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US4198254A Expired / Lapsed US ⏱️ 0.0 years remaining

Vitreous sheets with synthetic polymer spacer and process for making the same

Assignee: BFG Glassgroup GIE
•
Filing: 1977-11-25
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Granted: 1980-04-15
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Expires: 1997-11-25
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Abstract

Abstract A hollow panel is prepared by uniting vitreous sheets by a spacer of synthetic polymeric material between the sheets. Preferably the polymeric material is a mixture including two polymers of substantially different molecular weight. A ribbon made of the polymeric composition is also disclosed.

Inventors

  • 👤 Pierre Laroche
  • 👤 Jean Rase

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 17:56
CPC Classifications
B; B32; B32B; B32B3/00; B32B3/02; B32B3/08; B32B7/00; B32B7/04; B32B7/12; C; C03; C03C; C03C27/00; C03C27/06; C03C27/10; C09; C09J; C09J123/00; C09J123/02; C09J123/04; C09J123/08; C09J123/18; C09J123/20; C09J123/22; E; E06; E06B; E06B3/00; E06B3/66; E06B3/663; E06B3/66309; E06B3/66328; B32B2607/00; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/04

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 253 words
In a method of manufacturing a hollow panel by uniting vitreous sheets by means of a spacer of synthetic polymeric material located between and adherent to margins of such sheets, the improvement consisting essentially of the steps of (1) laying upon the margin of one of the sheets a hardenable viscoelastic ribbon having cross-sectional dimensions and a viscosity sufficient to maintain the two sheets at at least the required final inter-sheet spacing under the weight of the superimposed sheet when the sheets are disposed horizontally with the ribbon between them, (2) laying the other sheet in generally horizontal position supported by said ribbon, and (3) then subjecting said ribbon to hardening conditions while the sheets are at said final required spacing to convert the ribbon into a spacer having a tensile strength of at least 4 kg/cm 2 , an elongation at break in excess of 50% and a water permeability of the polymeric material less than 0.2 g of water per m 2 of surface per 24 hours per mm of material thickness per cm of Hg pressure, wherein said viscoelastic ribbon is cured in situ at less than 100° C. to form said spacer, and wherein prior to hardening, said viscoelastic ribbon is capable of resisting significant deformation under the forces imposed by the superencumbent vitreous sheet and of resisting any permanent deformation under any forces which may be imposed by the handling of the ribbon before it is laid on one of the vitreous sheets in the panel assembly operation.
Claim 2
Dependent Claim 253 words
In a method of manufacturing a hollow panel by uniting vitreous sheets by means of a spacer of synthetic polymeric material located between and adherent to margins of such sheets, the improvement consisting essentially of the steps of (1) laying upon the margin of one of the sheets a hardenable viscoelastic ribbon having cross-sectional dimensions and a viscosity sufficient to maintain the two sheets at at least the required final inter-sheet spacing under the weight of the superimposed sheet when the sheets are disposed horizontally with the ribbon between them, (2) laying the other sheet in generally horizontal position supported by said ribbon, and (3) then subjecting said ribbon to hardening conditions while the sheets are at said final required spacing to convert the ribbon into a spacer having a tensile strength of at least 4 kg/cm 2 , an elongation at break in excess of 50% and a water permeability of the polymeric material less than 0.2 g of water per m 2 of surface per 24 hours per mm of material thickness per cm of Hg pressure, wherein said viscoelastic ribbon is cured in situ at less than 100° C. to form said spacer, and wherein prior to hardening, said viscoelastic ribbon is capable of resisting significant deformation under the forces imposed by the superencumbent vitreous sheet and of resisting any permanent deformation under any forces which may be imposed by the handling of the ribbon before it is laid on one of the vitreous sheets in the panel assembly operation.
Claim 3
Dependent Claim 24 words
