Polyurethanes based on modified polyisocyanates containing sulphonic acid ester groups and process for the production thereof

Claim 2

A process for the preparation of modified polyisocyanates containing sulphonic acid alkyl ester groups, which may contain the isocyanate groups at least partly in dimerized form, characterized in that isocyanatoaryl sulphonic acids which contain at least two isocyanate groups and in which the isocyanate groups may be at least partly in dimerized form, are reacted with oxiranes and/or oxetanes at temperatures of from 0° to 190° C., the nature and proportions of the reactants being chosen so that the equivalent ratio of the total quantity of isocyanate groups, including the isocyanate groups which may be present in dimerized form, to the quantity of sulphonic acid groups is greater than 1 and the equivalent ratio of oxirane and/or oxetane groups to sulphonic acid groups is from 0.1:1 to 10:1.

Claim 3

The process of claim 1, wherein the aromatic polyisocyanates containing sulphonic acid ester groups are prepared by sulphonating aromatic polyisocyanates in known manner in a first reaction step and the polyisocyanate mixture obtained from this sulphonation, which mixture consists at least partly of isocyanatoaryl sulphonic acids, is reacted with oxiranes and/or oxetanes without being first isolated or purified.

Claim 4

The process of claim 1, wherein mono- and/or poly-isocyanates which are free from sulphonic acid groups are included in the reaction mixture.

Claim 5

The process of claim 1, wherein the equivalent ratio of isocyanate groups to sulphonic acid groups is from 1.05:1 to 50:1.

Claim 6

The process of claim 4, wherein the equivalent ratio of isocyanate groups to sulphonic acid groups is from 2:1 to 30:1.

Claim 7

The process of claim 4, wherein the equivalent ratio of oxirane and/or oxetane groups to sulphonic acid groups is from 0.6:1 to 2:1.

Claim 8

The process of claim 6, wherein the reaction is conducted at a temperature of from 20° to 140° C.

Claim 9

Polyisocyanate mixtures characterized as containing: (a) from about 4 to about 48%, by weight, of isocyanate groups, which may be partly in dimerized form; (b) from about 0.3 to about 38%, by weight, of groups of the formula --SO 2 --O-- forming part of an aryl sulphonic acid alkyl ester group; (c) from 0 to about 36%, by weight, of SO 3 H groups; (d) from 0 to about 25%, by weight, of urethane groups --NH--CO--O--; and (e) from 0 to about 28%, by weight, of allophanate groups ##STR12## the groups mentioned under (d) and (e) together amounting to from at least 0.4%, by weight, to not more than 28%, by weight, and the groups mentioned under (b) and (c) together amounting to not more than 38%, by weight.

Claim 10

Polyisocyanate mixtures characterized as containing: (a) from about 4 to about 48%, by weight, of isocyanate groups, which may be partly in dimerized form; (b) from about 0.3 to about 38%, by weight, of groups of the formula --SO 2 --O-- forming part of an aryl sulphonic acid alkyl ester group; (c) from 0 to about 36%, by weight, of SO 3 H groups; (d) from 0 to about 25%, by weight, of urethane groups --NH--CO--O--; and (e) from 0 to about 28%, by weight, of allophanate groups ##STR12## the groups mentioned under (d) and (e) together amounting to from at least 0.4%, by weight, to not more than 28%, by weight, and the groups mentioned under (b) and (c) together amounting to not more than 38%, by weight.

Claim 11

The mixtures of claim 8, wherein: Component (a) comprises from about 10 to about 40% by weight; Component (b) comprises from about 0.6 to about 28% by weight; Component (c) comprises from 0 to about 10% by weight: Component (d) comprises from about 0.2 to about 20% by weight; and Component (e) comprises from about 0.2 to about 20% by weight.

Claim 12

In the production of oligomeric or polymeric polyaddition products comprising reacting organic polyisocyanates with active hydrogen containing materials, the improvement wherein said polyisocyanate comprises (a) from about 4 to about 48%, by weight, of isocyanate groups, which may be partly in dimerized form; (b) from about 0.3 to about 38%, by weight, of groups of the formula --SO 2 --O-- forming part of an aryl sulphonic acid alkyl ester group; (c) from 0 to about 36%, by weight, of SO 3 H groups; (d) from 0 to about 25%, by weight, of urethane groups --NH--CO--O--; and (e) from 0 to about 28%, by weight, of allophanate groups ##STR13## the groups mentioned under (d) and (e) together amounting to from at least 0.4%, by weight, to not more than 28%, by weight, and the groups mentioned under (b) and (c) together amounting to not more than 38%, by weight.

Claim 13

In the production of oligomeric or polymeric polyaddition products comprising reacting organic polyisocyanates with active hydrogen containing materials, the improvement wherein said polyisocyanate comprises (a) from about 4 to about 48%, by weight, of isocyanate groups, which may be partly in dimerized form; (b) from about 0.3 to about 38%, by weight, of groups of the formula --SO 2 --O-- forming part of an aryl sulphonic acid alkyl ester group; (c) from 0 to about 36%, by weight, of SO 3 H groups; (d) from 0 to about 25%, by weight, of urethane groups --NH--CO--O--; and (e) from 0 to about 28%, by weight, of allophanate groups ##STR13## the groups mentioned under (d) and (e) together amounting to from at least 0.4%, by weight, to not more than 28%, by weight, and the groups mentioned under (b) and (c) together amounting to not more than 38%, by weight.