Patent US4200313A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4200313A Expired / Lapsed US ⏱️ 0.0 years remaining

Carbonless duplicating systems

Assignee: HD ACQUISITION CORP A CORP OF DE
•
Filing: 1979-03-12
•
Granted: 1980-04-29
•
Expires: 1999-03-12
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract 3-[4-(Disubstituted-amino)phenyl] or (9-julolidinyl)-3-(diphenylamino)phthalides useful as color formers in pressure-sensitive and thermal marking systems are prepared by reaction of 2-[4-(disubstituted-amino)benzoyl] or (9-julolidinyl-carbonyl)benzoic acids with diphenylamines.

Inventors

  • 👤 Paul J. Schmidt
  • 👤 William M. Hung

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 12:55
CPC Classifications
C; C07; C07D; C07D307/00; C07D307/77; C07D307/87; C07D307/90; B; B41; B41M; B41M5/00; B41M5/025; B41M5/0253; B41M5/124; B41M5/132; B41M5/136; B41M5/145; B41M5/26; B41M5/30; B41M5/323; B41M5/327; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 251 words
A pressure-sensitive carbonless duplicating system or thermal marking system containing a color-forming substance comprising a compound having the formula ##STR16## wherein: Q 4 is hydrogen or halo; Q 5 is the same as Q 4 ; or di-lower-alkylamino, halo or COX when Q 4 , Q 6 and Q 7 are each hydrogen; Q 6 is the same as Q 4 ; or di-lower-alkylamino, halo or COX when Q 4 , Q 5 and Q 7 are each hydrogen; Q 7 is the same as Q 4 ; X is hydroxy, benzyloxy, alkoxy having from 1 to 18 carbon atoms or OM where M is an alkali metal cation, an ammonium cation or a mono-, di- or trialkylammonium cation having from 1 to 18 carbon atoms; Y 1 , Y 2 , Y 3 and Y 4 are the same or different and are selected from the group consisting of hydrogen, halo, hydroxyl, lower-alkoxy, alkyl having from 1 to 9 carbon atoms, phenyl-lower-alkyl, COOR 4 and NR 5 R 6 where R 4 and R 5 are hydrogen or lower-alkyl and R 6 is hydrogen, lower-alkyl, cycloalkyl having from 5 to 7 carbon atoms, lower alkanoyl, phenylsulfonyl or lower-alkyl-substituted phenylsulfonyl; Z is a radical having the formula ##STR17## in which: R 1 is selected from the group consisting of hydrogen, halo, lower-alkyl, lower-alkoxy and di-lower-alkylamino; R 2 is lower-alkyl; and R 3 is selected from the group consisting of lower-alkyl, benzyl, phenyl, and phenyl substituted with a lower-alkyl or lower-alkoxy group.
Claim 2
Dependent Claim 251 words
A pressure-sensitive carbonless duplicating system or thermal marking system containing a color-forming substance comprising a compound having the formula ##STR16## wherein: Q 4 is hydrogen or halo; Q 5 is the same as Q 4 ; or di-lower-alkylamino, halo or COX when Q 4 , Q 6 and Q 7 are each hydrogen; Q 6 is the same as Q 4 ; or di-lower-alkylamino, halo or COX when Q 4 , Q 5 and Q 7 are each hydrogen; Q 7 is the same as Q 4 ; X is hydroxy, benzyloxy, alkoxy having from 1 to 18 carbon atoms or OM where M is an alkali metal cation, an ammonium cation or a mono-, di- or trialkylammonium cation having from 1 to 18 carbon atoms; Y 1 , Y 2 , Y 3 and Y 4 are the same or different and are selected from the group consisting of hydrogen, halo, hydroxyl, lower-alkoxy, alkyl having from 1 to 9 carbon atoms, phenyl-lower-alkyl, COOR 4 and NR 5 R 6 where R 4 and R 5 are hydrogen or lower-alkyl and R 6 is hydrogen, lower-alkyl, cycloalkyl having from 5 to 7 carbon atoms, lower alkanoyl, phenylsulfonyl or lower-alkyl-substituted phenylsulfonyl; Z is a radical having the formula ##STR17## in which: R 1 is selected from the group consisting of hydrogen, halo, lower-alkyl, lower-alkoxy and di-lower-alkylamino; R 2 is lower-alkyl; and R 3 is selected from the group consisting of lower-alkyl, benzyl, phenyl, and phenyl substituted with a lower-alkyl or lower-alkoxy group.
Claim 3
Dependent Claim 84 words
A pressure-sensitive carbonless duplicating system or thermal marking system according to claim 1 wherein Y 1 , Y 2 , Y 3 and Y 4 are the same or different and are selected from the group consisting of hydrogen, halo, hydroxyl, lower-alkoxy, alkyl having from 1 to 9 carbon atoms, phenyl-lower-alkyl, COOR 4 and NR 5 R 6 where R 4 and R 5 are hydrogen or lower-alkyl and R 6 is hydrogen, lower-alkyl, cycloalkyl having from 5 to 7 carbon atoms or lower-alkanoyl.
Claim 4
Dependent Claim 78 words
A pressure-sensitive carbonless duplicating system or thermal marking system according to claim 2 wherein R 1 is hydrogen or lower-alkyl; R 3 is lower-alkyl or benzyl; Y 1 and Y 3 are each hydrogen; and Y 2 and Y 4 are the same or different and are selected from the group consisting of hydrogen, lower-alkoxy, alkyl having from 1 to 9 carbon atoms and NR 5 R 6 where R 5 and R 6 are each lower alkyl.
