Patent US4200682A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4200682A Expired / Lapsed US ⏱️ 0.0 years remaining

Integrated fuel cell and fuel conversion apparatus

Assignee: RTX Corp
•
Filing: 1979-03-16
•
Granted: 1980-04-29
•
Expires: 1999-03-16
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A pair of reaction vessels provide hydrogen to a fuel cell by making hydrogen in one of the vessels while simultaneously regenerating the other vessel, and then reversing the function of the vessels. In the vessel making hydrogen a hydrocarbon feedstock is cracked and steam reformed using sensible heat generated during the regeneration of the vessel. Regeneration includes preheating, separately within the reaction vessel, fuel cell fuel electrode exhaust and an oxygen containing gas. Preheating is accomplished using the heat of combustion and/or sensible heat stored within material disposed within the vessel while it is making hydrogen. After being preheated the fuel electrode exhaust and oxygen containing gas are allowed to mix and combust within the vessel, thereby heating materials disposed therein. This heat is the heat used to crack and steam reform the hydrocarbon fuel.

Inventors

  • 👤 Richard A. Sederquist

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 04:46
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/06; H01M8/0606; H01M8/0612; C; C01; C01B; C01B3/00; C01B3/02; C01B3/32; C01B3/34; C01B3/46; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 318 words
In a method for providing a continuous supply of hydrogen fuel to a fuel cell from a pair of reaction vessels, said fuel cell comprising a fuel electrode, an oxygen electrode, and an electrolyte disposed therebetween, the steps of alternately: A. making hydrogen fuel in one of said pair of vessels while simultaneously regenerating the other of said pair of vessels; and B. regenerating said one of said pair of vessels while simultaneously making hydrogen fuel in said other of said pair of vessels; wherein steps (A) and (B) each comprise the steps of: (a) introducing a hydrocarbon feedstock and steam into a first of said vessels, which is making hydrogen; (b) cracking and steam reforming said feedstock to make said hydrogen in said first vessel using sensible heat stored within said first vessel, said sensible heat being obtained from the step of regenerating said first vessel; (c) directing the hydrogen produced in step (a) to the fuel electrode of the fuel cell; (d) introducing air into the oxygen electrode of the fuel cell; (e) directing the exhaust from the fuel electrode and an oxygen containing gas into the second of said vessels, which is being regenerated; (f) preheating said oxygen containing gas and said fuel electrode exhaust separately within said second vessel to temperatures high enough to result in combustion of said oxygen containing gas and said fuel electrode exhaust if they are mixed together; (g) mixing said preheated oxygen containing gas and said preheated fuel electrode exhaust within said second vessel and combusting said mixture within said second vessel to regenerate said second vessel by storing within material disposed within said second vessel heat from said step of combusting, wherein said step (f) of preheating is accomplished using the heat from said step of combusting and/or sensible heat stored within said second vessel; (h) exhausting the products of combustion of step (g) from said second vessel.
Claim 2
Dependent Claim 318 words
In a method for providing a continuous supply of hydrogen fuel to a fuel cell from a pair of reaction vessels, said fuel cell comprising a fuel electrode, an oxygen electrode, and an electrolyte disposed therebetween, the steps of alternately: A. making hydrogen fuel in one of said pair of vessels while simultaneously regenerating the other of said pair of vessels; and B. regenerating said one of said pair of vessels while simultaneously making hydrogen fuel in said other of said pair of vessels; wherein steps (A) and (B) each comprise the steps of: (a) introducing a hydrocarbon feedstock and steam into a first of said vessels, which is making hydrogen; (b) cracking and steam reforming said feedstock to make said hydrogen in said first vessel using sensible heat stored within said first vessel, said sensible heat being obtained from the step of regenerating said first vessel; (c) directing the hydrogen produced in step (a) to the fuel electrode of the fuel cell; (d) introducing air into the oxygen electrode of the fuel cell; (e) directing the exhaust from the fuel electrode and an oxygen containing gas into the second of said vessels, which is being regenerated; (f) preheating said oxygen containing gas and said fuel electrode exhaust separately within said second vessel to temperatures high enough to result in combustion of said oxygen containing gas and said fuel electrode exhaust if they are mixed together; (g) mixing said preheated oxygen containing gas and said preheated fuel electrode exhaust within said second vessel and combusting said mixture within said second vessel to regenerate said second vessel by storing within material disposed within said second vessel heat from said step of combusting, wherein said step (f) of preheating is accomplished using the heat from said step of combusting and/or sensible heat stored within said second vessel; (h) exhausting the products of combustion of step (g) from said second vessel.
Claim 3
Dependent Claim 46 words
The method according to claim 1 wherein the step (a) of introducing steam into said first vessel includes introducing at least a portion of the exhaust from said second vessel into said first vessel, said exhaust from said second vessel providing the steam for said reforming.
Claim 4
Dependent Claim 31 words
The method according to claim 2 wherein said step (e) of directing an oxygen containing gas into said second vessel includes directing exhaust from said oxygen electrode into said second vessel.
Claim 5
Dependent Claim 45 words
The method according to claim 2 wherein the electrolyte disposed between said electrodes is molten carbonate and wherein steps (A) and (B) also comprise the step of introducing a portion of the exhaust from said second vessel into said oxygen electrode of the fuel cell.
