B has been produced by the condensation of a conventional alcohol component I with an acid component III, wherein component III consists essentially of a mixture of: III.1 67-92 molar percent of hexahydroterephthalic acid or a lower alkyl ester thereof; and III.2 8-33 molar percent of an aromatic dicarboxylic acid or a lower alkyl ester derivative thereof; wherein the polyester component B has a molecular weight of 300-1,500 and wherein the binder may be obtained by the cocondensation of aminoplast component A with polyester component B, or by the cocondensation of the starting materials used for the production of aminoplast component A with polyester component B; the improvement wherein component III.2 is terephthalic acid or a lower alkyl ester derivative thereof.

Inventors

  • 👤 Jorg Dorffel
  • 👤 Werner Andrejewski
  • 👤 Wilfried Bartz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:51
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/91; C08G63/914; C08G63/02; C08G63/12; C08G63/16; C08G63/20; C09; C09D; C09D167/00

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 295 words
In a liquid coating composition comprising a small amount of solvent or no solvent, a binder and optionally conventional auxiliary agents, wherein the binder consists essentially of: (A) 45-10% by weight of an aminoplast, the low molecular weight precursors thereof, or mixtures thereof; and (B) 55-90% by weight of an at least difunctional polyester or a mixture of such polyesters; wherein the polyester component B has been produced by the condensation of an alcohol component I with an acid component III, wherein component I consists essentially of: I.1 0-50 molar percent of one or aliphatic polyols of 3 or 4 hydroxy groups and 3-6 carbon atoms; and I.2 100-50 molar percent of a mixture II of aliphatic and cycloaliphatic diols wherein mixture II consists essentially of: II.1 0-90 molar percent of ethylene glycol; II.2 0-90 molar percent of 1,2-propanediol; and II.3 0-40 molar percent of one or more aliphatic or cycloaliphatic diols whose hydroxy functions are separated by 2-8 carbon atoms and up to 2 carbon atoms of which can be replaced by oxygen atoms which are separated from each other and from the hydroxy groups by at least 2 carbon atoms; wherein component III consists essentially of a mixture of: III.1 67-92 molar percent of hexahydroterephthalic acid or a lower alkyl ester thereof; and III.2 8-33 molar percent of an aromatic dicarboxylic acid or a lower alkyl ester derivative thereof; wherein the polyester component B has a molecular weight of 300-1,500 and wherein the binder may be obtained by the cocondensation of aminoplast component A with polyester component B, or by the cocondensation of the starting materials used for the production of aminoplast component A with polyester component B; the improvement wherein component III.2 is terephthalic acid or a lower alkyl ester derivative thereof.
Claim 2
Dependent Claim 295 words
In a liquid coating composition comprising a small amount of solvent or no solvent, a binder and optionally conventional auxiliary agents, wherein the binder consists essentially of: (A) 45-10% by weight of an aminoplast, the low molecular weight precursors thereof, or mixtures thereof; and (B) 55-90% by weight of an at least difunctional polyester or a mixture of such polyesters; wherein the polyester component B has been produced by the condensation of an alcohol component I with an acid component III, wherein component I consists essentially of: I.1 0-50 molar percent of one or aliphatic polyols of 3 or 4 hydroxy groups and 3-6 carbon atoms; and I.2 100-50 molar percent of a mixture II of aliphatic and cycloaliphatic diols wherein mixture II consists essentially of: II.1 0-90 molar percent of ethylene glycol; II.2 0-90 molar percent of 1,2-propanediol; and II.3 0-40 molar percent of one or more aliphatic or cycloaliphatic diols whose hydroxy functions are separated by 2-8 carbon atoms and up to 2 carbon atoms of which can be replaced by oxygen atoms which are separated from each other and from the hydroxy groups by at least 2 carbon atoms; wherein component III consists essentially of a mixture of: III.1 67-92 molar percent of hexahydroterephthalic acid or a lower alkyl ester thereof; and III.2 8-33 molar percent of an aromatic dicarboxylic acid or a lower alkyl ester derivative thereof; wherein the polyester component B has a molecular weight of 300-1,500 and wherein the binder may be obtained by the cocondensation of aminoplast component A with polyester component B, or by the cocondensation of the starting materials used for the production of aminoplast component A with polyester component B; the improvement wherein component III.2 is terephthalic acid or a lower alkyl ester derivative thereof.
Claim 3
Dependent Claim 35 words
A coating composition of claim 1, wherein the mixture II consists essentially of: 60-90 molar percent of the component II.1; 10-40 molar percent of the component II.3; and 0 molar percent of the component II.2.
Claim 4
Dependent Claim 36 words
A coating composition of claim 1 wherein the mixture II consists essentially of 60-90 molar percent of the component II.2; and 10-40 molar percent of the component II.3; and 0 molar percent of the component II.1.
Claim 5
Dependent Claim 35 words
A coating composition of claim 1 wherein the mixture II consists essentially of: 10-90 molar percent of the component II.1; 90-10 molar percent of the component II.2; and 0-40 molar percent of the component II.3.
Claim 6
Dependent Claim 22 words
A coating composition of claim 1, wherein the polyester component B contains, as component III.2, 12-25 molar percent of terephthalic acid units.
Claim 7
Dependent Claim 41 words
A coating composition of claim 1, wherein said molar percentages are as follows: component A: 35-15%; component B: 65-85% component I.1: 0-20%; component I.2: 100-80%; component II.1: 20-80% component II.2: 80-20%; component II.3: 0-30%; component III.1: 75-88%; and component III.2: 12-25%.
Claim 8
Dependent Claim 21 words
A coating composition of claim 1, wherein the acid components III.1 and III.2 are used as the lower alkyl esters thereof.
Claim 9
Dependent Claim 12 words
A coating of claim 7, wherein the esters are the dimethyl esters.
Claim 10
Dependent Claim 15 words
A coating composition of claim 1, wherein the molecular weight of component B is 600-1,000.
Claim 11
Dependent Claim 28 words
The coating composition of claim 1, wherein component A is a hexamethylolmelamine derivative which is liquid at room temperature and is etherified with alcohols of 1-4 carbon atoms.
Claim 12
Dependent Claim 9 words
The coating composition of claim 1 which is solvent-free.
Claim 13
Dependent Claim 15 words
The coating composition of claim 1 which contains up to 30 wt. % of solvent.
Claim 14
Dependent Claim 17 words
A coated substrate whose coating has been applied by baking thereon a coating composition of claim 1.
Claim 15
Dependent Claim 15 words
The coating composition of claim 1, wherein the polyester carries predominantly free hydroxy end groups.
Claim 16
Dependent Claim 32 words
A method of providing a substrate with a protective coating comprising coating the substrate with a coating composition of claim 1 and baking the coated substrate at a temperature of 100°-250° C.

References Cited (Backward Citations)

US3819757A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-05-20 1983-11-19 1984-05-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-05-20 1987-11-19 1988-05-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-05-20 1991-11-19 1992-05-20 $7700.00 Window Closed / Lapsed

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