A method as defined in claim 1 wherein said viscoelastic ribbon is laid by extruding the same onto the margin of said one sheet.
Claim 4
Dependent Claim 66 words
A method as defined in claim 1 wherein the thickness of the ribbon measured in a direction normal to the vitreous sheets between which it is located preparatory to the hardening operation is in excess of the said required final inter-sheet spacing and pressure is exerted on the assembly to bring the inter-sheet spacing to that required value before the ribbon is converted into said spacer.
Claim 5
Dependent Claim 62 words
A method as defined in claim 3 wherein said pressure is exerted by bringing about relative horizontal displacement between a support on which the assembly is located and at least one roller which is spaced above said support by a distance equal to the required final overall thickness of the panel, to cause said roller to bear against the upper vitreous sheet.
Claim 6
Dependent Claim 37 words
A method as defined in claim 1 wherein the composition forming said viscoelastic ribbon has at 80° C. a viscosity of between 40,000 to 120,000 poises estimated by means of a Brabender plastograph test as herein defined.
Claim 7
Dependent Claim 23 words
A method as defined in claim 5 wherein the viscoelastic ribbon has a tensile strength of from 0.5 to 3 kg/cm 2 .
Claim 8
Dependent Claim 20 words
A method as defined in claim 6 wherein the viscoelastic ribbon has an elongation at break in excess of 700%.
Claim 9
Dependent Claim 35 words
A method as defined in claim 7 wherein the composition of said viscoelastic ribbon and said hardening conditions are such that the spacer has a tensile strength of from 4 to 50 kg/cm 2 .
Claim 10
Dependent Claim 34 words
A method as defined in claim 8 wherein the composition of said viscoelastic ribbon and said hardening conditions are such that the spacer has a tensile strength of at least 10 kg/cm 2 .
Claim 11
Dependent Claim 30 words
A method as defined in claim 9 wherein the composition of said viscoelastic ribbon and said hardening conditions are such that the spacer has an elongation at break exceeding 100%.
Claim 12
Dependent Claim 33 words
A method as defined in claim 10 wherein the composition of said viscoelastic ribbon and said hardening conditions are such that said spacer has an elongation at break of from 150 to 450%.
Claim 13
Dependent Claim 22 words
A method as defined in claim 1 wherein said viscoelastic ribbon incorporates a mixture of high and low molecular weight polymeric substances.
Claim 14
Dependent Claim 38 words
A method according to claim 12 wherein the high molecular weight polymeric substance is butyl rubber of molecular weight at least 400,000 and the low molecular weight polymeric substance is butyl rubber of molecular weight not over 50,000.
Claim 15
Dependent Claim 14 words
A method as defined in claim 1 wherein said viscoelastic ribbon incorporates a tackifier.
Claim 16
Dependent Claim 16 words
A method as defined in claim 1 wherein said viscoelastic ribbon incorporates a hot melt adhesive.
Claim 17
Dependent Claim 30 words
A method as defined in claim 1 wherein at least one desiccant-containing strip is laid adjacent to said ribbon so that the desiccant-containing strip is located internally of the panel.
Claim 18
Dependent Claim 22 words
A method as defined in claim 16 wherein at least one said desiccant-containing strip comprises a desiccant distributed in a water-permeable binder.
Claim 19
Dependent Claim 18 words
A method as defined in claim 16 wherein each desiccant-containing strip is caused to adhere to said ribbon.
Claim 20
Dependent Claim 33 words
A method as defined in claim 18 wherein said desiccant-containing strip and said ribbon are caused to adhere to each other as or before said ribbon is laid on said one vitreous sheet.
Claim 21
Dependent Claim 15 words
A method as defined in claim 16 wherein said desiccant-containing strip is an extruded strip.

References Cited (Backward Citations)

US2257680A Cited
US3630814A Cited
US3897580A Cited
US3758996A Cited
US3991910A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-04-15 1983-10-15 1984-04-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-04-15 1987-10-15 1988-04-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-04-15 1991-10-15 1992-04-15 $7700.00 Window Closed / Lapsed

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