Claim 6
Dependent Claim 16 words
The method according to claim 3 wherein the electrolyte disposed between said electrodes is phosphoric acid.
Claim 7
Dependent Claim 43 words
The method according to claim 2 including the step of preheating within said first vessel, prior to step (b) of cracking and reforming, one or both of said feedstock and exhaust from said second vessel using sensible heat stored within said first vessel.
Claim 8
Dependent Claim 33 words
The method according to claim 6 wherein the step (b) of cracking and reforming includes gas flow through said vessels countercurrent to the direction of flow of the combusting mixture during step (g).
Claim 9
Dependent Claim 271 words
A fuel cell system comprising: a fuel cell including a fuel electrode, an oxygen electrode, and an electrolyte disposed therebetween; a pair of reaction vessels, each being adapted to alternately make a hydrogen containing gas and to be regenerated, each of said reaction vessels having an upstream end and a downstream end, each vessel having disposed therein, in sequence from its upstream to downstream end, a first volume of inert packing material containing no reform catalyst, a second volume of material including a first region of reform catalyst material, and a third volume of material; means for alternately directing a hydrocarbon feedstock and steam first into said first volume of one of said vessels and then into said first volume of the other of said vessels; means for directing the hydrogen containing gas produced in the one of said vessels receiving said feedstock and steam into said fuel electrode of said fuel cell and for directing the exhaust from said fuel electrode into said third volume of material in the other of said vessels; conduit means within each of said vessels in heat transfer relationship with at least some of said materials disposed in said vessels and including outlet means upstream of said first region of reform catalyst; means for directing an oxygen containing gas into said conduit means, said conduit means constructed and arranged to prevent mixing of the oxygen containing gas and fuel electrode exhaust downstream of or within said first region of reform catalyst; and each of said vessels including combustion products outlet means at its upstream end for exhausting combustion products therefrom during regeneration of each vessel.
Claim 10
Dependent Claim 271 words
A fuel cell system comprising: a fuel cell including a fuel electrode, an oxygen electrode, and an electrolyte disposed therebetween; a pair of reaction vessels, each being adapted to alternately make a hydrogen containing gas and to be regenerated, each of said reaction vessels having an upstream end and a downstream end, each vessel having disposed therein, in sequence from its upstream to downstream end, a first volume of inert packing material containing no reform catalyst, a second volume of material including a first region of reform catalyst material, and a third volume of material; means for alternately directing a hydrocarbon feedstock and steam first into said first volume of one of said vessels and then into said first volume of the other of said vessels; means for directing the hydrogen containing gas produced in the one of said vessels receiving said feedstock and steam into said fuel electrode of said fuel cell and for directing the exhaust from said fuel electrode into said third volume of material in the other of said vessels; conduit means within each of said vessels in heat transfer relationship with at least some of said materials disposed in said vessels and including outlet means upstream of said first region of reform catalyst; means for directing an oxygen containing gas into said conduit means, said conduit means constructed and arranged to prevent mixing of the oxygen containing gas and fuel electrode exhaust downstream of or within said first region of reform catalyst; and each of said vessels including combustion products outlet means at its upstream end for exhausting combustion products therefrom during regeneration of each vessel.
Claim 11
Dependent Claim 17 words
The fuel cell system according to claim 8 wherein said third volume of material includes shift catalyst.
Claim 12
Dependent Claim 35 words
The reaction apparatus according to claim 8 or 9 wherein said conduit means passes through said third volume of material and includes inlet means located near the downstream end of said third volume of material.
Claim 13
Dependent Claim 26 words
The fuel cell system according to claim 8 or 9 wherein said conduit means is disposed entirely upstream of said first region of reform catalyst material.
Claim 14
Dependent Claim 14 words
The fuel cell system according to claim 8 wherein said electrolyte is phosphoric acid.
Claim 15
Dependent Claim 81 words
The fuel cell system according to claim 8 or 12 wherein said means for directing an oxygen containing gas into said conduit means includes means for directing the exhaust from said oxygen electrode into said conduit means, said system also including means for directing at least a portion of the combustion products from said combustion products outlet means of the vessel being regenerated into said first volume of material at the upstream end of the vessel producing the hydrogen containing gas.
Claim 16
Dependent Claim 78 words
The fuel cell system according to claim 8 wherein said electrolyte is an alkali metal which is molten at fuel cell operating temperatures, said system including means for directing a first portion of the combustion products from the combustion products outlet means of the vessel being regenerated into the first volume of material in the vessel producing hydrogen, and for directing air and a second portion of the combustion products to said oxygen electrode of said fuel cell.

References Cited (Backward Citations)

US1794232A Cited
US2289922A Cited
US2879139A Cited
US3380800A Cited
US3397962A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-04-29 1983-10-29 1984-04-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-04-29 1987-10-29 1988-04-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-04-29 1991-10-29 1992-04-29 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag