US4201840A
Expired / Lapsed
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Photographic film units containing a polymeric mordant which covalently bonds with certain dyes
Assignee: Eastman Kodak Co
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Filing: 1979-02-22
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Granted: 1980-05-06
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Expires: 1999-02-22
Abstract
Abstract A photographic element comprising a support, a layer containing certain photographically useful and/or active fragments and a layer containing a dye mordant composition comprising a polymer having recurring units of the formula selected from the group consisting of: ##STR1## wherein: R 2 is hydrogen or alkyl; R 1 is hydrogen, alkyl or aryl; L is a linking group; W is an electron-withdrawing group; X is a leaving group; and n is 0 or 1. The polymeric mordants covalently bond with dyes or dye precursors and are especially useful in diffusion transfer processes.
Inventors
- 👤 Gerald A. Campbell
- 👤 Hyman Cohen
- 👤 Lewis R. Hamilton
- 👤 George Villard
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 19:45
CPC Classifications
G; G03; G03C; G03C8/00; G03C8/42; G03C8/52; G03C8/56
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
257 words
A photographic element comprising a support; a layer comprising silver halide emulsion; and a layer containing non-uniformly and imagewise the reaction product of (a) a photographically useful and/or active fragment having appended thereto a moiety selected from the group consisting of ZNHR, --SO 2 NHR and ##STR88## wherein R is H or alkyl and Z is selected from the group consisting of alkylene, arylenealkylene, cycloalkylene and with R can be taken together with the NH to complete an N containing heterocyclic group and (b) a polymeric mordant, wherein said polymer contains recurring units having the formula selected from the group consisting of ##STR89## wherein R 2 is H or alkyl; R 1 is H, alkyl or aryl; L is a bivalent linking group providing a linkage between the vinyl group and W selected from the group consisting of alkylene, arylene, arylenealkylene, COOR 3 and CONHR 3 ; R 3 is selected from the group consisting of alkylene, arylene and arylenealkylene; W is an electron withdrawing group selected from the group consisting of SO 2 , CO, ##STR90## m is 1 or 2; n is 0 or 1; with the proviso that when n is O, W is SO 2 or ##STR91## and X is a leaving group which can be displaced by nucleophiles or eliminated in the form of HX by treatment with base; wherein said reaction product is formed (a) by displacement of X by said moiety in recurring unit (1), or (b) by addition of said moiety to the double bond of recurring unit (2).
Claim 2
Dependent Claim
257 words
A photographic element comprising a support; a layer comprising silver halide emulsion; and a layer containing non-uniformly and imagewise the reaction product of (a) a photographically useful and/or active fragment having appended thereto a moiety selected from the group consisting of ZNHR, --SO 2 NHR and ##STR88## wherein R is H or alkyl and Z is selected from the group consisting of alkylene, arylenealkylene, cycloalkylene and with R can be taken together with the NH to complete an N containing heterocyclic group and (b) a polymeric mordant, wherein said polymer contains recurring units having the formula selected from the group consisting of ##STR89## wherein R 2 is H or alkyl; R 1 is H, alkyl or aryl; L is a bivalent linking group providing a linkage between the vinyl group and W selected from the group consisting of alkylene, arylene, arylenealkylene, COOR 3 and CONHR 3 ; R 3 is selected from the group consisting of alkylene, arylene and arylenealkylene; W is an electron withdrawing group selected from the group consisting of SO 2 , CO, ##STR90## m is 1 or 2; n is 0 or 1; with the proviso that when n is O, W is SO 2 or ##STR91## and X is a leaving group which can be displaced by nucleophiles or eliminated in the form of HX by treatment with base; wherein said reaction product is formed (a) by displacement of X by said moiety in recurring unit (1), or (b) by addition of said moiety to the double bond of recurring unit (2).
Claim 3
Dependent Claim
20 words
The photographic element of claim 1 wherein the silver halide emulsion is in the same layer as the reaction product.
Claim 4
Dependent Claim
19 words
The photographic element of claim 2 wherein said photographically useful and/or active fragment is a dye or dye precursor.
Claim 5
Dependent Claim
58 words
The photographic element of claim 1 wherein said polymer contains recurring units having the formula selected from the group consisting of: ##STR92## said photographically useful and/or active fragment having appended thereto ZNHR when the polymeric mordant is anionic and said fragment having appended thereto ZNHR, --SO 2 NR or ##STR93## when the polymeric mordant is cationic or nonionic.
Claim 6
Dependent Claim
59 words
The photographic element of claim 1 wherein said polymer containing recurring units has the formula selected from the group consisting of ##STR94## wherein said photographically useful and/or active fragment has appended thereto the moiety ZNHR when the polymeric mordant is cationic or nonionic and said moiety being ZNHR, --SO 2 NHR or ##STR95## when the polymeric mordant is cationic.
Claim 7
Dependent Claim
37 words
The photographic element of claim 1 wherein said polymer is cationic and contains recurring units having the formula selected from the group consisting of ##STR96## said photographically useful and/or active fragment having appended thereto a ZNHR moiety.
Claim 8
Dependent Claim
19 words
The photographic element of claim 1 wherein said photographically useful and/or active fragment is a dye or dye precursor.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-05-06 | 1983-11-05 | 1984-05-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-05-06 | 1987-11-05 | 1988-05-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-05-06 | 1991-11-05 | 1992-05-06 | $7700.00 | Window Closed / Lapsed |