Claim 5
Dependent Claim 28 words
A pressure-sensitive carbonless duplicating system or thermal marking system according to claim 3 wherein Q 4 , Q 5 , Q 6 and Q 7 are each hydrogen.
Claim 6
Dependent Claim 32 words
A pressure-sensitive carbonless duplicating system according to claim 4 comprising a support sheet coated on one side with a layer of pressure-rupturable microcapsules containing a liquid solution of the color forming substance.
Claim 7
Dependent Claim 50 words
A thermal marking system according to claim 4 comprising a support sheet coated on one side with a layer containing a mixture of the color-forming substance and an acidic developer arranged such that application of heat will produce a mark forming reaction between the color-forming substance and the acidic developer.
Claim 8
Dependent Claim 31 words
A pressure-sensitive carbonless duplicating system or thermal marking system according to claim 3 wherein Q 4 , Q 5 and Q 7 are each hydrogen and Q 6 is di-lower alkylamino.
Claim 9
Dependent Claim 31 words
A pressure-sensitive carbonless duplicating system according to claim 7 comprising a support sheet coated on one side with a layer of pressure-rupturable microcapsules containing a liquid solution of the color-forming substance.
Claim 10
Dependent Claim 49 words
A thermal marking system according to claim 7 comprising a support sheet coated on one side with a layer containing a mixture of the color-forming substance and an acidic developer arranged such that application of heat will produce a mark-forming reaction between the color-forming substance and the acidic developer.
Claim 11
Dependent Claim 28 words
A pressure-sensitive carbonless duplicating system or thermal marking system according to claim 3 wherein Q 4 , Q 5 , Q 6 and Q 7 are each halo.
Claim 12
Dependent Claim 31 words
A pressure-sensitive carbonless duplicating system according to claim 10 comprising a support sheet coated on one side with a layer of pressure-rupturable microcapsules containing a liquid solution of the color-forming substance.
Claim 13
Dependent Claim 49 words
A thermal marking system according to claim 10 comprising a support sheet coated on one side with a layer containing a mixture of the color-forming substance and an acidic developer arranged such that application of heat will produce a mark-forming reaction between the color-forming substance and the acidic developer.
Claim 14
Dependent Claim 73 words
A pressure-sensitive carbonless duplicating system or thermal marking system containing a color-forming substance comprising a compound having the formula ##STR18## wherein Q 4 , Q 5 , Q 6 and Q 7 are hydrogen; Y 1 , Y 2 , Y 3 and Y 4 are the same or different and are selected from the group consisting of hydrogen, lower-alkoxy and alkyl having from 1 to 9 carbon atoms; and Z is 9-julolidinyl.
Claim 15
Dependent Claim 73 words
A pressure-sensitive carbonless duplicating system or thermal marking system containing a color-forming substance comprising a compound having the formula ##STR18## wherein Q 4 , Q 5 , Q 6 and Q 7 are hydrogen; Y 1 , Y 2 , Y 3 and Y 4 are the same or different and are selected from the group consisting of hydrogen, lower-alkoxy and alkyl having from 1 to 9 carbon atoms; and Z is 9-julolidinyl.
Claim 16
Dependent Claim 31 words
A pressure-sensitive carbonless duplicating system according to claim 13 comprising a support sheet coated on one side with a layer of pressure-rupturable microcapsules containing a liquid solution of the color-forming substance.
Claim 17
Dependent Claim 49 words
A thermal marking system according to claim 13 comprising a support sheet coated on one side with a layer containing a mixture of the color-forming substance and an acidic developer arranged such that application of heat will produce a mark-forming reaction between the color-forming substance and the acidic developer.

References Cited (Backward Citations)

US2997481A Cited
JPS478462U Cited
JPS479699U Cited
US4094877A Cited
DE2537776A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-04-29 1983-10-29 1984-04-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-04-29 1987-10-29 1988-04-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-04-29 1991-10-29 1992-04-29 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag